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Synthesis, Characterization, and Properties of Novel Metalloporphyrin Oligomers with Various Shapes

Research Project

Project/Area Number 08454206
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

IMAMURA Taira  Hokkaido Univ., Graduate School of Science., Assoc.Prof., 大学院・理学研究科, 助教授 (90113521)

Project Period (FY) 1996 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥7,600,000 (Direct Cost: ¥7,600,000)
Fiscal Year 1997: ¥2,400,000 (Direct Cost: ¥2,400,000)
Fiscal Year 1996: ¥5,200,000 (Direct Cost: ¥5,200,000)
Keywordsporhyrin / oligomer / ruthenium / osmium / interaction / tetramer / dimer / pentamer / 金属ポルフィリン / 分子内相互作用
Research Abstract

The purpose of this research was the preparation and characterization of novel ruthenium and osmium porphyrin oligomers. Structural analysis, electronic state, reactivity, and intramolecular interaction were also studied.
The results are as follows,
1.Various novel ruthenium and osmium porphyrin oligomers were self-assembled and characterized. The oligomers include cyclic tetramers, oblique tetramers, facial dimers, and pentamers.
2.The structure of one of the ruthenium porphyrin dimers was determined by X-ray crystallography.
3.The measurements of UV-vis spectra and electrochemistry clarified the existence of the intramolecular interactions between the constituent porphyrin subunits of these oligomers.
4.^1H NMR measurements of a series of the novel osmium porphyrin oligomers clarified a large ring-current effect of porphyrin subunit rings on the inner proton signal shifts of the adjacent porphyrin subunits.

Report

(3 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • Research Products

    (36 results)

All Other

All Publications (36 results)

  • [Publications] Mai, Osada: "In situ UV-visible Spectral Detection of a Molybdenum Dioxygen Porphyrin Complex Formed in the Solid State Process" Chemistry Letters. 1996. 713-714 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Nobuko, Kariya: "Synthesis,Characterization,and SpectralProperties of New Perpendicularly Linked Osmium(II) Porphyrin Oligomers" Inorganic Chemistry. 36. 833-839 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yoichi, Sasaki: "Reactivity of Di-and Tri-Nuclear Complexes of Heavy Mid-Transition Elements:A Case of Oxo-Carboxylato-Bridged Complexes" Pure and Applied Chemistry. 69. 205-210 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Kenji, Funatsu: "Perpendicularly Arranged Ruthenium Porphyrin Dimers and Trimers" Inorganic Chemistry. 36. 1625-1635 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Koji, Hoshiba: "Dioxygenation of a Molybdenum(IV) Porphyrin Complex as Studied by an In Situ Quartz Crystal Microbalance / UV-vis Spectroscopy Combined Method" Chemistry Letters. 1997. 853-854 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Mats, Valli: "An In situ X-ray Absorption Fine Structure Study of Different Oxidation States of Some Oxo-and Hydroxo-Bridged Ruthenium Dimers in Acetonitrile Solution" Inorganic Chemistry. 36. 4622-4626 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Junichi, Tachibana: "A Reversible Metalloporphyrin Oxygen Carrier both in the Solid State and in Solution.Preparation, Characterization and Kinetics of Formation of a Molybdenum(VI) Tetramesitylporphyrin Dioxygen Complex." Bulletin of the Chemical Society of Japan. 71. 363-369 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Kenji, Funatsu: "Synthesis and Properties of Cyclic Rutheniun(II) Porphyrin Tetramers" Inorganic Chemistry. 37(in press). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Nobuko, Kariya: "Synthesis and Properties of Osmium(II) Porphyrin Oligomers Linked by 3-Pyridyl Porphyrins" Inorganic Chemistry. 37(in press). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Kenji, Funatsu: "Novel Ruthenium Porphyrin Dimers and Tetramers" Inorganic Chemistry. 37(in press). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Junichi, Tachibana: "Supramolecular Hybrid Compositions of Metalloporphyrins and Fullerene Encapsulated in the Ordered Nano-Channels of FSM-16 as Oxygen Carriers,and Photo-catalysis for Selective Propene Oxidation towards Acetone" Supramolecular Sciencs. 5(in press). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Mai Osada: "In situ UV-visible Spectral Detection of a Molybdenum Dioxygen Porphyrin Complex Formed in the Solid State Process" Chemistry Letters. 1996. 713-714 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Nobuko Kariya: "Synthesis, Characterization, and Spectral Properties of New Perpendicularly Linked Osmium(II)Porphyrin Oligomers." Inorganic Chemistry. 36. 833-839 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yoichi Sasaki: "Reactivity of Di-and Tri-Nuclear Complexes of Heavy Mid-Transition Elements : A Case of Oxo-Carboxylato-Bridged Complexes" Pure and Applied Chemistry. 69. 205-210 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Kenji Funatsu: "Perpendicularly Arranged Ruthenium Porphyrin Dimers and Trimers" Inorganic Chemistry. 36. 1625-1635 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Koji Hoshiba: "Dioxygenation of a Molybdenum(IV)Porphyrin Complex as Studied by an In Situ Quartz Crystal Microbalance/UV-vis Spectroscopy Combined Method" Chemistry Letters. 1997. 853-854 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Mats Valli: "An In situ X-ray Absorption Fine Structure Study of Different Oxidation States of Some Oxo-and Hydroxo-Bridged Ruthenium Dimers in Acetonitrile Solution" Inorganic Chemistry. 36. 4622-4626 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Junichi Tachibana: "A Reversible Metalloporphyrin Oxygen Carrier both in the Solid State and in Solution.Preparation, Characterization and Kinetics of Formation of a Molybdenum (VI) Tetramesitylporphyrin Dioxygen Complex." Bulletin of the Chemical Society of Japan. 71. 363-369 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Kenji Funatsu: "Synthesis and Properties of Cyclic Rutheniun (II) Porphyrin Tetramers" Inorganic Chemistry. 37 (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Nobuko Kariya: "Synthesis and Properties of Osmium (II) Porphyrin Oligomers Linked by 3-Pyridy Porphyrins" Inorganic Chemistry. 37 (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Kenji Funatsu: "Novel Ruthenium Porphyrin Dimers and Tetramers" Inorganic Chemistry. 37 (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Junichi Tachibana: "Supramolecular Hybrid Compositions of Metalloporphyrins and Fullerene Encapsulated in the Ordered Nano-Channels of FSM-16 as Oxygen Carriers, and Photo-catalysis for Selective Propene Oxidation towards Acetone" Supramolecular Science. 5 (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Nobuko Kariya: "Synthesis,Characterization,and Spectral Properties of New Perpendicularly Linked Osmium(II)Porphyrin Oligomers" Inorganic Chemistry. 36. 833-839 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Yoichi Sasaki: "Reactivity of Di-and Tri-Nuclear Complexes of Heavy Mid-Transition Elements:A Case of Oxo-Carboxylato-Bridged Complexes" Pure and Applied Chemistry. 69. 205-210 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Kenji Funatsu: "Perpendicularly Arranged Ruthemium Porphyrin Dimers and Trimers" Inorganic Chemistry. 36. 1625-1635 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Koji Hoshiba: "Dioxygenation of a Molybdenum(IV)Porphyrin Complex as Studied by an In Situ Quartz Crystal Microbalance/UV-vis Spectroscopy Combined Method" Chemistry Letters. 1997. 853-854 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Mats Valli: "An In situ X-ray Absorption Fine Structure Study of Different Oxidation States of Some Oxo-and Hydroxo-Bridged Ruthenium Dimers in Acetonitrile Solution" Inorganic Chemistry. 36. 4622-4626 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Junichi Tachibana: "A Reversible Metalloporphyrin Oxygen Carrier both in the Solid State and in Solution.Preparation,Characterization and Kinetics of Formation of a Molybdenum(VI)Tetramesitylporphyrin Dioxygen Complex." Bulletin of the Chmeical Society of Japan. 71. 363-369 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Kenji Funatsu: "Synthesis and Properties of Cyclic Rutheniun(II)Porphyrin Tetramers" Inorganic Chemistry. 37(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Nobuko Kariya: "Synthesis and Properties of Osmium(II)Porphyrin Oligomers Linked by 3-Pyridyl Porphyrins" Inorganic Chemistry. 37(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Kenji Funatsu: "Novel Ruthenium Porphyrin Dimers and Tetramers" Inorganic Chemistry. 37(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Junichi Tachibana: "Supramolecular Hybrid Compositions of Metalloporphyrins and Fullerene Encapsulated in the Ordered Nano-Channels of FSM-16 as Oxygen Carriers,and Photo-catalysis for Selective Propene Oxidation towards Acetone" Supramolecular Science. 5(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Mai Osada: "In situ UV-visible Spectral Detection of a Molybdenum Dioxygen Porphyrin Complex Formed in the Solid State Process" Chemistry Letteres. 1996. 713-714 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Yoichi Sasaki: "Reactivity of Di- and Tri-Nuclear Complexes of Heavy Mid-Transition Elements : A case of Oxo-Carboxylato- Bridged Complexes" Pure and Applied Chemistry. (in press). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] Nobuko Kariya: "Synthesis, Characterization, and Spectral Properties of New Perpendicularly linked Osmium (11) Porphyrin Oligomers" Inorganic Chemistry. vol.36 (in press). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] Kenji Funatsu: "Perpendicularly Arranged Ruthenium Porphyrin Dimers and Trimers" Inorganic Chemistry. vol.36 (in press). (1997)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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