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Development of the Apparatus for Visualizing Stratospheric Chemical Reactions

Research Project

Project/Area Number 08559014
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 広領域
Research InstitutionOkazaki National Research Institutes

Principal Investigator

SUZUKI Toshinori  Okazaki National Research Institutes, Institute for Molecular Science, Associate Professor, 分子科学研究所, 助教授 (10192618)

Co-Investigator(Kenkyū-buntansha) KOHGUCHI Hiroshi  Okazaki National Research Institutes, Institute for Molecular Science, Research, 分子科学研究所, 助手 (40311188)
戸野倉 賢一  岡崎国立共同研究機構, 分子科学研究所, 助手 (00260034)
Project Period (FY) 1996 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥16,800,000 (Direct Cost: ¥16,800,000)
Fiscal Year 1997: ¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 1996: ¥14,500,000 (Direct Cost: ¥14,500,000)
KeywordsStratospheric reactions / Grossed molecular beams / Imaging / 散乱 / レーザー / オゾン層 / 酸素分子
Research Abstract

A new crossed molecular beam apparatus with a high-resolution ion imaging detector is described. Two pulsed supersonic molecular beams are crossed at the right angle in a vacuum of 10^<-7> Torr. The collision region is irradiated with a tunable laser pulse that ionizes the scattered particles state-selectively. The generated ions are accelerated by stacked electrodes in a two-dimensional (2D) space focusing mode that increases velocity resolution of the apparatus. A cylindrical hexapole deflector placed in the middle of the time-of-flight mass spectrometer compensates the center-of-mass velocity of the ions and directs them to the center of the 2D imaging detector. Real-time image processing of a CCD camera signal eliminates the blurring of the imaging detector. The performance of the apparatus was examined by observing the inelastic scattering of NO + Ar at the collision energy of 66 meV.The observed multiple rainbow peaks clearly demonstrate high performance of the apparatus.

Report

(3 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • Research Products

    (29 results)

All Other

All Publications (29 results)

  • [Publications] Yonekura et al.: "A crossed molecular beam apparatus using high resolution ion imaging" Review of scientific instruments. in press.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Hashimoto and Suzuki: "Predissociation of acetylene from the A state" Journal of Chemical Physics. 110. 2042-2050 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Mo et al.: "Probing the alignment of NO(X^2Pi) by (2+1) resonance enhanced multiphoton ionization" Journal of Chemical Physics. 110. 2029-2041 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Shi and Suzuki: "Formation of metastable triplet acetylene from the A state near the dissociation threshold" JOurnal of Physical Chemistry A. 102. 7414-7419 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Suzuki et al.: "Non-adiabatic bending dissocaiation in 16 valence electron system OCS" Journal of Chemical Physics. 109. 5778-5794 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Mo and Suzuki: "Geometrial factors of two-photon absorption for the determination of alignment and orientation" Journal of Chemical Physics. 108. 4691-4692 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Takeshi Shibata and Toshinori Suzuki: ""Photofragment ion imaging with femtosecond laser pulses"" Chemical Physics Letters. 262. 115-119 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Nobuhisa Hashimoto et al.: ""Nanosecond pump-probe measurements of predissociation reaction time of C_2H_2 from A(^1A_u) state"" Chemical Physics Letters. 264. 545 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Toshinori Suzuki et al.: ""Detection of metastable triplet acetylene produced by intersystem crossing from the excited A(^1A_u) state"" Journal of Chemical Physics. 106. 5292-5295 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Toshinori Suzuki, Hideki Katayanagi, and Michael C.Heaven: ""Detection of ArHI by (2+1) REMPI"" Journal of Physical Chemistry. 101. 6697-6701 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Kenichi Tonokura et al.: ""C-Cl bond rupture in ultraviolet photodissociation of vinyl chloride"" Journal of Physical Chemistry. 101. 7754-7764 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Takeshi Shibata et al.: ""Dissociation of metastable CH_3CO radical observed by subpicosecond time-clocked photofragment imaging"" Journal of Physical Chemistry. 102. 2643-2647 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Hideki Katayanagi et al.: ""C-Br bond rupture in 193 nm photodissociation of vinyl bromide"" Chemical Physics. 231. 345-353 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yuxiang Mo and Toshinori Suzuki: ""Quantal and semiclassical analysis of vector correlation in molecular photodissociation"" Journal of Chemical Physics. 108. 6780-6789 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yuxiang Mo and Tshinori Suzuki: ""Geometrical factors of two-photon absorption for the determination of alignment and orientation"" Journal of Chemical Physics. 108. 4691-4692 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Toshinori Suzuki et al: ""Non-adiabatic bending dissociation in 16 valence electron system OCS"" Journal of Chemical Physics. 109. 5778-5794 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yang Shi and Toshinori Suzuki: ""Formation of metastable triplet acetylene from the A(^1A_u) state near the dissociation threshold"" Journal of Physical Chemistry A. 102. 7414-7419 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Yuxiagn Mo et al.: ""Probing alignment of NO(X^2II) by [2+1] REMPI via C^2II state : a test of semiclassical theory in 355 nm photodissociation of NO_2"" Journal of Chemical Physics. 110. 2029-2041 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Nobuhisa Hashimoto and Toshinori Suzuki: ""Predissociation of acetylene from the A(^1A_u) state studied by absorption, LIF, and H-atom action spectrocopies"" Jouranal of Chemical Physics. 110. 2041-2050 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Nobuaki Yonekura et al.: ""Crossed beam apparatus using high-resolution ion imaging"" Review of Scientific Instruments. (in press.).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Suzuki, et al.: "Detection of metastable triplet acetylene produced by intersystem crossing from the excited A('Au) state" J.Chem.Phys.106. 5292-5295 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Suzuki, et al.: "Detection of ArHI by (2+1) REMPI" J.Phys.Chem.A. 101. 6697-6701 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Tonokura, et al.: "C-Cl bond rupture in ultraviolet photodissociation of viryl chloride" J.Phys.Chem.A. 101. 7754-7764 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Shibata, et al.: "Dissociation of metastable CH_3CO radical ohserved by subpicosecond time-clocked imaging" J.Phys.Chem.A. (in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Katayanagi, et al.: "C-Br bond rupture in 193nm photodissociation of Vinyl Bromide" Chem.Phys.(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Mo, et al.: "Quantal and semiclassical analysis of vector correlation in molecular photodissociation" J.Chem.Phys.(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Hashimoto and T.Suzuki: "Energy and State Dependence in the quenching and predissociation of C_2H_2" Journal of Chemical Physics. 104. 6070-6073 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Mo et al.: "Simultaneous Measurement of Recoil Velocity and Alignment of S (^1D_2) Atoms in Photodissociation of OCS" Physical Review Letters. 77. 830-833 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Shibata and T.Suzuki: "Photofragment Ion Imaging with Femtosecond Laser Pulses" Chemical Physics Letters. 262. 115-119 (1996)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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