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Control of Electronic Properties of Wide Bandgap Semiconductor and Application to Energy Electronics

Research Project

Project/Area Number 09102009
Research Category

Grant-in-Aid for Specially Promoted Research

Allocation TypeSingle-year Grants
Review Section Physics
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

MATSUNAMI Hiroyuki  Kyoto University, Graduate School of Eng., Professor, 工学研究科, 教授 (50026035)

Co-Investigator(Kenkyū-buntansha) KIMOTO Tsunenobu  Kyoto University, Graduate School of Eng., Associate Professor, 工学研究科, 助教授 (80225078)
冬木 隆  奈良先端科学技術大学院大学, 物質創成科学研究科, 教授 (10165459)
吉本 昌広  京都工芸繊維大学, 工芸学部, 助教授 (20210776)
Project Period (FY) 1997 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥255,000,000 (Direct Cost: ¥255,000,000)
Fiscal Year 2000: ¥35,000,000 (Direct Cost: ¥35,000,000)
Fiscal Year 1999: ¥61,000,000 (Direct Cost: ¥61,000,000)
Fiscal Year 1998: ¥74,000,000 (Direct Cost: ¥74,000,000)
Fiscal Year 1997: ¥85,000,000 (Direct Cost: ¥85,000,000)
Keywordssilicon carbide / power device / pn diode / MOSFET / ion implantation / thermal oxidation / エピタキシャル成長 / 深い準位 / 不純物ド-ピング / フォトルミネセンス
Research Abstract

In this research project, high-quality epitaxial growth of wide bandgap SiC, control of its properties and MOS (metal-oxide-semiconductor) interfaces, and applications to high-power devices have been investigated. By using high-purity and high-quality SiC epilayers, conductivity control has been realized in the wide range from 10^<14> to 10^<20>cm^<-3>. Selective impurity doping by ion implantation has been systematically investigated. Low sheet resistances of 105Ω/□ for n-type and 3600Ω/□ for p-type were obtained. Formation of deep pn junction by MeV ion implantation and semi-insulating SiC layers formed by V ion implantation were also investigated.
Detailed characterization of MOS capacitors on n- and p-type SiC revealed clear relationship between oxidation condition and MOS interface quality. The inversion channel mobility in SiC MOSFETs may be controlled by the electron trapping and negative charge caused by shallow acceptor-like interface states. The channel mobility has been improved from 5cm^2/Vs up to 96cm^2/Vs by utilizing a novel crystal face of (1120). The channel mobility for SiC (1120) MOSFETs showed a negative temperature coefficient for the first time, which is critical for power MOSFET applications.
Various high-voltage SiC devices have been successfully fabricated. Ni/SiC Schottky diodes exhibited a 1630V breakdown voltage together with a low on-resistance of 5mΩcm^2. Epitaxial mesa and implanted planar SiC pin diodes showed very high breakdown voltages of 4200V and 4600V, respectively. The breakdown voltages of SiC pin diodes increased with increasing temperature, indicating avalanche breakdown. Lateral high-voltage (700V) SiC MOSFETs have been also demonstrated.

Report

(5 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (38 results)

All Other

All Publications (38 results)

  • [Publications] H.Matsunami: "Progress in wide bandgap semiconductor SiC for power devices"Proc.of the 12th Int.Symp.on Power Semiconductor Devices and IC's. 3-10 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "An overview of SiC growth"Materials Science Forum. 338-342. 125-130 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "Formation of periodic steps with a unit-cell height on 6H-SiC(0001) surface by HCl etching"Applied Physics Letters. 76. 3412-3414 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "High channel mobility in inversion layer of SiC MOSFETs for power switching transistors"Japanese J.Applied Physics. 39. 2008-2011 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "Vanadium ion implanted guard rings for high-voltage 4H-SiC Schottky rectifiers"Japanese J.Applled Physics. 39. L1216-L1218 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "A cause for highly-improved channel mobility of 4H-SiC MOSFETs on (1120)"Applied Physics Letters. 86. 374-376 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "Progress in wide bandgap semiconductor SiC for power devices"Proc.of the 12th Int.Symp.on Power Semiconductor Devices and IC's. 3-10 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "An overview of SiC growth"Materials Science Forum. 338-342. 125-130 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "Formation of periodic steps with a unit-cell height on 6H-SiC (0001) surface by HCl etching"Applied Physics Letters. 76. 3412-3414 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "High channel mobility in inversion layer of SiC MOSFETs for power switching transistors"Japanese J.Applied Physics. 39. 2008-2011 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsuntami: "Vantadium ion implanted guard rings for high-voltage 4H-SiC Schottky rectifiers"Japanese J.Applied Physics. 39. L1216-L1218 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "A cause for highly-improved channel mobility of 4H-SiC MOSFETs on (1120)"Applied Physics Letters. 86. 374-376 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "4H-SiC (1120) epitaxial growth"Materials Sci.Forum. 338-342. 189-192 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "Recent progress in SiC ion implantation and MOS technologies for high power devices"Ext.Abstr.of the 2000 Int.Conf.on Solid States Devices and Materials. 134-135 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsunami: "Progress in wide bandgap semiconductor SiC for power devices"Proc. of the 12th Int. Symp. on Power Semiconductor Devices and IC's. 3-10 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Matsunami: "An overview of SiC growth"Materials Science Forum. 338-342. 125-130 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Matsunami: "Formation of periodic steps with a unit-cell height on 6H-SiC (0001) surface by HCI etching"Applied Physics Letters. 76. 3412-3414 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Matsunami: "High channel mobility in inversion layer of SiC MOSFETs for power switching transistors"Japanese J.Applied Physics. 39. 2008-2011 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Matsunami: "Vanadium ion implanted guard rings for high-voltage 4H-SiC Schottky rectifiers"Japanese J.Applied Physics. 39. L1216-L1218 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Matsunami: "A cause for highly-improved channel mobility of 4H-SiC MOSFETs on (1120)"Applied Physics Letters. 86. 374-376 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] H. Matsunami: "Performance limiting surface defects in SiC epitaxial p-n junction diodes"IEEE Trans. Electron Devices. 46. 471-477 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Matsunami: "Effects of wet oxidation/anneal on interface properties of thermally oxidized SiO_2/SiC MOS system and MOSFET's"IEEE Trans. Electron Devices. 46. 504-510 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Matsunami: "High-quality epitaxial growth of SiC and state-of-the-art device development"Ext. Abstr. Solid State Devices and Materials. 144-145 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Matsunami: "High channel mobility in inversion layer of SiC MOSFETs for power switching transistors"Ext. Abstr. Solid State Devices and Materials. 372-373 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Matsunami: "High channel mobility in inversion layer of 4H-SiC MOSFET's by utilizing (1120) face"IEEE Electron Device Letters. 20. 611-613 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Matsunami: "Specular surface morphology of 4H-SiC epilayers grown on (1120) face"Jpn. J. Appl. Phys.. 38. L1315-L1318 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Matsunami: "Al^+ and B^+ implantations into 6H-SiC epilayers and application to pn junction diodes" J.Electron.Mater.27. 358-364 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Matsunami: "Conductivity control of SiC by In-situ doping and ion implantation" Materials Sci.Forum. 264-268. 675-680 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Matsunami: "Implantation of Al and B acceptors into a-SiC and pn junction diodes" Materials Sci.Forum. 264-268. 705-708 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Matsunami: "Deep states in SiO_2/P-type 4H-SiC interface" Materials Sci.Forum. 264-268. 841-844 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Matsunami: "Performance limiting surface defects in SiC epitaxial p-n junction diodes" IEEE Trans.Electron Devices. 46. 471-477 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Matsunami: "Effects of wet oxidation/anneal on interface properties of thermally oxidized SiO_2/SiC MOS system and MOSFET's" IEEE Trans.Electron Devices. 46. 504-510 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Matsunami: "Step-controlled epitaxial growth of SiC : high-quality homoepitaxy" Mater.Sci.& Eng.Review. 20. 125-166 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Matsunami: "Deep defect centers in silicon carbide monitored with deep level transient spectroscopy" phys.stat.sol.(a). 162. 199-225 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Matsunami: "Step-controlled epitaxial growth of high-quality SiC layers" phys.stat.sol.(b). 202. 247-262 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Matsunami: "Deep interface states in SiO_2/p-type α-SiC structure" Jpn.J.Appl.Phys.36. L1430-L1432 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Matsunami: "Step bunching mechanism in chemical vapor deposition of α-SiC{0001}" J.Appl.Phys.81. 3494-3500 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Matsunami: "Progress in SiC epitaxy-surface polarity dependence in step-controlled epitaxy" Diamond and Related Materials. 6. 1333-1337 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2018-03-28  

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