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Development of Selective Organic Synthesis and Catalysis Based on Characteristics of Organotransition Compounds

Research Project

Project/Area Number 09309006
Research Category

Grant-in-Aid for Scientific Research (A).

Allocation TypeSingle-year Grants
Section一般
Research Field 広領域
Research InstitutionOsaka University

Principal Investigator

TANI Kazuhide  Osaka University, Graduate School of Engineering Science, Professor, 基礎工学研究科, 教授 (60029444)

Co-Investigator(Kenkyū-buntansha) YAMAGATA Tsuneaki  Osaka University, Graduate School of Engineering Science, Research Associate, 基礎工学研究科, 助手 (70166594)
KATAOKA Yasutaka  Osaka University, Graduate School of Engineering Science, Lecturer, 基礎工学研究科, 講師 (90221879)
MASHIMA Kazushi  Osaka University, Graduate School of Engineering Science, Associate Professor, 基礎工学研究科, 助教授 (70159143)
Project Period (FY) 1997 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥31,000,000 (Direct Cost: ¥31,000,000)
Fiscal Year 2000: ¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 1999: ¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 1998: ¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 1997: ¥20,200,000 (Direct Cost: ¥20,200,000)
Keywordsiridium / rhodium / tantalum / P-N ligand / stereospecific methyl migration / C-H activation / O-H activation / MMA polymerization / ジルコニウム / ハフニウム / MMA / 重合触媒 / パーアリールホスフィン / 水素移動型 / Cp'-P配位子 / 立体特異的 / モノアザジエン / パーアリールジホスフィン配位子 / カチオン錯体 / メタノールの活性化 / キレート / 面不斉 / ジアザジエン / 極性モノマー / パ-アリールジホスフィン / バナジウム / 炭素-炭素結合切断反応 / 4級炭素化合物 / 超原子価化合物 / Tp^*
Research Abstract

With the aim of discovering new organic synthesis and catalysis based on characteristics of organotransition metal compounds we performed the research project. The following new results were obtained.
1) Neutral iridium diphosphine complexes carrying peraryldiphosphines, [IrCl (diphosphine)]_2, can activate easily O-H bonds of alcohol, water, etc to produce their oxidative addition products. The complex is an efficient catalyst for transfer hydrogenation of unsaturated compounds using methanol as a hydrogen donor.
2) Low valent vanadium(II) compounds are useful reagents for selective alkylation, allylation, C-C bond formation accompanying C-O bond cleavage of carbonyl compounds.
3) General method of preparation of complexes Tp^*MCl_nL_O {Tp^*=hydrotris (pyrazolyl) borates, M=group 4-6 transition metal} using Tp^*SnR_nCl_<3-n> (R=alkyl) as a Tp^* transfer reagent was provided
4) New optically active Cp'-P ligands, containing both an indenyl group carrying an optically active substituent and … More a diphenylphosphino group connected by an alkylene spacer, were synthesized and their stereoselective rhodium complexes regulating the panar as well as the central chirality were prepared. A theoretical catalytic cycle for selective formation of α, β-unsaturated ketones from acetylene, CO, methyl iodide and trimethyl aluminum with (Cp'-P)Rh(CO) as a catalyst was established.
5) A coordinatively flexible P-N ligand which has a diphenylphosphino group and a 2-pyridyl group connected by an oxaalkylene chain was synthesized. Direct observation of reversible oxidative addition and reductive elimination of C(sp^3)-H bonds was accomplised by using the iridium complexes of the P-N ligand.
6) A series of 1,4-diazadiene complexes of niobium and tantalum have been prepared. These complexes becom active catalysts for polymerization of MMA.By choosing ancillary ligands, 1,4-diazadiene can coordinate to a metal in several different coordination geometry, planar σ^2-, prone and supine nonplanar σ^2, π-enediamide. Tacticity and polydispersity of PMMA could be regulated. Less

Report

(5 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (99 results)

All Other

All Publications (99 results)

  • [Publications] 片岡靖隆: "Direct Construction of Quaternary Carbons from Carbonyl Compounds Utilizing Low-Valeut Vanadium Complexes"Tetrahedron. 53巻. 9525-9540 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 真島和志: "Tp^*Sn (Cl) Bu_2 as a Convenient Reagent for the Preparation of Hydrotris (3,5-dimethylpyrazolyl)borate Complexes of Niobium,Tantalum, and Zirconium"Organometallics.. 16巻. 2760-2762 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 山縣恒明: "Preparation, Properties, and Structures of [IrCl (diphosphine)]_2(diphosphine=(R)-BINAP and BPBP)"Chem.Lett. 1215-1216 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 片岡靖隆: "A NovelC-C Single Bond Formation Accompanying C-O Bond Cleavage by Use of Ketone, an Alkylating Reagent, and a Low-valent Vanadium Complex in the Presence of a Catalytic Amount of Molecular Oxygen"J.Org.Chem.. 62巻. 8109-8113 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 片岡靖隆: "Stabilizing Effect of HMPA (Hexamethylphosphoric Triamide) on Vanadium-CarbonBonds and Their Application to Carbon-Carbon Bond Formation Reactions"Organometallics. 16巻. 4788-4795 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 片岡靖隆: "Generation of Versatile Reagents Derived from R_2Zn and a Vanadium (III) or a Vanadium (IV) Complex and Their Application to Organic Synthesis"J.Org.Chem.. 24巻. 8540-8543 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 真島和志: "Theoretical stnfies of Multiple Meteal-Metal Bonds between Divalent Molybdenum Ions in Dimers, Tetramera, and Clusters"Ball.Chem.Soc.Jpn.. 71. 99-112 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 真島和志: "1,8-Diphenylocta-1,3,5,7-teiraene Complexes of Ruthenium (II) : Crystal Structures of [μ-(s-cis-1,2,3,4-η ; s-cis-5,6,7,8-ηPhCH=CHCH=CHCH=CH-CH=CHPh) (RuClCp^*)_2] and [μ-(s-trans-1,2,3,4-η : s-trans-5,6,7,8-η-PhCH=CHCH=CHCH=CHCH=CHPh) {Ru(acac)_2} _2]"Organometallics. 17. 410-414 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 真島和志: "Unique Complexation by the Tridentate Ligands, 6-Diphenylphosphino-2-pyridonate (pyphos) and 6-Diphenylphosphino-2-pyridone (pyphosl I), on Ruthenium (II) : Crystal Structures of (pyphosl I) RuCl (μ-Cl) Mo_2Cl (pyphos)_3, RuCl-(CO)(pyphosl I)_2, [Ru (pyphos)_3] (μ-Na)_2 [Ru (Ryphos)_3"Inorganica Chimica Acta (Bioinorg.Chem.). 270. 459-466 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 谷一英: "Reductive dimerization of dialkyl acetylenedicarboxylate catalyzed by [Rh (binap)-(MeOH)_2 ClO_4 in Methanol"J.Organomet.Chem.. 560. 253-255 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 真島和志: "Polymerization of methyl methacrylate catalyzed by tantalum-diene complexes,Ta(η^5-C_5R_5) (η^4-1,3-butadiene)_2 (R=H and Me), in the presence of cocatalyst AlMe(OC_6H_2-2,6-(^tBu)_2-4-Me)_2"Proc.Japan Acad.. 74,SerB. 217-220 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 片岡靖隆: "Hight Diastereoselectiv Oxidative Addition of Aikyl Halides to Rhodium and Iridium Carbonyl Complexes Having an η^5 : η^1-(Ind-P)_n Ligand((Ind-P)_nH=C_9H_7-(CH_2)PR_2 ; R=Ph, Cy ; n=2-4)"Organometallics. 17. 4338-4340 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 真島和志: "The Half-sandwich Hydride and 16-Electron Complexes of Rhodium and Iridium Containing (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine : Relevant to the Asymmetric Transfer Hydrogenation"Chem.Lett.. 1201-1202 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 谷一英: "Facile Oxidative Addition of O-H Bonds of Methanol and Water to Ir^I Complexes HavinPeraryldiphoshine Ligands : Isolation and Characterization of Hydrido (methoxo)-and Hydrido (hydroxo) complexes of Ir^<III>"Angew.Chem.Internat.Ed.Engl.. 37巻. 3381-3383 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 谷一英: "Efficient Transfer Hydrogenation of Alkynes and Alkenes with Methanol Catalysed by Hydrido (methoxo) iridium (III) Complexes"Chem.Commun.. 1821-1822 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 真島和志: "Unique Complexation of 1,4-Diaza-1,3-butadiene Ligand on Half-metallocene Fragments of Niobium and Tantalum"Organometallics. 18巻. 1471-1481 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 片岡靖隆: "Third Generation of the Cp'-P Ligand : Highly Stereoselective Control of Central Chirality Arising at a Metal Center"Organometallics. 18巻. 5423-5425 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 谷一英: "有機遷移金属錯体反応活性種の開発とその選択的有機合成への応用"生産と技術. 52巻. 39-44 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 真島和志: "1-Aza-1,3-butadiene Complexes of Tantalum : Preparation and Alkylation of TaCl_2(η^5-C_5Me_5)(η^4-1-aza-1,3-butadieue)"Journal Organometallic Chemistry. 593〜594巻. 69-76 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 片岡靖隆: "Configurationally Stable Metal-centered Chirality : Stereospecific and Regioselectiv Rhodaacylation of Alkynes Controlled by the Third Generation of the [Cp'-P] H Ligand"Chemical Communications. 841-842 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 押木俊之: "Substituent Effect on Organotin Tp^* Compounds as the Tp^* Reagent for the Preparation of Mono Tp^* Complexes of Group 4-6 Metals (Tp^*=Tris (3,5-dimethylpyrazol-1-yl) hydroborate)"Bulletin Chemical Society of Japan. 73巻. 1735-1748 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 真島和志: "Convenient Synthesis of Anionic Dinuclear Ruthenium (II) Complexes [NR_2H_2] 〔{(RuCl(diphosphine)}_2 (μ-Cl)_3〕〔diphosphine=2,2'-bis (diphenyl-phosphino)-1,1'-binaphthyl,2,2'-bis (di(p-toly) phosphino)-1,1'-binaphthyl, and 1,2-bis(diphenyl-phosphino) benzene〕 : Crystal Structure of 〔NEt_2H_2〕〔{RuCl(1,2-bis(diphenylphosphino)-benzene)}_2(μ-Cl)_3〕"Journal Organometallic Chemistry. 607巻. 51-56 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 松尾豊: "Synthesis and Characterization of Bis (iminopyrrolyt) zirconinm Complexes"Chemistry Letters. 1114-1115 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 田中光洋: "Unique Axial Interaction of a Quadruply-Bouded Cr(II)=Cr(II) with Two Pt(II) Atoms in the Linearly Aligned pt-Cr-Cr-Pt Supported by Four 6-Diphenylphosphino-2-pyridonate Ligands"Bulletin Chemical Society of Japan. 73巻. 67-75 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 片岡靖隆: "Acetonitrile Accelerated Stcrcosetective C-H Bond Activation of the Cationic Ir(I) Complex Having the PN/CH_3 Heterochelate Hyrid Ligand"Chemistry Letters. 印刷中. (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 松尾豊: "Half-Metaliocene Tantalum Complexes Bearing Methyl Methacrylate (MMA) and 1,4-Diaza-1,3-diene Ligands as MMA Polymerization Catalysts"Angewandte Chemie International Edition. 40巻. (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 谷一英: "Isomerization of Olefin and the Related Reactions"Transition Metals for Organic Synthesis : Building Blocks and Fine Chemicals ed. by M.Beller and C.Bolm, Vol 1,Chapter 2.9, pp147-157, Wiley-VCH,Weinheim,1998.. 10 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 真島和志: "Living Polymerization Catalyzed by Transition Metal Complex"Ring-opening Metathesis Polymerization Catalyzed by Tantalum Complexes (in Japanese).. 24 (1999)

    • Description
      「研究成果報告書概要(和文)」より
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      2000 Final Research Report Summary
  • [Publications] 谷一英: "廣川 有機薬科学実験講座 第2巻 創薬化学の基礎となる不斉反応"廣川書店. 18 (2000)

    • Description
      「研究成果報告書概要(和文)」より
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      2000 Final Research Report Summary
  • [Publications] 谷一英: "Catalytic Heterofunctionalization"Wiley-VCH (印刷中). (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Kataoka, I.Makihira, H.Akiyama, and K.Tani: "Direct Construction of Quaternary Carbons from Carbonyl Compounds Utilizing Low-Valent Vanadium Complexes"Tetrahedron. 53. 9525-9540 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Mashima, Y.Matsuo, and K.Tani: "Nonplanar σ^2, π-and Planar σ^2 Enediamide Coordinations of 1,4-Di(p-methoxyphenyl)-1, 4-diaza-1, 3-butadiene (=MeOC_6H_4-DAD) on Ta(η^5-C_5R_5) Fragments (R=H, Me) : Crystal Structures of TaCl_2(σ^2, π-MeOC_6H_4-dad)(η^5-C_5H_5) and Ta(σ^2-MeOC_6H_4-dad)(η^5-C_5Me_5)(η^4-1,3-butadiene)"Chem.Lett.. 767-768 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Mashima, T.Oshiki, and K.Tani: "Tp^*Sn(CI)Bu_2 as a Convenient Reagent for the Preparation of Hydrotris(3,5-dimethylpyrazolyl)borate Complexes of Niobium, Tantalum, and Zirconium"Organometallics. 16. 2760-2762 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yamagata, A.Iseki, and K.Tani: "Preparation, Properties, and Structures of [IrCl(diphosphine)]_2 (diphosphine=(R)-BINAP and BPBP)"Chem.Lett.. 1215-1216 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Kataoka, H.Akiyama, I.Makihira, and K.Tani: "A Novel C-C Single Bond Formation Accompanying C-O Bond Cleavage by Use of Ketone, an Alkylating Reagent, and a Low-valent Vanadium Complex in the Presence of a Catalytic Amount of Molecular Oxygen"J.Org.Chem.. 62. 8109-8113 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Kataoka, I.Makihira, T.Yamagata, and K.Tani: "Stabilizing Effect of HMPA (Hexamethylphosphoric Triamide) on Vanadium-Carbon Bonds and Their Application to Carbon-Carbon Bond Formation Reactions"Organometallics. 16. 4788-4795 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Kataoka, I.Makihira, M.Utsunomiya, and K.Tani: "Generation of Versatile Reagents Derived from R_2n and a Vanadium(III) or a Vanadium(IV) Complex and Their Application to Organic Synthesis"J.Org.Chem.. 24. 8540-8543 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Tani, K.Ueda, K.Arimitsu, T.Yamagata, Y.Kataoka: "Reductive Dimerization of Dialkyl Acetylenedicarboxylate Catalyzed by [Rh(binap)(MeOH)_2] ClO_4 in Methanol"J.Organomet.Chem.. 560. 253-255 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Kataoka A.Shibahara, Y.Saito, T.Yamagata, and K.Tani: "Highly Diastereoselective Oxidative Addition of Alkyl Halides to Rhodium and Iridium Carbonyl Complexes Having an η^<5 : >η^1-(Ind-P)_n Ligand ((Ind-P)_n H=C_9H_7(CH_2)PR_2 ; R=Ph, Cy ; n=2-4)"Organometallics. 17. 4338-4340 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Mashima, T.Abe, and K.Tani: "Asymmetric Transfer Hydrogenation of Ketonic Substrates Catalyzed by (η^5-C_5Me_5)MCl Complexes (M=Rh and Ir) of (1S,2S)-N-(p-Toluenesulfonyl)-1, 2-diphenylethylene-diamine"Chem.Lett.. 1199-1200 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Mashima, T.Abe, and K.Tani: "The Half-sandwich Hydride and 16-Electron Complexes of Rhodium and Iridium Containing (1S, 2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine : Relevant to the Asymmetric Transfer Hydrogenation"Chem.Lett.. 1201-1202 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Mashima, Y.Matsuo, and K.Tani: "Polymerization of Methyl Methacrylate Catalyzed by Tantalum-diene Complexes, Ta(η^5-C_5R_5)(η^4-1,3-butadiene)_2 (R=H and Me), in the Presence of Cocatalyst AlMe(OC_6H_2-2,6-(^tBu)_2-4-Me)_2"Proc.Japan Acad.. 74, Ser.B. 217-220 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Kataoka, M.Imanishi, T.Yamagata. and K.Tani: "Direct Observation of Reversible C(sp')-H Bond Activation Characterization of the Structures of Both Ir Complexes before and after C-H Bond Activation by Using a Flexible P-N Heterochelate Hybrid Ligand"Organometallics. 18. 3563-3565 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Tani, A.Iseki and T.Yamagata: "Efficient Transfer Hydrogenation of Alkynes and Alkenes with Methanol Catalysed by Hydrido(methoxo)iridium(III) Complexes"Chem.Commun.. 1821-1822 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Mashima, Y.Matsuo, and K.Tani: "Unique Complexation of 1, 4-Diaza-1, 3-butadiene Ligand on Half-metallocene Fragments of Niobium and Tantalum"Organometallics. 18. 1471-1481 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Kataoka, Y.Iwato, T.Yamagata, and K.Tani: "Third Generation of the Cp'-P Ligand : Highly Stereoselective Control of Central Chirality Arising at a Metal Center"Organometallics. 18. 5423-5425 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Mashima, Y.Matsuo, S.Nakahara, and K.Tani: "1-Aza-1, 3-butadiene Complexes of Tantalum : Preparation and Alkylation of TaCl_2(η^5- C_5 Me_5)(η^4- 1-aza-1, 3-butadiene)"Chem.. 593-594. 69-76 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Kataoka, Y.Iwato, A.Shibahara, T.Yamagata, and K, Tani: "Configurationally Stable Metal-centered Chirality : Stereospecific and Regioselective Rhodaacylation of Alkynes Controlled by the Third Generation of the [Cp'-P]H Ligand"Chem.Commun.. 841-842 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Oshiki, K.Mashima, S-i.Kawamura, K.Tani, and K.Kitaura: "Substituent Effect on Organotin Tp^* Compounds as the Tp^* Reagent for the Preparation of Mono Tp^* Complexes of Group 4-6 Metals (Tp^*= Tris (3, 5-dimethylpyrazol-1-yl)hydroborate)"Bull.Chem.Soc.Jpn.. 73. 1735-1748 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.matsuo, K.Mashima, and K.Tani: "Half-Metallocene Tantalum Complexes Bearing Methyl Methacrylate (MMA) and 1, 4-Diaza-1, 3-diene Ligands as MMA Polymerization Catalysts"Angew.Chem.Int.Ed.. 40(in press). (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 真島和志: "I-Aza-1, 3-butadiene Complexes of Tantalum : Preparation and Alkylation of TaCl_2(η^5-C_5Me_5)(η^4-1-aza-1, 3-butadiene)"Journal Organometallic Chemistry. 593〜594巻. 69-76 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 片岡靖隆: "Configurationally Stable Metal-centered Chiralitv : Stereospecific and Regioselectiv Rhodaacylation of Alkynes Controlled by the Third Generation of the [Cp'-P]H Ligand"Chemical Communications. 841-842 (2000)

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      2000 Annual Research Report
  • [Publications] 押木俊之: "Substituent Effect on Organotin Tp^* Compounds as the Tp^* Reagent for the Preparation of Mono Tp^* Complexes of Group 4-6 Metals (Tp^*=Tris (3,5-dimethylpyrazol-I-yl) hydroborate)"Bulletin Chemical Society of Japan. 73巻. 1735-1748 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 真島和志: "Convenient Synthesis of Anionic Dinuclear Ruthenium (II) Complexes [NR_2H_2][{RuCl(diphosphine)}_2(μ-Cl)_3][diphosphine=2,2'-bis (diphenyl-phosphino)-1,1'-binaphthyl,2,2'-bis (di(p-tolyl)phosphino)-1,1'-binaphthyl, and 1,2-bis(diphenyl-phosphino)benzene]: Crystal Structure of [NEt_2H_2][{RuCl(1,2-bis(diphenylphosphino)-benzene)}_2(μ-Cl)_3]"Journal Organometallic Chemistry. 607巻. 51-56 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 松尾豊: "Synthesis and Characterization of Bis (iminopyrrolyl) zirconium Complexes"Chemistry Letters. 1114-1115 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 田中光洋: "Unique Axial Interaction of a Quadruply-Bonded Cr(II)=Cr(II) with Two Pt(II) Atoms in the Linearly Aligned Pt-Cr-Cr-Pt Supported by Four 6-Diphenylphosphino-2-pyridonate Ligands"Bulletin Chemical Society of Japan. 73巻. 67-75 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] 片岡靖隆: "Acetonitrile Accelerated Stereoselective C-H Bond Activation of the Cationic Ir(I) Complex Having the PN/CH_3 Helerochelate Hybrid Ligand"Chemistry Letters. (印刷中). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] 松尾豊: "Half-Metallocene Tantalum Complexes Bearing Methyl Methacrylate (MMA) and 1,4-Diaza-1,3-diene Ligands as MMA Polymerization Catalysts"Angewandte Chemie International Edition. 40巻. (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] 谷一英: "有機遷移金属錯体反応活性種の開発とその選択的有機合成への応用"生産と技術. 52巻. 39-44 (2000)

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      2000 Annual Research Report
  • [Publications] 谷一英: "廣川 有機薬科学実験講座 第2巻 創薬化学の基礎となる不斉反応"廣川書店. 18 (2000)

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      2000 Annual Research Report
  • [Publications] 谷一英: "Catalytic Heterofunctionalization"Wiley-VCH(印刷中). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] 中山 祐正: "Polymerization of Acrylonitrile Catalyzed by Thiolate Complexes of Divalent and Trivalent Lanthanoids"Polymer International. 48巻. 502-504 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 真島 和志: "1-Aza-1,3-butadiene Complexes of Tantalum : Synthesis and Alkylation of TaCl_2(η^5-C_5Me_5)(1-aza-1,3-butadiene)"Journal of Organometallie Chemistry. 593-594巻. 69-76 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 真島 和志: "Novel synthesis of Lanthanoid Complexes starting from Metallic Lanthanoid Sources"Journal of Chemical Society, Dalton Transcation. 3899 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 真島 和志: "Catalytic Diversity of Diene Complexes of Niobium and Tantalum on Polymerizations of Ethylene, Norbornene, and Methyl Methacrylate"Macromolecular symposium. (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 片岡 靖隆: "Third Generation of the Cp'-P Ligand : Highly Stereoselective Control of Central Chirality Arising at a metal Center"Organometallies. 18巻. 5423-5425 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 谷 一英: "Activation of E-H(E=hetero atom) and C-H Bonds by Iridium Complexes and Their Application to Homogeneous Catalysis (in Japanese)"有機合成化学協会誌. 57巻. 656-666 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 片岡 靖隆: "Direct Observation of Reversible C(sp3)-H Bond Activation. Characterization of the Strauctures of Both Ir Complexes before and after C-H bond activation by Using a Flexible P-N Heterochelate Hybrid Ligand"Organometallics. 18巻. 3563-3565 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 谷 一英: "Efficient transfer hydrogenation of alkynes and alkenes with methanol catalyzed by hydrido(methoxo)iridium(III) complexes"Chemical Communications. 1821-1822 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 真島 和志: "Unique Complexation of 1,4-Diaza-1,3-butadiene Ligand on Half-metallocene Fragments of Niobium and Tantalum"Organometallics. 18巻. 1471-1481 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 真島 和志: "Organometallics Group 3-7"Organometallic Complexes of Niobium and Tantalum. (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 真島 和志: "Living Polymerization Catalyzed by Transition Metal Complex"Ring-opening Metathesis Polymerization Catalyzed by Tantalum Complexes (in Japanese). 24 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 真島和志: "Theoretical Stufies of Multiple Metal-Metal Bonds between Divalent Molybdenum lons in Dimers,Tetramera,and Clusters" Bull.Chem.Soc.Jpn.71. 99-112 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 真島和志: "1,8-Diphenylocta-1,3,5,7-tetraene Complexes of Ruthenium(II):Crystal Structures of [μ-(s-cis-1,2,3,4-η;s-cis-5,6,7,8-η-PhCH=CHCH=CHCH=CH-CH=CHPh)(RuClCp^*)_2]and[μ-(s-trans-1,2,3,4-η;s-trans-5,6,7,8-η-PhCH=CHCH=CHCH=CHCH=CHPh){Ru(acac)_2}_2]" Organometallics. 17. 410-414 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 真島和志: "Unique Complexation by the Tridentate Ligands,6-Diphenylphospino-2-pyridonate(pyphos)and 6-Diphenylphosphino-2-pyridone(pyphosH),on Ruthenium(II):Crystal structures of (pyphosH)RuCl(μ-Cl)Mo_2Cl(pyphos)_3,RuCl-(CO)(pyphosH)_2,[Ru(pyphos)_3](μ-Na)_2[Ru(Ryphos)_3" Inorganica Chimica Acta(Bioinorg.Chem.). 270. 459-466 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 谷 一英: "Reductive dimerization of dialkyl acetylenedicarboxylate catalyzed by [Ru(binap)-(MeOH)_2]ClO_4 in Methanol" J.Organomel.Chem.560. 253-255 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 真島和志: "Polymerization of methyl methacrylate catalyzed by tantalum-diene complexes,Ta(η^5-C_5R_5)(η^4-1,3-butadiene)_2(R=H and Me),in the presence of cocatalyst AlMe(OC_6H_2-2,6-(^tBu)_2-4-Me)_2" Proc.Japan Acad.74,SerB. 217-220 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 片岡靖隆: "Highl Diastereoselecitv Oxidative Addition of Alkyl Halides to Phodium and Iridium Carbonyl Complexes Having an η^5:η^1-(ind-P)_n Ligand(lnd-P)_n H=C_9H_7-(CH_2)PR_2;R=Ph,Cy;n=2-4)" Organometallics. 17. 4338-4340 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 押木都俊之: "Oxidative Addition of a Hypervalent Transannular Sulfur-Sulfur Bond to a Pd(0)Complex:Synthesis and Crystal Structures of 1,5-Dithiacyclooctanepalladium(II)Bis(trifluoromethanesulfonate)Having Phosphine Ligands" Bull.Chem.Soc.Jpn.71. 2859-2864 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 真島和志: "The First Oxidative Addition of a Hypervalent Compound to Metallic Lanthanoid: Synthesis,Characterization,and Reaction of Samarium(II)Bis(trifluoromethane-sulfonate)Derived from Metallic Samarium and 1,5-Dithiabicyclo[3.3.0]octane Bis(trifluoromethanesulfonate)" J.Org.Chem.63. 7114-7116 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 真島和志: "Asymmetric Transfer Hydrogenation of Ketonic Substrates Catalyzed by (η^5-C_5Me_5)MCl Complexes(M=Rh and Ir)of(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine" Chem.Lett.1199-1200 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 真島和志: "The Half-sandwich Hydride and 16-Electron Complexes of Rhodium and Iridium Containing(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine:Relevant to the Asymmetric Transfer Hydrogenation" Chem.Lett.1201-1202 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 谷一英: "Facile Oxidativ Addition of O-H Bonds of Methanol and Water to Ir^1 Complexes Having Peraryldiphoshine Ligands;Isolation and Characterization of Hydrido(methoxo)-and Hydrido(hydroxo)complexes of Ir^<III>" Angew.Chem.Int.Ed.37. 3381-3383 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 真島和志: "Dative Pd(0)-Mo(II)Bonds in a Linearly Aligned Tetrametal System: Preparation,Characterization,and Reaction of a Tetranuclear Pd(0)-Mo(II)-Mo(II)-Pd(0)Supported by Four 6-Diphenylphosphino-2-pyridonate Ligands" J.Am.Chem.Soc.120. 12151-12152 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 谷 一英: "Isomerization of Olefin and the Related Reactions" Transition Metals for Organic Synthesis:Building Blocks and Fine Chemicals ed.by M.Better and C.Bolm,Vol 1,Chapter 2.9,pp147-157,Wiley-VCH,Weinheim,1998., 10 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 片岡靖隆: "Unique Behavior of an(Ind-P)_n Ligand on the Substitution Reaction{η^5,η^1-(Ind-P)_n}RhCO with nBu_3P" Chem.Lett.,. 621-622 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 片岡靖隆: "Direct Construction of Ouaternary Carbons from Carbonyl Compounds Utilizing Low-Valent Vanadium Complexes"" Teterahedron,. 53. 9525-9540 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 真島和志: "Tp^*Sn(CI)Bu_3 as a Convenient Reagent for the Preparation of Hydrotris(3,5-dimethylpyrazolyl)borate Complexes of Niobium,Tantalum,and Zirconium" Organometallics. 16. 2760-2762 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 真島和志: "Synthesis and Crystal Structure of a Cationic Trinuclear Ruthenium(II)Complex,[Ru_3(μ_2-Cl)_3-(μ_3-Cl)_2{1,2-bis(diphenylphosphino)benzene}_3]PF_6"" Inorg.Chem.,. 36. 2908-2912 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 真島和志: "Nonplanar σ^2,π-and Planar σ^2-Enediamide Cpordinations of 1,4-Di(p-methoxyphenyl)-1,4-diaza-1,3-butadiene(=MeOC_6H_4-DAD)on Ta(μ^5-C_5R_5)Fragments(R=H,Me):Crystal Structures of TaCl_2-(σ^2,π-MeOC_6H_4-dad)(η^5-C_5H_5)and Ta(σ^2-MeOC_6H_4-dad)(η^5-C_5Me_5)-(η^4-1,3-butadiene)" Chem.Lett.,. 767-768 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 真島和志: "Oxdative Reaction of 1,5-Dithioniabicyclo[3.3.0]octane Bis(trifluoromethanesulfonate)with Diene Complexes of Zirconium and Tantalum:Synthesis of Cp_2Zr(OTf)_2(thf)and Cp(η^4-1,3-buta-diene)Ta(OTf)_2" Chem.Lett.,. 793-794 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 真島和志: "Chemistry of Coordinatively Unsaturated Bis(thiolato)ruthenium(II)Complexes(η^6-arene)Ru-(SAr)_2[SAr=2,6-Dimethylbenzenethiolate,2,4,6-Trisopropylbenzenethiolate;(SAr)_2=1,2-Benzene-dithiolate;Arene=Benzene,p-Cymene,Hexamethylbenzene]" Organometallics,. 16. 1016-1025 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 谷 一英: "Tetraethyl(1z,3z)-Buta-1,3-diene-1,2,3,4-tetracarboxylate" Acta Cryst,. 16. 3138-3140 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 山縣恒明: "Preparation,Properties,and Structure of[IrCl(diphosphine)]_2[diphosphine=(R)-BINAP and BPBP)" Chem.Lett.,. 1215-1216 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 片岡靖隆: "A Novel C-C Single Bond Formation Accompanying C-O Bond Cleavage by Use of Ketone,an Alkylating Reagent,and a Low-valent Vanadium Complex in the Presence of a Catalytic Amount of Molecular Oxygen" J.Org.Chem.,. 62. 8109-8113 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 片岡靖隆: "Stabilizing Effect of HMPA(Hexamethylphosphoric Triamide)on Vanadium-Carbon Bonds and Their Application to Carbon-Carbon Bond Formation Reactions" Organometallics,. 16. 4788-4795 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 片岡靖隆: "Generation of Versatile Reagents Derived from R_2Zn and a Vanadium(III)or a Vanadium(IV)Complex and Their Application to Organic Synthesis" J.Org.Chem.,. 24. 8540-8543 (1997)

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      1997 Annual Research Report
  • [Publications] 真島和志: "A 16 Electron Cyclobutadiene-benzene-1,2-dithiolate Complex of Palladium(II)Bearing a Twolegged Piano-stool Geometry:(η^4-C_4Me_2(tBu)_2)Pd(1,2-S_2C_6H_4)" Chem.Lett.,. 347-348 (1997)

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      1997 Annual Research Report
  • [Publications] 真島和志: "Ligand Exchange Reactions of a 1,3-Butadiene Complex of Magnesium" J.Organomet.Chem.,. 545-546. 549-552 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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