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Grain boundaries and deformation in two-phase TiAl alloys-Approach with bi-PST TiAl-

Research Project

Project/Area Number 09450261
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

INUI Haruyuki  KYOTO UNIVERSITY,Graduate School of Engineering, Department of Materials Science and Engineering, Associate Professor, 工学研究科, 助教授 (30213135)

Co-Investigator(Kenkyū-buntansha) ITO Kazuhiro  KYOTO UNIVERSITY,Graduate School of Engineering, Department of Materials Science, 工学研究科, 助手 (60303856)
JOHNSON Daiv  京都大学, 工学研究科, 助手 (70283645)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥10,000,000 (Direct Cost: ¥10,000,000)
Fiscal Year 1998: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1997: ¥9,500,000 (Direct Cost: ¥9,500,000)
KeywordsIntermetallic compound / TiAl Alloys / lamellar structure / grain boundary structure / high-resolution electron microscopy / strain incompatibility / tensile ductility / Yield stress
Research Abstract

Two-phase TiAl alloys, which have attracted a considerable interest in recent years, usually exhibit lamellar microstructures when produced by usual ingot-metallurgy methods. However, TiAl alloys with this type of microstructure lacks in tensile ductility, although they are superior to TiAl alloys with any other microstructures in terms of fracture toughness and high-temperature strength and this has to be solved for the wide-spread applications of TiAl alloys. The brittleness of polycrystalline lamellar TiAl alloys is considered to be due to large anisotropy in mechanical properties of each lamellar grain, In the present study, we have produced bi-PST crystals of TiAl through diffusion-bonding PST (polysynthetically twinned) crystals, in which only a single lamellar gram is contained, and investigated their deformation behavior, paying special attention to effects of strain incompatibility at a bonding interface (i.e. grain boundary). PST crystals that constitute bi-PST are those with … More orientations A_1 and B_1, whose lamellar boundaries are inclined with respect to the loading axis by 0 and 31。, respectively. These PST crystals are diffusion-bonded at 800。C so that a grain boundary of bi-PST crystals is set parallel to the loading axis. One of the constituent crystals are rotated about the loading axis by a degree theta in the range of 0-180。. Calculation of strain incompatibility at a grain boundary based on the analysis of macroscopic deformation of PST crystals with the corresponding orientations indicates that for both A_1-A_1 and B_1-B_1 bi-PST crystals, the extent of strain incompatibility is largest at the angle theta = 90。. For B_1-B_1 bi-PST crystals, values for yield stress, work-hardening rate and tensile elongation are virtually the same as those obtained for B_1-oriented PST crystals when the extent of strain incompatibility is small, whereas when the extent of incompatibility is large (with theta closer to 90。), values of yield stress and work-hardening rate are higher and values of tensile elongation are lower than those for B_1-oriented PST crystals. This clearly indicates that strain incompatibility at grain boundaries plays a decisive role in determining tensile ductility of polycrystalline two-phase TiAl alloys. In contrast, bi-PST crystals of any combinations exhibit values of yield stress, work-hardening rate and tensile elongation comparable with those for A_1-oriented PST crystals. This results from the facts that the extent of strain incompatibility for A_1-A_1 bi-PST is smaller than that for B_1-B_1 bi-PST and that the flow stress for A_1-A_1 bi-PST is high enough for additional deformation, which is needed to compensate for the incompatibility, to occur. This result is an important and encouraging one for directionally-solidification (DS) techniques in which all lamellar boundaries are aligned parallel to the growth direction. Less

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (31 results)

All Other

All Publications (31 results)

  • [Publications] H.Inui: "Deformation of Lamellar Structure in TiAl/Ti_3Al Two-Phase Alloys" Philosophical Magazine. 78. 1-28 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui: "Deformation and Fracture of PST Crystals and Directionally Solidified Ingots of TiAl-Based alloys" Intermetallics. 6. 679-683 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui: "Microstructural Control of TiAl-Mo-B Alloys by Directional Solidification" Acta Materialia. 46. 6529-6540 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui: "Deformation and Fracture of Bi-PST Crystals of TiAl" Proc.PRICM-3 on Advanced Materials and Processing. 2413-2418 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui: "Deformation and Fracture of Bi-PST Crystals of TiAl Produced by Diffusion Bonding" MRS Symp.Proc.On High-Temperature Ordered Intermetallic Alloys VIII. 552 in press. (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui: "Deformation and Fracture of Bi-PST and Tri-PST Crystals and DS Ingots of TiAl-Base Alloys" Proc.2nd Int.Symp.on Gamma Titanium Aluminides. in press. (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui et al.: "Deformation of Lamelar Structure in TiAl-Ti_3Al Two-Phase Alloys" Philosophical Magazine A. 78[1]. 1-28 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui et al.: "Crystal Growth of TiAl Alloys" Intermetallics. 6[7-8]. 647-652 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui et al.: "Deformation and Fracture of PST Crystals and Directionally Solidified Ingots of TiAl-Based Alloys" Intermetallics. 6[7-8]. 679-683 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui et al.: "Microstructural Control of TiAl-Mo-B Alloys by Directional Solidification" Acta Materialia. 46[18]. 6529-6540 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui et al.: "Interface Diffusion in Polysynthetically-Twinned TiAl" MRS Symp.Proc.Vol.481 on Phase Transformations and Systems Driven Far From Equilibrium. 53-63 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui et al.: "Processing and Microstructural Control of Directionally Solidified TiAl-Mo Alloys" Proc.PRICM 3 on Advanced Materials and Processing. 2367-2372 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui et al.: "Deformation and Fracture of Bi-PST Crystals of TiAl" Proc.PRICM 3 on Advanced Materials and Processing. 2413-2418 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui et al.: "Deformation and Fracture of Bi-PST Crystals of TiAl Produced by Diffusion Bonding" MRS Symp.Proc.on High-Temperature Ordered Intermetallic Alloys VIII. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Imui et al.: "Microstructure Control of Ti-Al-Mo-B Alloys by Directional Solidification" MRS Symp.Proc.on High-Temperature Ordered Intermetallic Alloys VIII. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui et al.: "Deformation and Fracture of Bi-PST and Tri-PST Crystals and DS Ingots of TiAl-Base Alloys" Proc.2nd Int.Symp.on Gamma Titanium Aluminides(ISGTA '99). (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui et al.: "Greep Deformation of TiAl-Si Alloys with Aligned Lamellar Microstructures" Proc.2nd Int.Symp.on Gamma Titanium Aluminides(ISGTA '99). (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui et al.: "Directional Solidification and Creep Deformation of TiAl-Si Alloys" Proc.2nd Int.Symp.on Gamma Titanium Aluminides(ISGTA '99). (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui et al.: "Microstructural Control and lamellar Stability in As-Cast TiAl as a Function of Mo and C" Proc.2nd Int.Symp.on Gamma Titanium Aluminides(ISGTA '99). (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Inui: "Deformation of Lamellar Structure in TiAl/Ti_3Al Two-Phase Alloys" Philosophical Magazine. 78・1. 1-28 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Inui: "Deformation and Fracture of PST Crystals and Directionally Solidified Ingots of TiAl-Based alloys" Intermetallics. 6・7-8. 679-683 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Inui: "Microstructural Control of TiAl-Mo-B Alloys by Directional Solidification" Acta Materialia. 46・18. 6529-6540 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Inui: "Deformation and Fracture of Bi-PST Crystals of TiAl" Proc.PRICM-3 on Advanced Materials and Processing. 2413-2418 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Inui: "Deformation and Fracture of Bi-PST Crystals of TiAl Produced by Diffusion Bonding" MRS Symp.Proc.On High-Temperature Ordered Intermetallic Alloys VIII. 552 (in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Inui: "Deformation and Fracture of Bi-PST and Tri-PST Crystals and DS Ingots of TiAl-Base Alloys" Proc.2nd Int.Symp.on Gamma Titanium Aluminides. (in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] D.R.Johnson: "Alignment of the TiAl/Ti_3Al Lamellar Microstructure in TiAl Alloys by Growth from a Seed Material" Acta Materialia. 45. 2523-2533 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Umeda: "Effects of Al-Concentration and Lamellar Spacing on the Room-Temperature Strength and Ductility of PST Crystals of TiAl" Materials Science & Engineering. A239-240. 336-343 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Kishida: "Deformation and Fracture of Bi-PST Crystals and Directionally Solidified Ingots of TiAl" Materials Research Society Symposium Proceedings on High-Temperature Ordered Intermetallic Alloys VII. 460. 53-63 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] D.R.Johnson: "Directional Solidification of TiAl-Based Alloys" Proceedings of 2nd International Symposium on Structural Intermetallics (ISSI) at Seven Springs. 287-294 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 乾 晴行: "金属間化合物TiAlの相安定性と転位芯構造" 電子顕微鏡. 32. 144-149 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Kishida: "Deformation of Lamellar Structure in TiAl/Ti_3Al Two-Phase Alloys" Philosophical Magazine. (in press). (1998)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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