Industrialization of New PTCR Materials Based on a Ceramics Matrix with a Dispersion of Bi Metal Particles as Ceramic Heaters
Grant-in-Aid for Scientific Research (B)
|Allocation Type||Single-year Grants|
|Research Institution||Tohoku University|
OKADA Masuo Graduate School of Engineering, Tohoku University, Professor, 大学院・工学研究科, 教授 (80133049)
UMEHARA Nobuo Electronics Device Division, TDK Corporation, Technical Manager, 電子デバイス事業本部・技術統括部, 第一技術部課長(研究職)
YODOGAWA Masatada Electronics Device Division, TDK Corporation, General Manager, 電子デバイス事業本部・技術統括部, 第一技術部副部長(研究職)
KAMEGAWA Atsunori Graduate School of Engineering, Tohoku University, Research Associate, 大学院・工学研究科, 助手 (90292242)
FUDA Yoshiaki 2nd Research Dept. of R&D Center, Tokin Corporation, Manager, R&Dセンター, 第2研究部担当部長(研究職)
梅原 伸男 TDK(株)電子デバイス事業本部, 技術総括部, 第一技術部課長(研究
高村 仁 東北大学, 大学院・工学研究科, 講師 (30250715)
|Project Period (FY)
1997 – 1999
Completed(Fiscal Year 1999)
|Budget Amount *help
¥13,200,000 (Direct Cost : ¥13,200,000)
Fiscal Year 1999 : ¥1,600,000 (Direct Cost : ¥1,600,000)
Fiscal Year 1998 : ¥5,100,000 (Direct Cost : ¥5,100,000)
Fiscal Year 1997 : ¥6,500,000 (Direct Cost : ¥6,500,000)
|Keywords||positive temperature coefficient of resistivity / Bi metal / Ceramics Composites / Ceramic Heater / PTCR thermistor / Hot-Pressing / Bi金属の融点 / BiSn合金 / BiSb合金 / Bi / SrBi_4Ti_4O_<15> / BaTiO_3 / TiO_2 / Al_2O_3|
A new type of PTCR materials based on a Bi metal/Ceramics composites has been developed. In this study the possibility for industrialization of the material has been investigated.
The composites based on a ceramics matrix with a dispersion of Bi metal particles showed PTCR properties at the melting point of Bi metal of about 270℃. The melting points of temperature were controlled by varying the melting points of Bi alloy particles.
The ceramics matrix such as AlィイD22ィエD2OィイD23ィエD2, SrBiィイD24ィエD2TiィイD24ィエD2OィイD215ィエD2 and TiOィイD22ィエD2 have an effect on magnitude of the PTCR properties and a room-temperature resistivity.
It was found that the sample 0.76Bi-0.24SrBiィイD24ィエD2(TiィイD20.95ィエD2NbィイD20.05ィエD2)ィイD24ィエD2OィイD215ィエD2 sintered by optimum condition (1125℃, 2h) and by decreasing the particle size of Bi metal to a few micron showed the PTCR property of about 5 orders of magnitude.
The relative density of hot-pressed composites with using fine Bi metal reached more than 99% and its resistivity of nearly 10ィイD1-1ィエD1Ωcm at room-temperature unchanged after the cyclic measurement. In addition, the magnitudes of PTCR effect reached 7 order of magnitude, and resistivity-temperature curve also remained unchanged even after 3rd measurements.
Research Output (9results)