| Project/Area Number |
09556047
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 展開研究 |
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| Research Field |
Fisheries chemistry
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| Research Institution | Yamaguchi University |
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Principal Investigator |
KAJIWARA Tadahiko Yamaguchi University, Faculty of Agriculture, Professor, 農学部, 教授 (90035121)
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| Co-Investigator(Kenkyū-buntansha) |
KAWAI Tetsuo Shiono Koryo Kaisha Ltd, Chief Researcher, 主任研究員
AKAKABE Yoshihiko Yamaguchi University, Faculty of Agriculture, Assistant Professor, 農学部, 助手 (20274186)
MATSUI Kenji Yamaguchi University, Faculty of Agriculture, Associate Professor, 農学部, 助教授 (90199729)
FUJIMURA Taichiro Shiono Koryo Kaisha Ltd, Chief Researcher, 主任研究員
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| Project Period (FY) |
1997 – 1999
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| Project Status |
Completed (Fiscal Year 1999)
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| Budget Amount *help |
¥4,800,000 (Direct Cost: ¥4,800,000)
Fiscal Year 1999: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 1998: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1997: ¥1,900,000 (Direct Cost: ¥1,900,000)
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| Keywords | Aroma components / Flavor / Marine note / Fatty acid / Long-chain aldehyde / Olfactory evaluation / Hydroperoxide / Algae / α-酸化 / 精油 / 揮発成分 / リポキシゲナーゼ / 遺伝子組み換え |
|---|
| Research Abstract |
With a part of research for development of fresh marine notes in algae, following research results were obtained. A novel heme protein, which catalyzes oxygenation of polyunsaturated fatty acids affording oxylipins in Chapter I.
Both enantiomers of neodictyoprolene and neodictyoprolenol reminiscent of algae, were successfully obtained by chemo-enzymatic syntheses, and their attractive olfactory properties were found in Chapter II.
The biosynthetic intermediates of characteristic long-chain aldehydes were identified as (2R)-hydrperoxy fatty acids in green algae in Chapter III.
The (Z)-unsaturated dienenals and trienals of CィイD217ィエD2 and CィイD216ィエD2 were stereoselectively synthesized and their olfactory evaluation showed a variety of applications in perfume industry in Chapter IV.
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