Thermophysical property measurements of polymer solutions and development of their data bases
Grant-in-Aid for Scientific Research (B)
|Allocation Type||Single-year Grants|
|Research Institution||Hiroshima University|
MASUOKA Hirokatsu Chemical Engineering, Hiroshima University, Professor, 工学部, 教授 (50034385)
ISHIKAWA Takeshi Mitsubishi Chem. Co., General Manager, 部長
SATO Yoshiyuki Chemical Engineering, Hiroshima University, Research Associate, 工学部, 助手 (50243598)
TAKISHIMA Shigeki Chemical Engineering, Hiroshima University, Associated Professor, 工学部, 助教授 (10188120)
TSUBOI Akio Mitsubishi Chem. Co., Chief Researcher, 主任研究員
|Project Period (FY)
1998 – 1999
Completed(Fiscal Year 1999)
|Budget Amount *help
¥13,300,000 (Direct Cost : ¥13,300,000)
Fiscal Year 1999 : ¥2,700,000 (Direct Cost : ¥2,700,000)
Fiscal Year 1998 : ¥10,600,000 (Direct Cost : ¥10,600,000)
|Keywords||solubility / polymer / data base / 相平衡 / 気液平衡比|
The objective of this work is measurements and data accumulation of gas solubility and gas diffusivity as well as development of prediction method and data base of these properties. Outcomes obtained in this work are shown as follows :
1. Solubilities of solute in polymer (vapor-liquid equilibria)
Investigated systems: ethylene + high impact polypropylene, propylene + high impact polypropylene, infinite dilution vapor-liquid equilibrium ratio of hexane in ethylene + high impact polypropylene, infinite dilution vapor-liquid equilibrium ratio of hexane in propylene + high impact polypropylene
The infinite dilution vapor-liquid equilibrium ratios of hexane could be predicted by Sanchez-Lacombe (S-L) equation of state in conjunction with binary interaction parameters obtained from fitting binary phase equilibrium data.
2. Liquid-liquid equilibria for polymer and solvent system
Investigated systems: hexane + polyethylene, ethylene + hexane + polyethylene
Ternary liquid-liquid equilibrium data could be predicted by S-L equation of state with binary interaction parameter.
3. PVT of polymer
Investigated systems: polylactide, poly(butylene succinate), poly(butylenes succinate-co-adipate)
PVT properties of these biodegradable polymer melts could be predicted by group contribute modified cell model equation of state.
4. Data base development for polymer solutions
The data base was developed by using the experimental data described above and literature values. This data base, which plays a part in the thermophysical property data base developed by Dr. T. Baba, National Research Laboratory of Metrology. Japan, will be appeared on the Internet.
Research Output (10results)