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The development of adsorbent of offensive odor based on polyamine intercalated layered phosphate

Research Project

Project/Area Number 10650831
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 無機工業化学
Research InstitutionKobe Pharmaceutical University

Principal Investigator

TSUHAKO Mitsutomo  Pharmacy, Kobe Pharmaceutical University, Prof., 薬学部, 教授 (60068335)

Co-Investigator(Kenkyū-buntansha) EGUCHI Taro  Graduate School of Science, Osaka University, Associate Prof., 大学院・理学研究科, 助教授 (50107083)
NAKAYAMA Hirokazu  Pharmacy, Kobe Pharmaceutical University, Associate Prof., 薬学部, 助教授 (40189080)
Project Period (FY) 1998 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1999: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1998: ¥2,700,000 (Direct Cost: ¥2,700,000)
KeywordsIntercalation / Adsorption / 吸着 / インターカレーション
Research Abstract

We found that polyamines, that is, diethylenetriamine and pentaethylenehexamine, intercalated into layered phosphates absorb considerable amount of gaseous aldehydes and carboxylic acids. The physical properties and adsorption mechanism of layered phosphates were investigated by XRD and solid-state NMR.
Carboxylic acids are I intercalated into interlayer spaces by the interaction with terminal amino groups. And the interlayer distance of intercalation compound increases by adsorption of carboxylic acids. The adsorption capabilities of them are closely related with the arrangement and conformation of polyamines in the interlayer space. Aldehyde molecule is decomposed to form methanol and formic acid by the aid of terminal amino group as catalyst. Therefore, there was no change of the interlayer distance by the adsorption of aldehyde. The differences in adsorption mechanism of carboxylic acid and aldehyde reflected in the adsorption mechanisms of carboxylic acid and aldehyde reflected in the adsorption capacities of them.

Report

(3 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] Hirokazu Nakayama: "Characterization of Polymorphic Cerium Phosphates as Studied by Solid-state High-resolution ^<31>P NMR"Phosphorus Res. Bull. 8. 89-94 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Tatsuya Asanuma: "Molecular Motion and Plastic-Phase Transition of Crystalline C_2F_6 as Studied by^<19>F NMR"Mol. Cryst. Liq. Cryst.. 326. 395-407 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hirokazu Nakayama: "Synthesis and Characterization of n-Alkylamine Intercalation Compounds of γ-Ce(H_2PO_4)(PO_4)・1.33H_2O"Phosphorus Res. Bull.. 9. 55-62 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Aki Hayashi: "Intercalation of α, ω-Alkanediamines in Layered Aluminium Dihydrogen Triphosphate Dihydrate"J. Inclusion. Phenom.. 34. 401-412 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Mayumi Danjo: "Structure and Organic Gas-adsorption Properties of Polyamine Intercalated α-Zirconium Phosphate"Bull. Chem. Soc.Jpn.. 17. 2079-2084 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Junko Nagano: "^1H and ^<129>Xe NMR Investigation of the Microporous Structure of Dealuminated H-Mordenite Probed by Methane and Xenon"Microporous nad Mesoporous Materials. 33. 249-256 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hirokazu Nakayama, et al.: "Characterization of Polymorphic Cerium Phosphates as Studied by Solid-state High-resolution ィイD131ィエD1P NMR"Phoaphorus Res.Bull.. 8. 89-98 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Aki Hayashi, et al.: "Intercalation of α,ω-Alkanediamines in Layered Aluminium Dihydrogen Triphosphate Dihydrate"J. Inclusion. Phenom.. 34. 401-412 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Tatsuya Asanuma, et al.: "Molecular Motion and Plastic-Phase Transition of Cryatalline CィイD22ィエD2FィイD26ィエD2 as Studied by ィイD119ィエD1F NMR"Mol. Cryst. Loq. Cryst.. 326. 395-407 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hirokazu Nakayama, et al.: "Synthesis and Characterization of n-Alkylamine Intercalation Compounds of ィイD2γィエD2-Ce(HィイD22ィエD2POィイD24ィエD2)(POィイD24ィエD2)・1.33HィイD22ィエD2O"Phosphorus Res. Bull.. 9. 55-62 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Mayumi Danjo, et al.: "Structure and Organic Gas-adsorption Properties of Polyamine Intercalated ィイD2αィエD2-Zirconium Phosphate"Bull. Chem. Soc. Jpn.. 17. 2079-2084 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Junko Nagano, et al.: "ィイD11ィエD1H and ィイD129ィエD1Xe NMR Investigation of the Microporous Structure of Dealuminationed H-Mordenite Probed by Methane and Xenon"Microporous and Mesoporous Materials. 33. 249-256 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] J.V.Barkley: "Solid State Studies (X-ray and ^1H-,^<13>C-NMR) on (Nme_4)_<4-x>[H_xNi_<12>(CO)_<21>]・S(x=1,S=Me_2CO;x=2,S=2THF)"J.Organometal.Chem.. 573. 254-260 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Tatsuya Asanuma: "Molecular Motion and Plastic-Phase Transition of Crystalline C_2F_6 as Studied by ^<19>F NMR"Mol.Cryst.Liq.Cryst.. 326. 395-407 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Hirokazu Nakayama: "Synthesis and Characterization of n-Alkylamine Intercalation Compounds of γ-Ce(H_2PO_4)(PO_4)・1.33H_2O"Phosphorus Res.Bull.. 9. 55-62 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Aki Hayashi: "Intercalation of α,ω-Alkanediamines in Layered Aluminium Dihydrogen Triphosphate Dihydrate"J.Inclusion.Phenom.. 34. 401-412 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Mayumi Danjo: "Structure and Organic Gas-adsorption Properties of Polyamine Intercalated α-Zirconium Phosphate"Bull.Chem.Soc.Jpn.. 17. 2079-2084 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Junko Nagano: "Intercalation of α,ω-Alkanediamines in Layered aluminium Dihydrogen Triphosphate Dihydrate"Microporous and Mesoporous Materials. 33. 249-256 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Hideko Inoue: "Selective Synthesis of β-D-Glucopyranosyl 1-Triphosphate by Reaction of D-Glucopyranose with Inorganic cyclo-Triphosphate" Chem.Pharm.Bull.46. 681-683 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hirokazu Nakayama: "Characterization of Polymorphic Cerium Phosphates as Studied by Solid-state High-resolution ^<31>P NMR" J.Materials Chem.8. 89-94 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] R.A.Harding: "H-motion of H_4Ru_4(CO)_<12-X>L_X(X=0,1;L=P(OMe)_3)from Solid State NMR Studies" Polyhedron. 17. 2857-2863 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hironobu Tada: "Dynamic Properties and Phase Transitions in A_3ZnBr_4(A=(CH_3)_4N,and (CH_3)_4P)as Studied by ^<79>Br NQR and Multinuclear NMR" Z.Naturforsch.(a),. 53. 459-465 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Tatsuya Asanuma: "^<19>F NMR Study on C_nF_<2n+2>(n=1 and 2)Adsorbed in Na-Mordenite:Dynamic Behaviour and Host-guest Interaction" J.Chem.Soc,Faraday Trans.17. 3521-3526 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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