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ESTABLISHMENT OF BIOMASS CONVERSION INDUSTRY IN HOKKAIDO

Research Project

Project/Area Number 11793013
Research Category

Grant-in-Aid for University and Society Collaboration

Allocation TypeSingle-year Grants
Research Field 林産学
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

SANO Yoshihiro  Hokkaido Univ. Grad. School of Agr., Prof., 大学院・農学研究科, 教授 (10001463)

Co-Investigator(Kenkyū-buntansha) TABARA Masayoshi  Hokkaido Univ. Grad, School of Eng., Asso. Prof., 大学院・工学研究科, 助教授 (50091476)
URAKI Yasumitu  Hokkaido Univ. Grad. School of Agr., Asso. Prof., 大学院・農学研究科, 助教授 (90193961)
SHINOHARA Kunio  Hokkaido Univ. Grad. School of Eng., Prof., 大学院・工学研究科, 教授 (60001294)
KISHIMOTO Takao  Hokkaido Univ. Grad. School of Agr., Inst., 大学院・農学研究科, 助手 (60312394)
久保 智史  北海道大学, 大学院・農学研究科, 学振研究員
Project Period (FY) 1999 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥8,100,000 (Direct Cost: ¥8,100,000)
Fiscal Year 2001: ¥8,100,000 (Direct Cost: ¥8,100,000)
KeywordsBIOMASS / BIRCH / STRAWS / BIOMASS REFNERY METHOD / CELLUOLSE / LIGNIN / HEMICELLULOSE / BETULIN / グリーンケミカルズ / バイオマス変換産業 / 酢酸分離システム / 製紙・溶解・糖化用セルロース / 酢酸リグニン / 糖類 / スベリン / シラカバ / 常圧酢酸成分分離プロセス / 製紙・溶解・糖化用パルプ / 単糖類
Research Abstract

There are a large quantity of birch tree fast-growing in a cold district, and also poor-grade biomass materials such as thinning and agricultural wastes in Hokkaido, but they have been utilized less effective use or discarded. We carried out a fundamental investigation to establish a novel biomass-conversion mill in Hokkaido to convert their biomass materials to green chemicals, fine chemicals, biodegradation plastics, bioenergy and so forth.
We established two biomass refinery processes with non-pollution and save-energy. One is an atmospheric acetic acid method and another HBS method. Birch wood and other biomas materials were easily fractionated into cellulose, lignin and/or hemicellulose in almost quantitative yields. The resulting cellulose had excellent properties for paper and dissolving pulps, and biochemicals. Hemicellulose obtained as monosaccharides from the former can be used for biochemicals and food additives. Lignin can be utilized for biofuel with clean and high calorific value, and functional biopolymers (epoxide, phenol-resorcinol and maybe polyurethane resins), molding active carbons and so forth.
Betulin was extracted with acetic acid and other solvents in a yield of 30% from outer bark of birch. Betulin appears to be used as raw materials for fine chemicals, biodegradation polymers, and medicine such as anti-HIZ agents.

Report

(4 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (39 results)

All Other

All Publications (39 results)

  • [Publications] Uraki, Y.: "Preparation of amphiphilic lignin derivatives as a cellulase stabilizer"Journal of Wood Science. 47. 301-307 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Kishimoto T.: "Delignification Mechanism during High-Boiling Solvent Pulping. Part 1. Reaction of Guaiacylglycerol-β-Guaiacyl ether"Holzforshung. 52. 611-616 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Uraki, Y.: "Preparation of activated carbon fibers from large specific surface area from softwood acetic acid lignin"Journal of Wood Science. 47. 465-469 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 浦木康光: "古紙を含有する酢酸リグニンの連続成形と成形活性炭への変換"日本木材学会北海道支部講演集. 33. 17-20 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 三春洋介: "ポリウレタン繊維に吸湿性を付与するセルロース系ポリマーブレンド"日本木材学会北海道支部講演集. 33. 21-24 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 佐野嘉拓: "リグニンの工業的利用法"機能材料. 12. 41-52 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] X-J. Pan: "Atmospheric acetic acid pulping of rice straw II : Behavior of ash and silica in rice straw during atmospheric acetic acid pulping and bleaching"Holzforschung. 53. 49-55 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Uraki: "Polyhydric alcohol pulping at atmospheric pressure : An effective method for organosolv pulping of softwoods"Holzforschung. 53. 411-415 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] X-J. Pan: "Atmospheric acetic acid pulping of rice straw IV : Physico-chemical characterization of acetic acid lignins from rice straw and woods. Part 1. Physical characteristics"Holzforschung. 53. 511-518 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] X-J. Pan: "Atmospheric acetic acid pulping of rice straw IV : Physico-chemical characterization of acetic acid lignins from rice straw and woods. Part 2. Chemical structures"Holzforschung. 53. 590-596 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] X-J. Pan: "Acetic acid pulping of wheat straw under atmospheric pressure"J. Wood Sci.. 45. 319-325 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] X-J. Pan: "Comparison of acetic acid lignin with milled wood and alkaline lignins from wheat straw"Holzforschung. 54. 61-65 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Uraki: "Activated carbon sheet prepared from softwood acetic acid lignin"J. Wood Sci.. 46. 52-58 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] J. Kajimoto: "HBS pulping (1) -Pulping of softwood"J. Tappi. 54. 1252-1259 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Wahyu Eko Widodo: "HBS pulping (2)- Pulping of hardwood and nonwood"J. Tappi. 54. 1394-1402 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H. Yamamoto: "Gel formation of lignin and biodegradation of the lignin gels by microorganisms"Mat. Sci. Eng.. C7. 143-147 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Uraki: "Preparation and Characterization of Alginate-blended Rayon"Sen-i Gakkaishi. 56. 482-486 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Shimamoto: "Optical properties and photopolymerization of liquid crystalline (acetyl) (ethyl) cellulose/acrylic acid system"Cellulose. 7. 347-358 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] J. Kajimoto: "HBS pulping (3) - Accelerated delignification of sugars"J. Tappi. 55. 1470-1479 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Uraki, A. Nakatani, S. Kubo and Y. Sano.: "Preparation of activated carbon fibers with large specific surface area from softwood acetic acid lignin"J. Wood Sci.. 47. 465-469 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Uraki, Y.: "Preparation of amphiphilic lignin derivatives as a cellulase stabilizer"Journal of Wood Science. 47. 301-307 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Kishimoto T.: "Delignification Mechanism during High-Boiling Solvent Pulping. Part 1. Reaction of Guaiacylglycerol-β-Guaiacyl ether"Holzforshung. 52. 611-616 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Uraki, Y.: "Preparation of activated carbon fibers from large specific surface area from softwood acetic acid lignin"Journal of Wood Science. 47. 465-469 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 浦木康光: "古紙を含有する酢酸リグニンの連続成形と成形活性炭への変換"日本木材学会北海道支部講演集. 33. 17-20 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 三春洋介: "ポリウレタン繊維に吸湿性を付与するセルロース系ポリマーブレンド"日本木材学会北海道支部講演集. 33. 21-24 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 佐野嘉拓: "リグニンの工業的利用法"機能材料. 12. 41-52 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Pan,X.-J.: "Comparison of Acetic Acid Lignin with Milled Wood and Alkaline Lignins from Wheat Straw"Holzforshung. 54・1. 61-65 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Yamamoto H.: "Gel formation of lignin and biodegradation of the lignin gels by microorganisms"Materials Science and Engineering. C7. 143-147 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Uraki,Y.: "Activated carbon sheet prepared from softwood acetic acid Lignin"J Wood Sci. 46・1. 52-58 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Uraki,Y.: "Preparation and characterization of Alginate-blended Rayon"SEN'I GAKKAISHI. 56・10. 482-486 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Uraki,Y.: "Self-Assembly of Pulp Derivatives as Amphiphilic Compounds : Verification of Molecular Association and Complexation with Low and High Molecular Mass Compounds"Holzforshung. 54・5. 535-540 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 飯塚尭介: "ウッドケミカルスの最新技術-バイオマスの成分分離技術"(株)シーエムシー. 309 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Eds.David N.-S.Hon: "Chmisry of Lignin.In Wood and Cellulosic Chemistry"Marcel Dekker, Inc.. 914 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Pan Xue-Jun: "Atomospheric Acetic Acid Pulping of Rice Straw II"Holzforshung. 53. 49-55 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 佐野嘉拓: "自然と調和する次世代の木材化学産業(上)"ウッディエイジ. 48・1. 2A-7A (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 佐野嘉拓: "自然と調和する次世代の木材化学産業(下)"ウッディエイジ. 48・2. 1A-6A (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Pan X.-J: "Atomospheric Acetic Acid Pulping of Rice Straw IV"Holzforshung. 53. 511-518 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Pan X.-J: "Acetic acid pulping of wheat straw under atmospheric pressure"J. Wood Sci.. 45・4. 319-326 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Pan X.-J.: "Atomoshperic Acetic Acid Pulping of Rice Straw IV"Holzforshung. 53. 590-596 (1999)

    • Related Report
      1999 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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