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Novel Smart Membrane with Controlled Molecular Cavity

Research Project

Project/Area Number 13133101
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionNagoya Institute of Technology

Principal Investigator

TSUJITA Yoshiharu  Nagoya Institute of Technology, Graduate School of Engineering, Professor, 大学院工学研究科, 教授 (70016591)

Co-Investigator(Kenkyū-buntansha) SANUI Kohei  Sophia University, Department of Chemistry, Professor, 理工学部, 教授 (30053664)
ANDO Isao  Tokyo Institute of Technology, Department of Chemistry and Materials Science, Professor, 大学院・理工学研究科, 教授 (20016637)
FUKUDA Mitsuhiro  Hyogo University of Teacher Education, Textile Materials Science Laboratory, Professor, 学校教育学部, 教授 (40183587)
吉水 広明  名古屋工業大学, 大学院・工学研究科, 助教授 (10240350)
猪股 克弘  名古屋工業大学, 大学院・工学研究科, 助教授 (80232578)
岡本 茂  名古屋工業大学, 大学院・工学研究科, 助教授 (50262944)
梶山 千里  九州大学, 総長 (60037976)
白井 汪芳  信州大学, 繊維学部, 教授 (80021153)
岡本 佳男  名古屋工業大学, 大学院・工学研究科, 教授 (60029501)
Project Period (FY) 2001 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥28,400,000 (Direct Cost: ¥28,400,000)
Fiscal Year 2005: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2004: ¥8,800,000 (Direct Cost: ¥8,800,000)
Fiscal Year 2003: ¥8,800,000 (Direct Cost: ¥8,800,000)
Fiscal Year 2002: ¥4,100,000 (Direct Cost: ¥4,100,000)
Fiscal Year 2001: ¥5,200,000 (Direct Cost: ¥5,200,000)
KeywordsSmart membrane / Molecular cavity / Permselectivity / Separation properties / Prediction of function / Characterization / Polymeric separation membranes / 分離機構 / 膜分離 / 分子認識 / 光学分割 / 磁場勾配NMR法 / MD計算 / 異性体分離 / メゾフェイズ膜
Research Abstract

The research project, grant-in-aid for scientific research on priority area entitled as "Novel Smart Membrane with Controlled Molecular Cavity" was started at autumn in 2001 with 16 investigators, via the some preparative research committees on the intelligent fibers and membranes for about 2 years. This project was promoted with relatively few investigators, but very good communications and cooperative research planning among them were considerably active, and then, the mission of this project could be completed. According to the objects which were how to make, characterize, predict by computer simulations, and estimate the well-designed "molecular cavity" in polymeric membranes, this project research was organized with 4 Groups as follows;
Group A : "Creation of Novel Smart Membranes",
Group B : "Characterization of Smart Membranes",
Group C : "Molecular Design and Prediction of Functions of Smart Membranes by Simulations",
Group D : "Estimations of Separation Properties of Smart Membranes".
Small meetings between groups were held many times. Especially, the research results of Group C introduced the some new research plan of other groups. This project leads the important and novel concepts on not only the membrane separation technology but also polymer science, physical chemistry, and chemical engineering. It is easily believed that reliable methods of creating the well-designed "molecular cavity" having polymeric membranes were established by this project. In addition, the publication of special issue on "Smart Membranes and Molecular cavity" of the Journal of Molecular Structure, volume 739, 2005, by Elsevier was performed with cooperative contributions of all investigators of this project.

Report

(6 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (33 results)

All 2005 2004 Other

All Journal Article (13 results) Book (2 results) Publications (18 results)

  • [Journal Article] Smart membrane, Preparation of molecular cavity and preferential sorption of small molecule2005

    • Author(s)
      Y.Tsujita, H.Yoshimizu, S.Okamoto
    • Journal Title

      Journal of Molecular Structure 739(1-3)

      Pages: 3-12

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Sorption of Organic Solvents on the Surface of Crystalline Syndiotactic Polystyrene Studied by Molecular Dynamics Simulation2005

    • Author(s)
      Y.Tamai, M.Fukuda
    • Journal Title

      Journal of Molecular Structure 739(1-3)

      Pages: 27-32

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Diffusion process of methane molecules in cylindrical channel cavities of oriented polyester with long n-alkyl side chains as studied by field-gradient ^1H NMR spectroscopy2005

    • Author(s)
      M.Matsui, Y.Yamane, S.Kuroki, I.Ando, K.Fu, J.Watanabe
    • Journal Title

      Journal of Molecular Structure 739(1-3)

      Pages: 131-136

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Proton conductivity of smart membranes based on hydrocarbon polymers having phosphoric acid groups2005

    • Author(s)
      M.Rikukawa, D.Inagaki, K.Kaneko, Y.Takeoka, I.Ito, Y.Kanzaki, K.Sanui
    • Journal Title

      Journal of Molecular Structure 739(1-3)

      Pages: 153-161

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Diffusion process of methane molecules in cylindrical channel cavities of oriented polyester with long n-alkyl side chains as studied by field-gradient 1H NMR spectroscopy2005

    • Author(s)
      M.Matsui, Y.Yamane, S.Kuroki, I.Ando, K.Fu, J.Watanabe
    • Journal Title

      Journal of Molecular Structure 739(1-3)

      Pages: 131-136

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Cross-linked Smart Polydimethylsiloxane Membranes for Removal of Volatile Organic Compounds from Water2005

    • Author(s)
      T.Ohshima, T.Miyata, T.Uragami
    • Journal Title

      Journal of Molecular Structure 739(1-3)

      Pages: 47-55

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Structural Study on Rodlike Aromatic Polyimides Derived by Solid-state Thermal and chemical imidization of poly(amic n-dodecyl ester)2005

    • Author(s)
      K.Inomata, Y.Ozeki, S.Shimomura, Y.Sakamoto, E.Nakanishi
    • Journal Title

      Journal of Molecular Structure 739(1-3)

      Pages: 117-123

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Intercalated Formation of Two-dimensional and Multi-layered Perovskites in Organic Thin Films2005

    • Author(s)
      Y.Takeoka, M.Fukasawa, T.Matsui, K.Kikuchi, M.Rikukawa, K.Sanui
    • Journal Title

      Chemical Communications

      Pages: 378-380

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Preparation and Characterization of Highly Oriented Poly(γ-benzyl L-glutamate) Networks and Gels with Long Channels with Micrometer-Scale Diameters2004

    • Author(s)
      Y.Yamane, M.Kanekiyo, S.Koizumi, C.Zhao, S.Kuroki, I.Ando
    • Journal Title

      Journal of Applied Polymer Science 92巻

      Pages: 1053-1060

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Effect of Enhanced Aromatic Guests on the Shape and Connectivity of Molecular Cavity in Crystalline Polystyrene Evaluated by Molecular Simulations2004

    • Author(s)
      Y.Tamai, M.Fukuda
    • Journal Title

      The Journal of Chemical Physics 121巻・23号

      Pages: 12085-12093

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Molecular Design of a Novel Ring Polyimide with Nanoscale Cavity Using DFT Calculations2004

    • Author(s)
      M.Fukuda, Y.Takao, Y.Tamai
    • Journal Title

      Transactions of the Materials Research Society of Japan 29巻・8号

      Pages: 3703-3706

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Structure and Properties of the Mesophase of Syndiotactic Polystyrene.VIII. Solvent Sorption Behavior of Syndiotactic Polystyrene/p-Chlorotoluene Mesophase Membranes2004

    • Author(s)
      K.P.O.Mahesh, M.Sivakumar, Y.Yamamoto, Y.Tsujita, H.Yoshimizu, S.Okamoto
    • Journal Title

      Journal of Polymer Science : part B : Polymer Physics 42巻

      Pages: 3439-3446

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 水中に溶存するVCOsを選択的に除去する高分子膜の構造設計2004

    • Author(s)
      浦上 忠
    • Journal Title

      繊維学会誌 60巻・12号

    • Related Report
      2004 Annual Research Report
  • [Book] 最先端の機能膜技術-未来の膜技術を展望する-2005

    • Author(s)
      樋口亜紺(分担執筆)
    • Total Pages
      241
    • Publisher
      シーエムシー出版
    • Related Report
      2005 Annual Research Report
  • [Book] 高分子ゲルの最新動向,第13章 NMR(監修:柴山充弘, 梶原莞爾)2004

    • Author(s)
      安藤勲, 黒木重樹, 兼清真人, 小泉聡, 山根祐治, 上口憲陽
    • Total Pages
      342
    • Publisher
      シーエムシー出版
    • Related Report
      2004 Annual Research Report
  • [Publications] A.Higuchi, Y.Higuchi, K.Furuta, B.-O.Yoon, M.Hara, S.Maniwa, M.Saitoh, K.Sanui: "Chiral separation of phenylalanine by ultrafiltration through immobilized DNA membranes"J.Membrane Sci.. Vol.221. 207-218 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Kim, H.Kimura, S.Kuroki, I.Ando: "A Study of Diffusion Behavior of n-Paraffin in Urea/n-Paraffin Adduct by High Field-Gradient ^1H NMR Spectroscopy"Chem.Phys.Lett.. Vol.376. 581-585 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Imase, A.Ohira, K.Okoshi, N.Sano, S.Kawauchi, J.Watanabe, M.Kunitake: "AFM Study of Tow-Dimensional Epitaxial Arrays of Poly(γ-_L-gulutamate) with Long n-Alkyl Side Chains on Graphite"Macromolecules. Vol.36,No.6. 1865-1869 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Fukuda, Y.Tamai: "Nanoscale Cylindrical Cavity Formed by Stacking Ring Polyimide Molecules : A Molecular Dynamics Simulation"ITE Letters. Vol.4. 456-460 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Saitoh, D.Amutharani, Y.Yamamoto, Y.Tsujita, H.Yoshimizu, S.Okamoto: "Structure and Properties of the Mesophase of Syndiotactic Polystyrene IV. Release of Guest Molecules from δ-Form of Syndiotactic Polystyrene by Time Resolved FT-IR and WAXD Measurement"Polymer.J.. Vol.35,No.11. 868-871 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Uragami, T.Meotoiwa, T.Miyata: "Effect of Morphology of Multicomponent Polymer Membranes Containing Calixarene on Permselective Removal of Benzene from a Dilute Aqueous Solution of Benzene"Macromolecules. Vol.36,No.25. 9430-9436 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] B.O.Yoon, T.Asano, M.Hara, A.Higuchi: "Removal of endocrine disruptors by selective sorption method using polydimethylsiloxane membranes"J. Membrane Sci.. 213. 137-144 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Kanekiyo, M.Kobayashi, I.Ando, H.Kurosu, S.Amiya: "A study of solvent exchange process in (ethylene-vinyl alcohol) copolymer gels by a proton nuclear magnetic resonance spectroscopy imaging method"J.Appl.Polym.Sci.. 86. 504-508 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] J.Thisayukta, H.Niwano, H.Takezoe, J.Watanabe: "Enhancement of Twisting power of chiral nematic phase by an introduction of achiral banana-shaped molecules"J.Am.Chem.Soc.. 124. 3354-3358 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Uragami, K.Okazaki, H.Matsugi, T.Miyata: "Structure and permeation characteristics of an aqueous ethanol solution of organic-inorganic hybrid membranes composed of poly(vinyl alcohol) and tetraethoxysilane"Macromolecules. 35. 9156-9163 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Suzuki, T.Tanaka, M.Nakajima, H.Yoshimizu, Y.Tsujita: "Characterization of the cavity in poly(4-methyl-1-pentene) crystal by gas permeation and ^<129>Xe NMR measurements"Polym.J.. 34. 891-896 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] D.Amutha Rani, Y.Yamamoto, S.Mohri, M.Sivakumar, Y.Tsujita, H.Yoshimizu: "Structure and properties of the mesophase of syndiotactic polystyrene. II. Effect of stepwise extraction on the preparation of the mesophase"J.Polym.Sci. Part B : Polym Phys.. 41. 269-273 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.Takeoka, K Asai, M.Rikukawa, K sanui: "Incorporaion of Conjugated Polydiacetylene Systems into Organic-inorganic Quantum-well Structures"Chem. Commun.. 2592-2593 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] A.Higuchi, B.O.Yoon, T.Asano, K.Nakagawa, S.Miki, M.Hara, Z.He, I.Pinnau: "Separation of Endocrine Disruptors from Aqueous Solutions by Pervaporation"J. Membrane Science. 198. 311-320 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Hotta, I.Ando: "A Study or shrinkage process or polymer gel under electric field1 ^1H NMR imaging method using an NMR cell with thin platinum electrodes"J. Molecular Structure. 602-603. 165-170 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Yin, C.Zhao, S.Kuroki, I.Ando: "Diffusion of rodlike polypeptides with different main-chain length in the themotropic liquid crystalline state as studied by the field-gradient ^1H NMR method"Macuromolecules. 35. 2335-2338 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Uragami, H.Yamada, T.Miyata: "Removal or dilute volatile organic compounds in water through graft copolymer membranes consisting of poly(alkymenthacrylate) and poly(dimethylsiloxane) by pervaporation and their membrane morphology"J. Membrane Science. 187. 255-269 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Sivakumar, Y.Yamamoto, D.Amuthrani, Y.Tsujita, H.Yoshimizu, T.Kinoshita: "Study on d-form Complex in Syndiotactic Polystyrene-Organic Molecules System : I.Preferential Complexation of Xylene Isomers"Macromol. Rapid. Commun.. 23. 77-79 (2002)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2018-03-28  

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