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Construction of Transition Metal Chalcogenide Clusters and Their Functions

Research Project

Project/Area Number 13304052
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionNagoya University

Principal Investigator

TATSUMI Kazuyuki  Nagoya University, Research Center for Materials Science, Professor, 物質科学国際研究センター, 教授 (10155096)

Co-Investigator(Kenkyū-buntansha) OHKI Yasuhiro  Nagoya University, Graduate School of Science, Research Assistant, 大学院・理学研究科, 助手 (10324394)
MATSUMOTO Tsuyoshi  Nagoya University, Graduate School of Science, Research Assistant, 大学院・理学研究科, 助手 (50311717)
久家 克明  名古屋大学, 物質科学国際研究センター, 講師(研究機関研究員)
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥53,300,000 (Direct Cost: ¥41,000,000、Indirect Cost: ¥12,300,000)
Fiscal Year 2003: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
Fiscal Year 2002: ¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2001: ¥21,450,000 (Direct Cost: ¥16,500,000、Indirect Cost: ¥4,950,000)
KeywordsTransition Metal Thiolato Complex / Transition Metal Sulfido Complex / Transition Metal Thiallyl Complex / Alkynethiolate / Diynethiolate / Inorganic Polymer / Activation of Hydrogen Molecule / Metal Cluster / クラスター / チオラート / シリルチオラート / シリル-硫黄結合切断 / 鉄 / 銅 / チタン / モリブデン / カルコゲン / イオウ / ゲルマニウム / ルテニウム / ニッケル
Research Abstract

During this research project, we have made substantial progress in many phases of research items, viz,
1. We have synthesized a novel rhenium selenido cluster, of [Cp^*Re(Se_3)(μ-Se_2)]_8, having a octa-nuclear diamond-crown shape of [Re(μ-Se_2)]_8 24-membered macrocyclic core, from the reaction of Cp^*ReCl_4 with 2-3 equiv of Li_2Se_5. On the other hand, the analogous reaction between Cp^*ReCl_4 and 2 equiv of Li_2Te_5 gave rise to a trinuclear cluster of a birdcage shape, Cp^*3Re_3Te_8.
2. A series of alkynethiolato complexes, alkyneselenolato complexes, diynethiolato complexes have been synthesized. These thiolate ligands are unique in that they carry unsaturated C-C bonds as substituents, and have shown interesting reactivity at various transition metal centers. For instance, we found unusual C-C coupling reactions, cyclic dimerizatino/trimerization of the functional carbon sites, C-S bond cleavage occurring at the thiolate ligands.
3. Thiolate-type sulfur is coordinated at transition … More metal centers relatively strongly, while thioether-type sulfur forms weak M-S bonds, often exhibiting facile dissociation equilibration. We have utilized the mixed ligands RSCH_2CH_2S(-) (R=Et (etet), R=^iPr (^1ptet), R=Ph (ptet)) for assemblage of iron(II) and Ni(II) metal atoms. For instance, the 1:2 NiCl_2/Li(etet) reaction system gave rise to a linear polymer [Ni(etet)_2]_n, while the analogous 1:2 NiCl_2/Li(ptet) reaction resulted in formation of a cyclic hexamer [Ni_6(ptet)_<12>]. An interesting feature of these 1-dimensional polymers of Ni and Fe is that they can be dissolved in toluene by virtue of coordination of thioether-type sulfur atoms, and that the polymer structures are regenerated upon recrystallization.
4. A series of sulfido-bridged tungsten-ruthenium dinuclear complexes Cp^*W(μ-S)_3RuX(PPh_3)_2, Cp^*W(O) (μ-S)_2RuX(PPh_3)_2, and Cp^*W(NPh) (μ-S)_2RuX(PPh_3)_2 have been synthesized. The heterolytic cleavage of H_2 was found to proceed at room temperature upon treating Cp^*W(O) (μ-S)_2RuX(PPh_3)_2 and Cp^*W(NPh)(μ-S)_2RuX(PPh_3)_2 with NaBArF_4 under atmospheric pressure of H_2, which gave rise to [Cp^*W(OH)(μ-S)_2RuH(PPh_3)_2](BarF_4) and [Cp^*W(NHPh)(μ-S)_2RuH(PPh_3)_2](BarF_4), respectively. The mechanism of the heterolytic H_2 activation and the reverse H_2 evolution reactions have been investigated. Less

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (99 results)

All Other

All Publications (99 results)

  • [Publications] Ohki, Y., Tatsumi, K., et al.: "Heterolytic Cleavage of Dihydrogen Promoted by Sulfido-Bridged Tungsten-Ruthenium Dinuclear Complexes"J.Am.Chem.Soc.. 125. 7978-7988 (2003)

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  • [Publications] Ohki, Y., Tatsumi, K., et al.: "Synthesis of the P-Cluster Inorganic Core of Nitrogenases"J.Am.Chem.Soc.. 125. 4052-4053 (2003)

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      2003 Final Research Report Summary
  • [Publications] Komuro, T., Tatsumi, K., et al.: "Unusual Coordination Modes of Arylthiolates in Mo{η^5-SC_6H_3-2,6-(SiMe_3)_2}{η^7-SC_6H_3-2,6-(SiMe_3)_2"J.Am.Chem.Soc.. 125. 2070-2071 (2003)

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      2003 Final Research Report Summary
  • [Publications] Komuro, T., Tatsumi, K., et al.: "Synthesis and Characterization of Ti(IV) and Ti(III) Complexes with (2-Dimethyl-phosphino)ethane-1-thiolate and (3-Dimethylphosphino) propane-1-thiolate as Ligands"Angew.Chem.Int.Ed.. 41. 465-468 (2003)

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      2003 Final Research Report Summary
  • [Publications] Komuro, T., Tatsumi, K., et al.: "Coordination Chemistry of Silanedithiolato Ligands Derived from Cyclotrisilathiane : Synthesis and Structures of Complexes of Iron(II),Cobalt(II) Copper(I),and Silver(I)"Inorg.Chem.. 42. 5340-5347 (2003)

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      「研究成果報告書概要(和文)」より
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      2003 Final Research Report Summary
  • [Publications] G.-X.Jin, Y Arikawa, K.Tatsumi: "Spontaneous Formation of a Diamond-crown Structure of Re_8 Polyselenide and a Cage Structure of Re_3 Polytelluride"J.Am.Chem.Soc.. 123. 735-736 (2001)

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      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Kawaguchi, K.Tatsumi: "Synthesis of a Pentamethylcyclopentadienyl Complex of Tungsten with Three Different Chalcogenido (O^<2->,S^<2->,Se^<2->) Ligands"Angew.Chem.Int.Ed.. 40. 1266-1268 (2001)

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      2003 Final Research Report Summary
  • [Publications] T.Matsumoto, Y.Matsui, Y.Nakaya, K.Tatsumi: "1,2,3,4,5,6,7-Hexathiagermepanes : Synthesis, Structures and the Ring Contraction to 1,2,3,4,5-tetrathiagermolanes."Chem.Lett.. 60-61 (2001)

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      2003 Final Research Report Summary
  • [Publications] T.Matsumoto, K.Tatsumi: "Sterically Protected Dipotassium Germanedithiolate"Chem.Lett.. 964-965 (2001)

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      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Yu, Q.-F.Xu, Z.-R.Sun, S.-J.Ji, J.-X.Chen, Q.Liu, J.-P.Lang, K.Tatsumi: "Unique Formation of Two Different W/Ag/S Clusters from the Same Components via a Low Heating Temperature Solid State Reaction and a Solution Reaction and Their Third-Order NLO Properties in Solution."Chem.Commun.. 2614-2615 (2001)

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      2003 Final Research Report Summary
  • [Publications] Y.Sunada, Y.Hayashi, H.Kawaguchi, K.Tatsumi: "Alkynethiolato and Alkyneselenolato Ruthenium Half-sandwich Complexes : Synthesis, Structures, and Reactions with (η^5-C_5H_5)_2Zr."Inorg.Chem.. 40. 7072-7078 (2001)

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    • Related Report
      2003 Final Research Report Summary
  • [Publications] Y.Arikawa, H.Kawaguchi, K.Kashiwabara, K.Tatsumi: "Trithiotungsten(VI) Complexes having Phosphine-Thiolate Hybrid Ligands : Synthesis and Cluster Forming Reactions with CuBr, FeCl_2 and [Fe(CH_3CN)_6](ClO_4)_2."Inorg.Chem.. 41. 513-520 (2002)

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      2003 Final Research Report Summary
  • [Publications] Y.Yamamoto, H.Suzuki, N.Tajima, K.Tatsumi: "Stepwise Formation of Quasi-Octahedral Macrocyclic Complexes of Rhodium(III) and Iridium(III) Bearing a Pentamethyl-cyclopentadienyl Group"Chem.Eur.J.. 8. 372-379 (2002)

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      2003 Final Research Report Summary
  • [Publications] K.Ogata, K.Kuge, K.Tatsumi, Y.Yamamoto: "One-step Synthesis of Alkenyl Ketone Complexes from Cp^*RhCl_2(PPh_3),Alkyne and H_2O in the Presence of KPF_6."Chem.Commun.. 128-129 (2002)

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      2003 Final Research Report Summary
  • [Publications] T.Matsumoto, T.Kasai, K.Tatsumi: "Chiral Crystallization of a Linear Two-coordinated Palladium(O) Complex Bearing Propeller-shaped Bulky Phosphine Ligands."Chem.Let.. 346-347 (2002)

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      2003 Final Research Report Summary
  • [Publications] T.Komuro, H.Kawaguchi, K.Tatsumi: "Palladium Dimethylsilanedithiolate Complex : A Precursor for Ti-P and Ti-Pd_2 Heterometllic Complexes."Chem.Commun.. 988-989 (2002)

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      2003 Final Research Report Summary
  • [Publications] R.Chen, K.Tatsumi: "Synthesis and Molecular Structure of a Novel Dilithium Complex of(i-Pr_2C_6H_3)_<2-> dad."Chin.J. of Org.Chem.. 272-274 (2002)

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  • [Publications] J.-P.Lang, H.Kawaguchi, K.Tatsumi: "Reactions of Tetrathiotungstate and Tetrathiomolybdate with Substituted Haloalkanes."J.Chem.Soc.,Dalton. 2753-2580 (2002)

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      2003 Final Research Report Summary
  • [Publications] R.Cao, K.Tatsumi: "Alkylation Reactions of [WS_4]^<2-> and [η^5-C_5Me_5)WS_3]^- with 2,6-Bis(bromomethyl) pyridine : The First Isolation of Bis-alkylated Tetrathiometallate WS_2{2,6-(SCH_2)_2-(C_5H_3N)}."Inorg.Chem.. 41. 4102-4104 (2002)

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      2003 Final Research Report Summary
  • [Publications] M.-C.Hong, R.Cao, H.Kawaguchi, K.Tatsumi: "Synthesis and Reactions of Group 6 Metal Half Sandwich Complexes of 2,2-dicyanoethylene-1,1-dichalcogenolates[Cp^*M{E_2C=C(CN)_2}_2]^-(M=Mo, W ; E =S Se)."Inorg.Chem.. 41. 4824-4833 (2002)

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  • [Publications] R.Cao, K.Tatsumi: "Use of the Dipotassium Salt of Cyanamide for the Synthesis of Tungsten and Cobalt Complexes Having NCN Ligand."Chem.Commun.. 2144-2145 (2002)

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  • [Publications] T.Komuro, H.Kawaguchi, K.Tatsumi: "Synthesis and Reaction of Triphenylsilanethiolato Complexes of Manganese(II),Iron(II),Cobalt(II) and Nickel(II)."Inorg.Chem.. 41. 5083-5090 (2002)

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  • [Publications] R.Chen, K.Tatsumi: "Synthesis and Molecular Structure of a Novel Ion Pair Lithium Complex of a Diazabutadiene."J.Coord.Chem.. 1219-1222 (2002)

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  • [Publications] Y.Yamamoto, H.Settu, K.Nishiyama, K.Kuge, K.Tatsumi: "Unprecedented Formation of Dinuclear Macrocyclic Complexes by Insertion of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquino-dimethane (Li[F4-tcnq]) into a C-H Bond and Its Coordination to Metal Atoms."Eur.J.Inorg.Chem.. 2447-2452 (2002)

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  • [Publications] Y.Yamamoto, K.Ogata, K.Kuge, K.Tatsumi: "A Convenient One-step Synthesis of Alkenyl-phosphino Complexes of Ruthenium(II),Rhodium(III) and Iridium(III)."Inorg.Chem.Commun.. 862-864 (2002)

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  • [Publications] J.P.Lang, H.Yu, S.J.Ji, K.Tatsumi: "Syntheses and Crystal Structures of Nickel and Manganese Cluster Compounds of the Pentamethylcyclopentadienyl Trisulfido Tungsten"Inorg.Chim.Acta.. 344. 169-173 (2003)

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  • [Publications] J.P.Lang, S.J.Ji, Q.F.Su, Q.Shen, K.Tatsumi: "Structural Aspects of Copper(I) and Silver(I) Sulfide Clusters of Pentamethyl-cyclopentadienyl Trisulfido Tungsten(VI) and Molybdenum(VI)."Coord.Chem.Rev.. 241. 47-60 (2003)

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  • [Publications] S.E.d'Arbeloff, P.B.Hitchcock, J.F.Nixon, H.Kawaguchi, K.Tatsumi: "[2+2] Cycloaddition Reactions of Bis-Pentamethylcyclopenta-dienyl Zirconium Metal Complexes Containing Terminal Chalcogenide Ligands with the Phospha-alkyne PCBu^t. Synthesis, Crystal and Molecular Structures of [Zr(η^5-(C_5Me_5)_2(SC(^tBu)=P)),[Zr(η^5-(C_5Me_5)_2(SeC(^tBu)=Pse)) and [Zr(η^5-(C_5Me_5)_2(SC(^tBu)=PC(Ph)=N)"J.Organomet.Chem.. 672. 1-10 (2003)

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  • [Publications] Y.Yamamoto, A.Nagata, H.Nagata, Y.Ando, Y.Arikawa, K.Tatsumi, K.Itoh: "Palladium(0)-Catalyzed Intramolecular [2+2+2] Alkyne Cyclotrimerizations with Electron-Deficient Diynes and Triynes"Chem.Eur.J.. 9. 2469-2483 (2003)

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  • [Publications] Y.Kosaka, Y.Shinozaki, Y.Tsutsumi, Y.Yamamoto Y.Sunada, K.Tatsumi: "Stereochemistry of Mono- and Di-nuclear Complexes of Rhodium, Iridium, and Ruthenium Bearing [Bis(diphenylphosphinomethyl)]phenylphosphine"J.Organomet.Chem.. 671. 8-12 (2003)

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  • [Publications] K.Matsuzaki, H.Kawaguchi, P.Voth, K.Noda, S.Itoh, H.D.Takagi, K.Kashiwabara, K.Tatsumi: "Synthesis and Characterization of Ti(IV) and Ti(III) Complexes with (2-Dimethyl-phosphino)ethane-1-thiolate and (3-Dimethylphosphino)propane-1-thiolate as Ligands."Inorg.Chem.. 42. 5320-5329 (2003)

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      2003 Final Research Report Summary
  • [Publications] J.-P.Lang, Z.-R.Sun, Q.-F.Xu, H.Yu, K.Tatsumi: "Optical Limiting Properties of Two Organometallic Half-open Cubane-like Cluster Compounds [η^5-C_5Me_5]WS_3Cu_3Br_2(EPh_3)_2](E=As, P)."Materials Chem. and Phys.. 82. 493-498 (2003)

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  • [Publications] S.Arndt, P.M.Zeimentz, T.P.Spaniol, J.Okuda, M.Honda, K.Tatsumi: "Neutral and Cationic Trimethylsilylmethyl Complexes of the Rare Earth Metals Supported by a Crown Ether : Synthesis and Structural Characterization"J.Chem.Soc.,Dalton. 3622-3627 (2003)

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  • [Publications] K.Tamao, R.West, K.Tatsumi: "A Half Century of Polysilane Chemistry"J.Organomet.Chem. (special issue). (2003)

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  • [Publications] Y.Yamamoto, Y.Kohsaka, Y.Shinozaki, Y.Tsutsumi, Y.Kaburagi, K.Kuge, Y.Sunada, K.Tatsumi: "Homo- and Heteronuclear Complexes of (Pentamethylcyclopentadienyl)rhodium)(III) Bearing [Bis(diphenylphosphanylmethyl)]phenylphosphate."Eur.J.Inorg.Chem.. 134-142 (2003)

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  • [Publications] Y.Yamamoto, Y.Sinozuka, Y.Tsutsumi, K.Fuse, K.Kuge, Y.Sunada, K.Tatsumi: "Homo- and Heteronuclear Complexes Based on Arene Ruthenium Complexes Bearing Bis(diphenylphosphinomethyl)phenylphosphine (dpmp)."Inorg.Chim.Acta.. (in press). (2004)

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  • [Publications] Y.Ohki, H.Sadohara, Y.Takikawa, K.Tatsumi: "A Coordinatively Unsaturated 2,6-Dimesitylphenyl Thiolate Complex of Half-Sandwich Ruthenium(II)."Angew.Chem.Int.Ed.. 43. 2290-2293 (2004)

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  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Synthesis and Structural Characterization of Silanethiolato Complexes Having teri-Butyldimethylsilyl and Trimethylsilyl Groups"J.Chem.Soc.,Dalton. (in press). (2004)

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  • [Publications] M.Fujita, W.-H.Kim, Y.Sakanishi, K.Fujiwara, S.Hirayama, T.Okuyama, Y.Ohki, K.Tatsumi, Y.Yoshikawa: "Elimination-Addition Mechanism for Nucleophilic Substitution Reaction of Cyclohexenyl Iodonium Salts and Regioselectivity of Nucleophilic Addition to the Cyclohexyne Intermediate."J.Am.Chem.Soc.. (submitted). (2004)

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  • [Publications] H.Sugiyama, Y.Hayashi, K.Tatsumi: "Carbon-carbon Bond Forming Reactions of Alkynethiolate and Alkyneselenolate at Ti(III) and Zr(IV) Centers."Organometallics. (submitted). (2004)

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  • [Publications] 巽 和行, 大木靖, 弘川口博之: "実験化学講座21"丸善株式会社. 83-94 (2004)

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  • [Publications] G.-X.Jin, Y Arikawa, K.Tatsumi: "Spontaneous Formation of a Diamond-crown Structure of Re_8 Polyselenide and a Cage Structure of Re_3 Polytelluride"J.Am.Chem.Soc.. 123. 735-736 (2001)

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      2003 Final Research Report Summary
  • [Publications] H.Kawaguchi, K.Tatsumi: "Synthesis of a Pentamethylcyclopentadienyl Complex of Tungsten with Three Different Chalcogenido (O^<2->, S^<2->, Se^<2->) Ligands."Angew.Chem.Int.Ed.. 40. 1266-1268 (2001)

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      2003 Final Research Report Summary
  • [Publications] T.Matsumoto, Y Matsui, Y Nakaya, K.Tatsumi: "1,2,3,4,5,6,7-Hexathiagermepanes : Synthesis, Structures and the Ring Contraction to 1,2,3,4,5-tetrathiagermolanes."Chem.Lett.. 60-61 (2001)

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      2003 Final Research Report Summary
  • [Publications] T.Matsumoto, K.Tatsumi: "Sterically Protected Dipotassium Germanedithiolate."Chem.Lett.. 964-965 (2001)

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    • Related Report
      2003 Final Research Report Summary
  • [Publications] H., Yu, Q.-F.Xu, Z.-R.Sun, S.-J.Ji, J.-X.Chen, Q.Liu, J.-P.Lang, K.Tatsumi: "Unique Formation of Two Different W/Ag/S Clusters from the Same Components via a Low Heating Temperature Solid State Reaction and a Solution Reaction and Their Third-Order NLO Properties in Solution."Chem.Commun.. 2614-2615 (2001)

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      2003 Final Research Report Summary
  • [Publications] Y.Sunada, Y.Hayashi, H.Kawaguchi, K.Tatsumi: "Alkynethiolato and Alkyneselenolato Ruthenium Half-sandwich Complexes : Synthesis, Structures, and Reactions with (η^5-C_5H_5)_2Zr."Inorg.Chem.. 40. 7072-7078 (2001)

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      2003 Final Research Report Summary
  • [Publications] Y.Arikawa, H.Kawaguchi, K.Kashiwabara, K.Tatsumi: "Trithiotungsten(VI) Complexes having Phosphine-Thiolate Hybrid Ligands : Synthesis and Cluster Forming Reactions with CuBr,FeCl_2 and [Fe(CH_3CN)_6](ClO_4)_2."Inorg.Chem.. 41. 513-520 (2002)

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      2003 Final Research Report Summary
  • [Publications] Y.Yamamoto, H.Suzuki, N.Tajima, K.Tatsumi: "Stepwise Formation of Quasi-Octahedral Macrocyclic Complexes of Rhodium(III) and Iridium(III) Bearing a Pentamethyl-cyclopentadienyl Group."Chem.Eur.. 8. 372-379 (2002)

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      2003 Final Research Report Summary
  • [Publications] K.Ogata, K.Kuge, K.Tatsumi, Y.Yamamoto: "One-step Synthesis of Alkenyl Ketone Complexes from Cp^*RhCl_2(PPh_3), Alkyne and H_2O in the Presence of KPF_6."Chem.Commun.. 128-129 (2002)

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      2003 Final Research Report Summary
  • [Publications] T.Matsumoto, T.Kasai, K.Tatsumi: "Chiral Crystallization of a Linear Two-coordinated Palladium(0) Complex Bearing Propeller-shaped Bulky Phosphine Ligands."Chem.Lett.. 346-347 (2002)

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  • [Publications] T.Komuro, H.Kawaguchi, K.Tatsumi: "Palladium Dimethylsilanedithiolate Complex : A Precursor for Ti-P and Ti-Pd_2 Heterometllic Complexes."Chem.Commun.. 988-989 (2002)

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  • [Publications] R.Chen, K.Tatsumi: "Synthesis and Molecular Structure of a Novel Dilithium Complex of (i-Pr_2C_6H_3)_2-dad."Chin.J.of Org.Chem.. 272-274 (2002)

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  • [Publications] J.-P.Lang, H.Kawaguchi, K.Tatsumi: "Reactions of Tetrathiotungstate and Tetrathiomolybdate with Substituted Haloalkanes."Chem.Soc, Dalton. 2573-2580 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] R.Cao, K.Tatsumi: "Alkylation Reactions of [WS_4]^<2-> and [(η^5-C_5Me_5)WS_3]^-with 2,6-Bis(bromomethyl)pyridine : The First Isolation of Bis-alkylated Tetrathiometallate WS_2{2,6-(SCH_2)_<2->(C_5H_3N)}."Inorg.Chem.. 1. 4102-4104 (2002)

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      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] M.-C.Hong, R.Cao, H.Kawaguchi, K.Tatsumi: "Synthesis and Reactions of Group 6 Metal Half Sandwich Complexes of 2,2-dicyanoethylene-1,1-dichalcogenolates[Cp^*M{E_2C=C(CN)_2}_2]^-(M=Mo, W; E=S, Se)."Inorg.Chem.. 41. 4824-4833 (2002)

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      2003 Final Research Report Summary
  • [Publications] R.Cao, K.Tatsumi: "Use of the Dipotassium Salt of Cyanamide for the Synthesis of Tungsten and Cobalt Complexes Having NCN Ligand."Chem.Commun.. 2144-2145 (2002)

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      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] T.Komuro, H.Kawaguchi, K.Tatsumi: "Synthesis and Reaction of Triphenylsilanethiolato Complexes of Manganese(II), Iron(II), Cobalt(II) and Nickel(II)."Inorg.Chem.. 41. 5083-5090 (2002)

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      2003 Final Research Report Summary
  • [Publications] R.Chen, K.Tatsumi: "Synthesis and Molecular Structure of a Novel Ion Pair Lithium Complex of a Diazabutadiene."J.Coord.Chem.. 1219-1222 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] Y.Yamamoto, H.Settu, K.Nishiyama, K.Kuge, K.Tatsumi: "Unprecedented Formation of Dinuclear Macrocyclic Complexes by Insertion of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquino-dimethane (Li[F4-tcnq]) into a C-H Bond and Its Coordination to Metal Atoms."Eur.J.Inorg.Chem.. 2447-2452 (2002)

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      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] Y.Yamamoto, K.Ogata, K.Kuge, K.Tatsumi: "A Convenient One-step Synthesis of Alkenyl-phosphino Complexes of Ruthenium(II), Rhodium(III) and Iridium(III)."Inorg.Chem.Commun.. 862-864 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Copper and Silver Complexes Containing a Novel S(SiME_2S)_2^<2-> Efficient Entries into Heterometallic Silfido Clusters."Angew.Chem.Int.Ed.. 41. 465-468 (2003)

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      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] J.P.Lang, H.Yu, S.J.Ji, K.Tatsumi: "Syntheses and Crystal Structures of Nickel and Manganese Cluster Compounds of the Pentamethylcyclopentadienyl Trisulfido Tungsten"Inorg.Chim.Acta. 344. 169-173 (2003)

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      2003 Final Research Report Summary
  • [Publications] J.P.Lang, S.J.Ji, Q.F.Su, Q.Shen, K.Tatsumi: "Structural Aspects of Copper(I) and Silver(I) Sulfide Clusters of Pentamethyl-cyclopentadienyl Trsulfido Tungsten(VI) and Molybdenum(VI)."Coord Chem.Rev.. 241. 47-60 (2003)

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  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Unusual Coordination Modes of Arylthiolates in Mo{η^5-SC_6H_3-2,6-(SiMe_3)_2}{η^7-SC_6H_3-2,6-(SiMe_3)_2"J.Am.Chem.Soc.. 125. 2070-2071 (2003)

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      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] S.E.d'Arbeloff, P.B.Hitchcock, J.F.Nixon, H.Kawaguchi, K.Tatsumi: "[2+2] Cycloaddition Reactions of Bis-Pentamethylcyclopenta-dienyl Zirconium Metal Complexes Containing Terminal Chalcogenide Ligands with the Phospha-alkyne PCBu^t. Synthesis, Crystal and Molecular Structures of [Zr(η^5-(C_5Me_5)_2(SC(^tBu)=P)), [Zr(η^5-(C_5Me_5)_2(SeC(-tBu)=P)), [Zr(η^5-(C_5Me_5)_2(SC(^tBu)=Pse)) and [Zr(η^5-(C_5Me_5)_2 (SC(^tNu)=PC(Ph)=N)"J.Organomet.Chem.. 672. 1-10 (2003)

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      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] Y.Yamamoto, A.Nagata, H.Nagata, Y.Ando, Y.Arikawa, K.Tatsumi, K.Itoh: "Palladium(0)-Catalyzed Intramolecular [2+2+2] Alkyne Cyclotrimerizations with Electron-Deficient Diynes and Triynes."Chem.Eur.J.. 9. 2469-2483 (2003)

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      「研究成果報告書概要(欧文)」より
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  • [Publications] Y.Ohki, Y.Sunada, M.Honda, M.Katada, K.Tatsumi: "Synthesis of the P-Cluster Inorganic Core of Nitrogenases."J.Am.Chem.Soc.. 125. 4052-4053 (2003)

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      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] Y.Kosaka, Y.Shinozaki, Y.Tsutsumi, Y.Yamamoto Y Sunada, K.Tatsumi: "Stereochemistry of Mono-and Di-nuclear Complexes of Rhodium, Iridium, and Ruthenium Bearing [Bis(diphenylphosphinomethyl)]phenylphosphine"J.Organomet.Chem.. 671. 8-12 (2003)

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      2003 Final Research Report Summary
  • [Publications] Y.Ohki, N.Matsuura, T.Marumoto, H.Kawaguchi, K.Tatsumi: "Heterolytic Cleavage of Dihydrogen Promoted by Sulfido-Bridged Tungsten-Ruthenium Dinuclear Complexes"J.Am.Chem.Soc.. 125. 7978-7988 (2003)

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      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] K.Matsuzaki, H.Kawaguchi, P.Voth, K.Noda, S.Itoh, H.D.Takagi, K.Kashiwabara, K.Tatsumi: "Synthesis and Characterization of Ti(IV) and Ti(III) Complexes with (2-Dimetphosphino)ethane-1-thiolate and (3-Dimethylphosphino)propane-1-thiolate as Ligands."Inorg.Chem.. 42. 5320-5329 (2003)

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      2003 Final Research Report Summary
  • [Publications] J.-P.Lang, Z.-R.Sun, Q.-F.Xu, H.Yu, K.Tatsumi: "Optical Limiting Properties of Two Organometallic Half-open Cubane-like Cluster Compounds [η~5-C_5Me_5]WS_3Cu_3Br_2(EPh_3)_2] (E=As, P)."Materials Chem.and Phys.. 82. 493-498 (2003)

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  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Coordination Chemistry of Silanedithiolato Ligands Derived from Cyclotrisilathiane : Synthesis and Structures 'of Complexes of Iron(II), Cobalt(II) Copper(I), and Silver(I)."Inorg.Chem.. 42. 5340-5347 (2003)

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      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] S.Arndt, P.M.Zeimentz, T.P.Spaniol, J.Okuda, M.Honda, K.Tatsumi: "Neutral and Cationic Trimethylsilylmethyl Complexes of the Rare Earth Metals Supported by a Crown Ether : Synthesis and Structural Characterization"J.Chem.Soc., Dalton. 3622-2627 (2003)

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  • [Publications] K.Tamao, R.West, K.Tatsumi: "A Half Century of Polysilane Chemistry"J.Organomet.Chem.. Special Issue. (2003)

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  • [Publications] Y.Yamamoto, Y.Kohsaka, Y.Shinozaki, Y.Tsutsumi, Y.Kaburagi, K.Kuge, Y.Sunada, K.Tatsumi: "Homo-and Heteronuclear Complexes of (Pentamethylcyclopentadienyl)rhodium)(III) Bearing [Bis(diphenylphosphanylmethyl)]phenylphosphate."Eur.J.Inorg.Chem.. 134-142 (2004)

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  • [Publications] Y.Yamamoto, Y.Sinozuka, Y.Tsutsumi, K.Fuse, K.Kuge, Y.Sunada, K.Tatsumi: "Homo-and Heteronuclear Complexes Based on Arene Ruthenium Complexes Bearing Bis(diphenylphosphinomethyl)phenylphosphine (dpmp)."Inorg.Chim.Acta. (in press). (2004)

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  • [Publications] Y.Ohki, H.Sadohara, Y.Takikawa, K.Tatsumi: "A Coordinatively Unsaturated 2,6-Dimesitylphenyl Thiolate Complex of Half-Sandwich Ruthenium(II)."Angew.Chem.Int.Ed.. 43. 2290-2293 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
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  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Synthesis and Structural Characterization of Silanethiolato Complexes Having tert-Butyldimethylsilyl and Trimethylsilyl Groups"J.Chem.Soc., Dalton. (in press). (2004)

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      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] M.Fujita, W.-H.Kim, Y Sakanishi, K Fujiwara, S.Hirayama, T.Okuyama, Y Ohki, K.Tatsumi, Y.Yoshikawa: "Elimination-Addition Mechanism for Nucleophilic Substitution Reaction of Cyclohexenyl Iodonium Salts and Regioselectivity of Nucleophilic Addition to the Cyclohexyne Intermediate."J.Am.Chem Soc.. (submitted). (2004)

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  • [Publications] H.Sugiyama, Y.Hayashi, K.Tatsumi: "Carbon-carbon Bond Forming Reactions of Alkynethiolate and Alkyneselenolate at Ti(III) and Zr(IV) Centers."Organometallics. (submitted). (2004)

    • Description
      「研究成果報告書概要(欧文)」より
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      2003 Final Research Report Summary
  • [Publications] Ohki, Y., Tatsumi, K., et al.: "Heterolytic Cleavage of Dihydrogen Promoted by Sulfido-Bridged Tungsten-Ruthenium Dinuclear Complexes"J.Am.Chem.Soc. 125. 7978-7988 (2003)

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      2003 Annual Research Report
  • [Publications] Ohki, Y., Tatsumi, K., et al.: "Synthesis of the P-Cluster Inorganic Core of Nitrogenases"J.Am.Chem.Soc. 125. 4052-4053 (2003)

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      2003 Annual Research Report
  • [Publications] Komuro, T., Tatsumi, K., et al.: "Unusual Coordination Modes of Arylthiolates in Mo{η^5-SC_6H_3-2,6-(SiMe_3)_2}{η^7-SC_6H_3-2,6-(SiMe_3)_2"J.Am.Chem.Soc. 125. 2070-2071 (2003)

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      2003 Annual Research Report
  • [Publications] Komuro, T., Tatsumi, K., et al.: "Copper ans Silver Complexes Containing a Novel S(SiMe_2S)_2^<2-> Ligand : Efficient Entries into Heterometallic Silfido Clusaters"Angew.Chem.Int.Ed.. 41. 465-468 (2003)

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      2003 Annual Research Report
  • [Publications] Matsuzaki, K., Tatsumi, K.et al.: "Synthesis and Characterization of Ti(IV) and Ti(III) Complexes with (2-Dimetphosphino)ethane-1-thiolate and (3-Dimethylphosphino)propane-1-thiolate as Ligands"Inorg.Chem.. 42. 5320-5329 (2003)

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      2003 Annual Research Report
  • [Publications] Komuro, T., Tatsumi, K., et al.: "Coordination Chemistry of Silanedithiolato Ligands Derived from Cyclotrisilathiane : Synthesis and Structures of Complexes of Iron(II), Cobalt(II) Copper(I), and Silver(I)"Inorg.Chem.. 42. 5340-5347 (2003)

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      2003 Annual Research Report
  • [Publications] T.Kornuro, H.Kawaguchi, K.Tatsumi: "Palladium Dimethylsilanedithiolate Complex : A Precursor for Ti-P and Ti-Pd_2 Heterornetilic Complexes"Chem.Commun. No.9. (2002)

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      2002 Annual Research Report
  • [Publications] R.Cao, K.Tatsumi: "Alkylation Reactions of [WS_4]^<2-> and [(η^5-C_5Me_5)WS_3]^-with 2,6-Bis(bromomethyl) pyridine : The First Isolation of Bis-alkylated Tetrathiometallate WS_2{2,6-(SCH_2)_2-(C_5H_3N)}"Inorg.Chem. 41(No.16). 4102-4104 (2002)

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      2002 Annual Research Report
  • [Publications] M.-C.Hong, R.Cao, H.Kawaguchi, K.Tatsumi: "Synthesis and Reactions of Group 6 Metal Half Sandwich Complexes of 2,2-dicyanoethylene-1,1-dichalcogenolates[Cp*M{E_2C=C(CN)_2}_2]^-(M=Mo, W ; E=S Se)"Inorg.Chem. 41(No.18). 4824-4833 (2002)

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      2002 Annual Research Report
  • [Publications] T.Komuro, H.Kawaguchi, K.Tatsumi: "Synthesis and Reaction of Triphenylsilanethiolato Complexes of Manganese (II),Iron(II),Cobalt(II) and Nickel(II)"Inorg.Chem. 41(No.20). 4824-4833 (2002)

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      2002 Annual Research Report
  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Copper ans Silver Complexes Containing a Novel S(SiMe_2S)_2^<2-> Ligand : Efficient Entries into Heterometallic Silfido Clusaters"Angew.Chem.Int. Ed. 41(No.1). 465-468 (2003)

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      2002 Annual Research Report
  • [Publications] T.Komuro, T.Matsuo, H.Kawaguchi, K.Tatsumi: "Unusual Coordination Modes of Arylthiolates in Mo{η^5-SC_6H_3-2,6-(SiMe_3)_2} {η^7-SC_6H_3-2,6-(SiMe_3)_2"J.Am.Chem.Soc..

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      2002 Annual Research Report
  • [Publications] G. -X. Jin, et al.: "Spontaneous Formation of a Diamond-crown Structure of Re_8 Polyselenide and a Cage Structure of Re_3 Polytelluride"J. Am. Chem. Soc.. 123・No4. 735-736 (2001)

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      2001 Annual Research Report
  • [Publications] H. Kawaguchi, et al.: "Synthesis of a Pentamethylcyclopentadienyl Complex of Tungsten with Three Different Chalcogenido (O^<2->,S^<2->,Se^<2->) Ligands"Angew. Chem. Int. Ed.. 40・No7. 1266-1268 (2001)

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      2001 Annual Research Report
  • [Publications] T. Matsumoto, et al.: "1,2,3,4,5,6,7-Hexathia germepanes : Synthesis, Structures and the Ring Contraction to 1,2,3,4,5- tetrathiagermolanes"Chem. Lett.. No1. 60-61 (2001)

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      2001 Annual Research Report
  • [Publications] H. Yu, et al.: "Unique Formation of Two Different W/Ag/S Clusters from the Same Components via a Low Temperature Solid State Reaction and ・・・"Chem. Commun.. No24. 2614-2615 (2001)

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      2001 Annual Research Report
  • [Publications] Y. Sunada, et al.: "Alkynethiolato and Alkyneselenolato Ruthenium Half-sandwich Complexes : Synthesis, Structures, and Reactions with (η^5-C_5H_5)_2Zr"Inorg. Chem.. 40・No27. 7072-7078 (2001)

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      2001 Annual Research Report
  • [Publications] Y. Arikawa, et al.: "Trithiotungsten (VI) Complexes having Phosphine-Thiolate Hybrid Ligands : Synthesis and Cluster Forming Reactions with CuBr, F_2Cl_2 and [Fe(CH_3CN)_6](ClO_4)_2"Inorg. Chem.. 41・No3. 513-520 (2002)

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      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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