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Chemical reaction control in nano-area by radiation -transformation of radiation physics to radiation chemistry -

Research Project

Project/Area Number 13358008
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Nuclear engineering
Research InstitutionNagoya University

Principal Investigator

TANABE Tetsuo  Nagoya University, Department of Nuclear Engineering, Professor, 工学研究科, 教授 (00029331)

Co-Investigator(Kenkyū-buntansha) TANAKA Isao  Kyoto University, Department of Energy Science, Professor, 大学院・エネルギー科学研究科, 助教授 (70183861)
YOSHIDA Tomoko  Nagoya University, Department of Nuclear Engineering, Associate Professor, 工学研究科, 助教授 (90283415)
MUTO Shunsuke  Nagoya University, Department of Nuclear Engineering, Associate Professor, 工学研究科, 助教授 (20209985)
MARUYAMA Tadashi  Wakasawan Energy Research Center, Principal Researcher, 主席研究員
HOJOU Kiichi  Japan Atomic Energy Research Institute, Tokai Establishment, Principal Researcher, 東海研究所・固体物理研究室, 室長
KITAJIMA Masahiro  National Research Institute of Materials, Principal Researcher
北條 喜一  日本原子力研究所, 東海研究所・固体物理研究室, 室長
丸山 忠志  若狭湾エネルギー研究センター, 主席研究員
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥42,510,000 (Direct Cost: ¥32,700,000、Indirect Cost: ¥9,810,000)
Fiscal Year 2003: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2002: ¥13,650,000 (Direct Cost: ¥10,500,000、Indirect Cost: ¥3,150,000)
Fiscal Year 2001: ¥24,180,000 (Direct Cost: ¥18,600,000、Indirect Cost: ¥5,580,000)
KeywordsNano-structure analysis / Electron Energy loss spectroscopy / EXAFS / Radiation damage / Lattice defects / Energetic particle induced luminescence / Effective utilization of Radiation / Laser probe analysis / 電子線エネルギー損失分光 / X線広域吸収端微細構造分析
Research Abstract

(1) New in situ analysis methods to study materials modification near surface regions brought by ion implantation were developed utilizing various radiation like electrons, ions, laser photons, as a probe.
(2) Applying EXELFS and EELS, developed by this study, damage process of graphite was examined. It is clearly demonstrated that some new type of bonding different from sp^2 accompanying flouren type structure formation in both electron-and ion-irradiation.
(3) Glazing incidence electron microscopy was also developed and successfully applied for the surface modification like a blister formation. A new blistering mechanism was proposed for covalent and semiconductor materials based on ductile transformation.
(4) Molecular dynamic approach was applied to examine the swelling of SiC by ion irradiation and probed to be very effective. It was found that in SiC, an additional mechanism i.e. changes of bond length between Si-Si and Si-C atoms and bond angles of Si-C-Si is contributing the swelling in addition to the void swelling.
(5) The nano-identation method was also applied to examine change of surface mechanical properties by ion implantation and the material strength in nanometer thickness was successfully extracted.
(6) Appling various simulation codes, energy conversion or damaging process in nano-range was extensively studied. It was found that electron excitation play very important role in damaging process of covalent and semiconductor materials.
(7) Energy conversion of γ-ray through production of secondary electrons and photons was successfully demonstrated. A new electric cell driven by γ-ray source was developed.

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (39 results)

All Other

All Publications (39 results)

  • [Publications] S.Muto, T.Tanabe: "Local structures and damage processes of electron irradiated a-SiC studied with transmission electron microscopy and electron energy-loss spectroscopy"J.Appl.Phys.. 93巻. 3765-3775 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Muto, T.Tanabe: "Reverse Monte Carlo analysis of extended energy-loss fine structure for disordered structures of tetrahedrally coordinated materials : its applicability"J. Electron Microscopy. 52巻. 125-132 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yoshida, T.Tanabe, A.Chen 他: "A new method for the degradation of dibutyl phthalate in water by gamma-ray irradiation"Radioanalytical and Nuclear Chemistry. 255巻. 271-274 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Hojo, J.Aihara, K.Hojou 他: "Irradiation effects on yttria-stabilized zirconia irradiated with neon ions"J.Nucl.Mater.. 319巻. 81-86 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Muto, T.Tanabe, T.Maruyama: "Cross Sectional TEM Observation of Gas-Ion-Irradiation Induced Surface Blisters and Their Precursors in SiC"Materials Transactions. 44巻. 259-260 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Tanabe, S.Muto, S.Tohtake: "Development of new TEM specimen holder for cathodoluminescence detection"J.Electron Microscopy. Vol.51(5). 311-313 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Muto, T.Tanabe, T.Shibayama, H.Takahashi: "Damaging process of -SiC under electron irradiation studied with electron microscopy and spectroscopy"Nucl.Instr.and Method.B. Vol.191. 519-523 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yoshida, T.Ii, Tetsuo Tanabe, H.Yoshida, K.Yamaguchi: "In-situ luminescence and optical absorption measurements of silica in reactor core"J.Nucl.Mater.. Vol.307-311. 1268-1272 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Igarashi, S.Muto, T.Tanabe, Jun Aihara, Kiichi Houjyou: "In-situ observation of surface blistering in silicon by deuterium and helium ion irradiation"Surface And Coating technology. Vol.158-159. 421-425 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Igarashi, S.Muto, T.Tanabe, T.Maruyama: "Surface blistering of ion irradiated SIC studied by grazing incidence electron microscopy"J.Nucl.Mater.. Vol.307-311. 1126-1129 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Muto, T.Tanabe, A.Hirota, M.Rubel, V.Philipps: "TEM and EELS characterization of carbon dust and co-deposited layers from the TEXTOR tokamak"J.Nucl.Mater.. Vol.307-311. 1289-1293 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Muto, T.Tanabe: "Local structures and damage processes of electron irradiated a-SiC studied with transmission electron microscopy and electron energy-loss spectroscopy"J.Appl.Phys.. Vol.93(7). 3765-3775 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Muto, T.Tanabe: "Reverse Monte Carlo analysis of extended energy-loss fine structure for disordered structures of tetrahedrally coordinated materials : its applicability"J.Electron Miroscopy. Vol.52(2). 125-132 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Muto, T.Tanabe, T.Maruyama: "Cross Sectional TEM Observation of Gas-Ion-Irradiation Induced Surface Blisters and Their Precursors in SiC"Materials Transactions. Vol.44(12). 2599-2604 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Muto, S.Dhara, A.Datta, et al.: "Characterization of nanodome on GaN nanowires formed with Ga ion irradiation, Materials Transactions"Materials Transactions. Vol.45(2). 1-5 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Sawasaki, T.Tanabe, T.Yoshida, R.Ishida: "The application of gamma radiolysis of water for H_2 production"Journal of Radioanalytical and Nuclear Chemistry. Vol.255. 271-274 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yoshida, T.Tanabe, A.Chen, et al.: "A new method for the degradation of dibutyl phthalate in water by gamma-ray irradiation"Radioanalytical and Nuclear Chemistry. Vol.255. 271-274 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Hojo, J.Aihara, K.Hojou, et al.: "Irradiation effects on yttria-stabilized zirconia irradiated with neon ions"J.Nucl.Mater.. Vol.319. 81-86 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] N.Fukata, Y.Yamamoto, K.Murakami, M.Hase, M.Kitajima: "In situ spectroscopic measurement of structural change in SiO_2 during femtosecond laser irradiation"Appl.Phys.Lett.. Vol.83. 3495-3497 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Muto, H.Sugiyama, T.Kimura, T.Tanabe: "Structure of an Oxygen-Related Defect Complex in SiC Studied with Electron Energy-Loss Spectroscopy"Japanese Journal of Applied Physics. 43(3)(in press). (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yoshida, T.Tanabe, M.Hirano, S.Muto: "FT-IR Study on the effect of OH content on the damaging process in silicon irradiated by hydrogen"Nucl.Instr.Methods B. (in press). (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Muto, T.Tanabe: "Local structures and damege processes of electron irradiated a-SiC studied with transmission electron microscopy and electron energy-loss spectroscopy"J.Appl.Phys.. 93巻7号. 3765-3775 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Muto, T.Tanabe: "Reverse Monte Carlo analysis of extended energy-loss fine structure for disordered structures of tetrahedrally coordinated materials : its applicability"J.Electron Miroscopy. 52巻2号. 125-132 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Yoshida, T.Tanabe, A.Chen 他: "A new method for the degradation of dibutyl phthalate in water by gamma-ray irradiation"Radioanalytical and Nuclear Chemistry. 255巻. 271-274 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Hojo, J.Aihara, K.Hojou 他: "Irradiation effects on yttria-stabilized zirconia irradiated with neon ions"J.Nucl.Mater.. 319巻. 81-86 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Muto, T.Tanabe, T.Maruyama: "Cross Sectional TEM Observation of Gas-Ion-Irradiation Induced Surface Blisters and Their Precursors in SiC"Materials Transactions. 44巻12号. 2599-2600 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S, Muto, S.Dhara, A.Datta, 他: "Characterization of nanodome on GaN nanowires formed with Ga ion irradiation, Materials Transactions"Materials Transactions. 45巻2号. 435-439 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Yoshida, T.Tanabe, A.Chen, 他4名: "A new method for the degradation of dibutyl phthalate in water by gamma-ray irradiation"Journal of Radioanalytical and Nuclear Chemistry. 255. 271-274 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Sawasaki, T.Tanabe, T.Yoshida, R.Ishida: "The application of gamma radiolysis of water for H_2 production"Journal of Radioanalytical and Nuclear Chemistry. 255. 265-269 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Tomoko Yoshida, Tatsuya Ii, Tetsuo Tanabe他2名: "In-situ luminescence and optical absorption measurements of silica in reactor core"J. Nucl. Mater.. 307-311. 1268-1272 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 武藤俊介, 田辺哲朗: "透過電子エネルギー損失分光における内殻励起スペクトルを利用した軽元素材料の局所構造解析"表面科学. 23. 381-388 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Tanabe, S.Muto, S.Tohtake: "Development of new TEM specimen holder for cathodoluminescence detection"J. Electron Microscopy. 51巻・5号. 311-313 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] S.Muto, T.Tanabe: "Local structures and damage processes of electron irradiatedad a-SiC studied with transmission electron microscopy and electron energy-loss spectroscopy"J. Appl. Phys. 93巻・7号. (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] S. Muto, T. Matsui, T. Tanabe: "Non-destructive analysis of surface blistering by TEM and EELS in a reflection configuration"J. Nucl. Mater.. 290-293. 131-134 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] S. Muto, N. Yokoya, T. Tanabe: "Detailed structure analysis of deposited layer in TEXTOR by means of TEM technique"J. Nucl. Mater.. 290-293. 295-298 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 武藤俊介, 田辺哲朗: "エネルギー損失広域微細構造短距離構造解析-二体分布から多体分布導出へ-"日本金属学会誌. 65巻,5号. 332-337 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 五十嵐慎一, 武藤俊介, 田辺哲朗: "低角度入射電子顕微鏡法による表面微小構造体の非破壊分析"日本金属学会誌(2001)pp.423-426. 65巻,5号. 423-426 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] N.Asaoka, S. Muto, T. Tanabe: "Formation of Si clusters in electron-irradiated SiC studied by electron energy-loss spectroscopy"Diamond and Related Materials, (2001)pp.1251-1254.. 10. 1251-1254 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T. Yoshida, T. Tanabe, et al.: "Degradation of Dibutyl phtalate in water by the aid of metals under γ-Ray irradaitaon"Chemistry Lett.2001,pp.876-877. 876-877 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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