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Synthesis and Functional Organization of Multiply N-Confused Porphyrins

Research Project

Project/Area Number 13440189
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionKyushu University (2002)
Kyoto University (2001)

Principal Investigator

FURUTA Hiroyuki  Kyushu University, Faculty of Engineering, Professor, 工学研究院, 教授 (40244157)

Project Period (FY) 2001 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥10,700,000 (Direct Cost: ¥10,700,000)
Fiscal Year 2002: ¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 2001: ¥8,500,000 (Direct Cost: ¥8,500,000)
KeywordsPorphyrin / N-Confused porphyrin / Porphyrin Isomer / Metal Complex / Calixphyrin / Expanded Porphyrin / Hexphyrin / Aromaticity
Research Abstract

The total electronic energy and nucleus-independent chemical shift (NICS) of 95 isomers of N-confused porphyrin (NCP) have been calculated by density functional theory (DFT) method. The aromatic nature and the stability were not directly related. The introduction of confusion decreases the stability ca. 18 kcal/mol per one confusion. The results were partially supported by the actual synthesis of cis-doubly N-confused porphyrin (N2CP). Furthermore, a different type of porphyrinoids, such as corrorin, oxyindolophyrin, and tripyrrinone, were obtained in the reactions of N2CP and NCP metal complexation. Electrochemistry and photochemistry of N2CP metal complexes were investigated and the potentiality for the use in water splitting and photodynamic therapy (PDT) were suggested.
On the other hand, a series of expanded porphyrins including, pentaphyrin, hexaphyrin, octaphyrins, and nonaphyrins, were synthesized and the structures were determined by the X-ray single crystal analyses. The normal type of meso-aryl substituted expanded porphyrins were non-planar but the doubly N-confused hexaphyrins were fond planar and could complex bis metal ions in the cavity maintaining the aromaticity.
The inner and outer metal coordination were found more general for the NCP. By using Pd(II) and Pt(II), unique double-decker type face-to-face dimers and the linear linked dimers were synthesized, respectively. When Zn(II) and Cd(II) were used, a new type of metal bridged dimers were formed. A versatile mode of NCP metal coordination were explicitly elucidated and opened the way for the metal assisted supramolecular assembly.

Report

(3 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • Research Products

    (90 results)

All Other

All Publications (90 results)

  • [Publications] Shin, J.-Y.: "N-Fused Pentaphyrins"Angew.Chem., Int.Ed.. 40. 619-621 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Araki, K.: "Acid-Base and Spectroelectrochemical Properties of Doubly N-Confused Porphyrins"Inorg.Chem.. 40. 2020-2025 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Pushpan, S.K.: "N-Confused Expanded Porphyrins : First Example of a Modified Sapphyrin with an Inverted N-Confused Pyrrole Ring"J.Am.Chem.Soc.. 123. 5138-5139 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Metal Complexes of N-Confused Calix[4]phyrin Derivative-The First X-ray Structure of Organometallic Compound of Divalent Copper"Angew.Chem., Int.Ed.. 40. 2323-2325 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "NH Tautomerism of N-Confused porphyrin"J.Am.Chem.Soc.. 123. 6207-6208 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Metal Complexes of N-Confused Calix[4]phyrin Derivative-The First X-ray Structure of Organometallic Compound of Divalent Copper"J.Am.Chem.Soc.. 123. 6435-6436 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Shin, J.-Y.: "Meso-Aryl Substituted Expanded Porphyrins"J.Am.Chem.Soc.. 123. 7190-7191 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H: "Theoretical Study of Stability, Structures, and Aromaticity of Multiply N-Confused Porphyrins"J.Org.Chem.. 66. 8563-8572 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Alagar, S.: "The First bis-Rh(I) Complex of N-Confused Porphyrin"Chem.Commun.. 1666-1667 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Nakano, A.: "Directly Linked Dehydropurpurin -Porphyrin Dyads from Ag(I)-promoted Oxidation of meso-Phenylethynyl Substituted Zinc(II) Porphyrins"Chem.Commun.. 1920-1921 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Tsuda, A.: "Syntheses, Structural Characterizations, and Optical and Electrochemical Properties of Directly Fused Diporhyrins"J.Am.Chem.Soc.. 123. 10304-10321 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Regioselective Oxidative Liberation of Aryl-Substituted Tripyrrinone Metal Complexes from N-Confused Porphyrin"Org.Lett.. 4. 181-184 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Sessler, J.L.: "Quinoxaline-oligopyrroles : Improved Pyrrole-based Anion Receptors"Chem.Commun.. 862-863 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H: "Flexible Inner and Outer Coordination of Zn(II) N-Confused Porphyrin Complex"J.Am.Chem.Soc.. 124. 5622-5623 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H: "Confusion, Inversion, and Creation -A New Spring from Porphyrin Chemistry"Chem.Commun.. 1795-1804 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Shinmori, H: "Effective Face-to-face Dimerization of a Crown Ether Appended N-Confused porphyrins"Tetrahedron Lett.. 43. 4881-4884 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Takase, M.: "Efficient Synthesis of Benzene-Centered Cyclic Porphyrin Hexamers"Tetrahedron Lett.. 43. 5157-5159 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Sessler, J.L.: "Quinoxaline-Bridged Porphyrinoids"J.Am.Chem.Soc.. 124. 13474-13479 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Shimizu, S.: "Perfluorinated meso-Aryl Expanded Porphyrins"Angew.Chem., Int.Ed.. 42. 78-82 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Crystal Structures of Palladium(II) and Copper(II) Complexes of meso-Phenyl Tripyrrinone"Inorg.Chem.Commun.. 6. 162-164 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H: "Zinc Complex of N-confused Calix[4]phyrin"Inorg.Chem.Commun.. 6. 398-401 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Alagar, S.: "Doubly N-Confused Hexaphyrin : A Novel Aromatic Expanded Porphyrin that Complexes Bis-Metals in the Core"J.Am.Chem.Soc.. 125. 878-879 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Araki, K.: "Doubly N-Confused Porphyrins as Efficient Sensitizers for Singlet Oxygen Generation"Chem.Lett.. 32. 244-245 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Taniguchi, R.: "Ring Size Selective Synthesis of meso-Aryl Expanded Porphyrins"Tetrahedron Lett.. 44. 2505-2507 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Facile Formation of N-Confused Porphyrin Dimers by Pt(II) Coordination to Outer-Nitrogens"Angew.Chem., Int.Ed.. 42. 2186-2188 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Maeda, H: "2-Allenylbenzotriazole"Acta Crysatllogr. C.. 59. o338-o339 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Liu, J.-C.: "Modulation of Axial Coordination in N-Confused Porphyrin-Antimony(V) Dibromide Complex by Proton Stimulus"Chem.Commun.. (印刷中). (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Chemistry of N-confused Porphyrin : A Novel Porphyrin Isomer"J. Oleo Sci.. 3. 77-82 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Maeda, H.: "1D Hydrogen Bonding 1-D Chain Network of Cis-Doubly N-Confused Porphyrins"Supramolecular Chemistry. 15(印刷中). (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Meda, H.: "N-Confused Porphyrin Bearing meso-Perfluorophenyl Group : A Potential Agent that Forms Stable Squareplanar Complexes with Cu(II) and Ag(III)"Org.Lett. 5. 1293-1296 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Synthesis and Structures of N-Confused 5, 20-Diphenylporphy rin and Ag(III) Complex"Org.Lett. 5. 1427-1430 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Shin, J. -Y.: "N-Fused Pentaphyrins"Angew Chem. Int. Ed.. 40. 619-621 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Araki, K.: "Acid-Base and Spectroelectrochemical Properties of Doubly N-Confused Porphyrins"Inorg. Chem.. 40. 2020-2025 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Pushpan, S. K.: "N-Confused Expanded Porphyrins : First Example of a Modified Sapphyrin with an Inverted N-Confused Pyrrole Ring"J. Am. Chem.. 123. 5138-5139 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Metal Complexes of N-Confused Calix[4]phyrin Derivative- The First X-ray Structure of Organometallic Compound of Divalent Copper"Angew. Chem. Int. Ed.. 40. 2323-2325 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "NH Tautomerism of N-Confused porphyrin"J. Am. Chem. Soc.. 123. 6207-6208 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Oxyindolophyrin : A Novel Fluoride Receptor Derived from N-Confused Corrole Isomer"J. Am. Chem. Soc.. 123. 6435-6436 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Shin, J. -Y.: "Meso-Aryl Substituted Expanded Porpyrins"J. Am. Chem. Soc.. 123. 7190-7191 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Theoretical Study of Stability, Structures, and Aromaticity of Multiply N-Confused Porphyrins"J. Org. Chem.. 66. 8563-8572 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Alagar, S.: "The Firsr bis-Rh(I) Complex of N-Confused Porphyrin"Chem. Commun.. 1666-1667 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Nakano, A.: "Directly Linked Dehydropurpurin - Porphyrin Dyads from Ag(I)-promoted Oxidation of meso-Phenylethynyl Substituted Zinc(II) Porphyrins"Chem. Commun.. 1920-1921 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Tsuda, A.: "Syntheses, Structural Characterizations, and Optical and Electrochemical Properties of Directly Fused Diporphyrins"J. Am. Chem. Soc.. 123. 10304-10321 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Regioselective Oxidative Liberation of Aryl-Substituted Tripyrrinone Metal Complexes from N-Confused Porphyrin"Org. Lett.. 4. 181-184 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Sessler, J. L.: "Quinoxaline-oligopyrroles : Improved Pyrrole-based Anion Receptors"Chem. Commun.. 862-863 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Flexible Inner and Outer Coordination of Zn(II) N- Confused Porphyrin Complex"J. Am. Chem. Soc.. 124. 5622-5623 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Confusion, Inversion, and Creation - A New Spring from Porphyrin Chemistry"Chem. Commun.. 1795-1804 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Shinmori, H.: "Effective Face-to-face Dimerization of A Crown Ether Appended N-Confused porphyrins"Tetrahedron Lett.. 43. 4881-4884 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Takase, M.: "Efficient Synthesis of Benzene-Centered Cyclic Porphyrin Hexamers"Tetrahedron Lett.. 43. 5157-5159 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Sessler, J. L.: "Quinoxaline-Bridged Porphyrinoids"J. Am. Chem. Soc.. 124. 13474-13479 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Shimizu, S.: "Perfluorinated meso-Aryl Expanded Porphyrins"Angew. Chem. Int. Ed.. 42. 78-82 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Crystal Structures of Palladium(II) and Copper(II) Complexes of meso-Phenyl Tripyrrinone"Inorg. Chem. Commun.. 6. 162-164 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Zinc Complex of N-confused Calix[4]phyrin"Inorg. Chem. Commun.. 6. 398-401 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Alagar, S.: "Doubly N-Confused Hexaphyrin : A Novel Aromatic Expanded Porphyrin that Complexes Bis-Metals in the Core"J. Am. Chem. Soc.. 125. 878-879 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Araki, K.: "Doubly N-Confused Porphyrins as Efficient Sensitizers for Singlet Oxygen Generation"Chem. Lett.. 32. 244-245 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Taniguchi, R.: "Ring Size Selective Synthesis of meso-Aryl Expanded Porphyrins"Tetrahedron Lett.. 44. 2505-2507 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Facile Formation of N-Confused Porphyrin Dimers by Pt(II) Coordination to Outer-Nitrogens"Angew. Chem. Int. Ed.. 42. 2186-2188 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Maeda, H.: "N-Confused Porphyrin Bearing meso-Perfluorophenyl Groups : A Potential Agent that Forms Stable Squareplanar Complexes with Cu(II) and Ag(III)"Org. Lett.. 5. 1293-1296 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Synthesis and Structures of N-Confused 5,20- Diphenylporphyrin and Ag(III) Complex"Org. Lett.. 5. 1427-1430 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Maeda, H.: "2-Allenylbenzotriazole"Acta Crysatllogr. C. 59. o338-o339 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Liu, J. -C.: "Modulation of Axial Coordination in N-Confused Porphyrin-Antimony(V) Dibromide Complex by Proton Stimulus"Chem. Commun.. in press.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Furuta, H.: "Chemistry of N-confused Porphyrin : A Novel Porphyrin Isomer"J. Oleo Sci.. 3. 77-82 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Maeda, H.: "Hydrogen Bonding 1-D Chain Network of Cis-Doubly N- Confused Porphyrins"Supramolecular Chemistry. in press.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Araki, K.: "Acid-Base and Spectroelectrochemical Properties of Doubly N-Confused Porphyrins"Inorg. Chem.. 40. 2020-2025 (2001)

    • Related Report
      2002 Annual Research Report
  • [Publications] Pushpan, S.K.: "N-Confused Expanded Porphyrins : First Example of a Modified Sapphyrin with an Inverted N-Confused Pyrrole Ring"J. Am. Chem. Soc.. 123. 5138-5139 (2001)

    • Related Report
      2002 Annual Research Report
  • [Publications] Furuta, H.: "Metal Complexes of N-Confused Calix[4]phyrin Derivative-The First X-ray Structure of Organometallic Compound of Divalent Copper"Angew. Chem. Int. Ed.. 40. 2323-2325 (2001)

    • Related Report
      2002 Annual Research Report
  • [Publications] Furuta, H.: "NH Tautomerism of N-Confused porphyrin"J. Am. Chem. Soc.. 123. 6207-6208 (2001)

    • Related Report
      2002 Annual Research Report
  • [Publications] Furuta, H.: "Oxyindolophyrin : A Novel Fluoride Receptor Derived from N-Confused Corrole Isomer"J. Am. Chem. Soc.. 123. 6435-6436 (2001)

    • Related Report
      2002 Annual Research Report
  • [Publications] Shin, J.-Y: "Meso-Aryl Substituted Expanded Porphyrins"J. Am. Chem. Soc.. 123. 7190-7191 (2001)

    • Related Report
      2002 Annual Research Report
  • [Publications] Furuta, H.: "Theoretical Study of Stability, Structures, and Aromaticity of Multiply N-Confused Porphyrins"J. Org. Chem.. 66. 8563-8572 (2001)

    • Related Report
      2002 Annual Research Report
  • [Publications] Alagar, S.: "The First bis-Rh(I) Complex of N-Confused Porphyrin"Chem. Commun.. 1666-1667 (2001)

    • Related Report
      2002 Annual Research Report
  • [Publications] Furuta, H.: "Regioselective Oxidative Liberation of Aryl-Substituted Tripyrrinone Metal Complexes from N-Confused Porphyrin"Org. Lett.. 4. 181-184 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Furuta, H.: "Flexible Inner and Outer Coordination of Zn(II) N-Confused Porphyrin Complex"J. Am. Chem. Soc.. 124. 5622-5623 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Furuta, H.: "Confusion, Inversion, and Creation -A New Spring from Porphyrin Chemistry"Chem. Commun.. 1795-1804 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Shinmori, H: "Effective Face-to-face Dimerization of A Crown Ether Appended N-Confused porphyrins"Tetrahedron Lett.. 43. 4881-4884 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Shimizu, S.: "Perfluorinated meso-Aryl Expanded Porphyrins"Angew. Chem. Int. Ed.. 42. 78-82 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Furuta, H.: "Crystal Structures of Palladium(II) and Copper(II) Complexes of meso-Phenyl Tripyrrinone"Inorg. Chem. Commun.. 6. 162-164 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Furuta, H.: "Zinc Complex of N-confused Calix[4]phyrin"Inorg. Chem. Commun.. 6. 398-401 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Furuta, H.: "Chemistry of N-confused Porphyrin : A Novel Porphyrin Isomer"J. Oleo. Sci.. 3. 878-879 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Alagar, S.: "Doubly N-Confused Hexaphyrin : A Novel Aromatic Expanded Porphyrin that Complexes Bis-Metals in the Core"J. Am. Chem. Soc.. 125. 878-879 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Araki, K.: "Doubly N-Confused Porphyrins as Efficient Sensitizers for Singlet Oxygen Generation"Chem. Lett.. 32. 244-245 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Taniguchi, R.: "Ring Size Selective Synthesis of meso-Aryl Expanded Porphyrins"Tetrahedron Lett.. 44. 2505-2507 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Furuta, H.: "Facile Formation of N-Confused Porphyrin Dimers by Pt(II) Coordination to Outer-Nitrogens"Angew. Chem. Int. Ed.. 42(印刷中). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Maeda, H.: "N-Confused Porphyrin Bearing meso-Perfluorophenyl Groups : A Potential Agent that Forms Stable Squareplanar Complexes with Cu(II) and Ag(III)"Org. Lett.. 5(印刷中). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Araki: "Acid-Base and Spectro electro chemcil Properties of Dovlly N-Confused Porphyin"Inorg. Chem.. 40. 2020-2025 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Furuta: "Metal Complexes of N-Confused Calix [4] phyri Derivative"Angew. Chem. Int. Ed.. 40. 2323-2325 (2001)

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      2001 Annual Research Report
  • [Publications] H.Furuta: "NH Tautomerism of N-Confused porphyrin"J. Am. Chem. Soc.. 123. 6207-6208 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Furuta: "Oxyindolophyrin : A Novel Fluoride Receptor Derived from N-Confesed Corrob lsoner"J. Am. Chem. Soc.. 123. 6435-6436 (2001)

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      2001 Annual Research Report
  • [Publications] S.Alagar: "The First bis-Rh(I) complex of N-Confased Porphys"Chem. Commun.. 1666-1667 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Furuta: "Theovetical Study of Stability Structures and Aromaticety of Moltiply N-Confused Porphys"J. Org. Chem.. 66. 8563-8572 (2001)

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      2001 Annual Research Report
  • [Publications] H.Furuta: "Regioselective Oxidative Liberation of Aryl Substitutel Tripyrrinone Metal Complenes from N-Confused Porphys"Org. Lett.. 4. 181-184 (2002)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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