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Construction Method for Super Lattice Structure by Electreochemical Atomic Layer Epitaxy

Research Project

Project/Area Number 13554026
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 機能・物性・材料
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

UOSAKI Kohei  Hokkaido Univ., Grad. School of Sci., Prof., 大学院・理学研究科, 教授 (20133697)

Co-Investigator(Kenkyū-buntansha) KONDO Toshihiro  Ochanomizu Univ, Fac. of Sci., Asso. Prof., 理学部, 助教授 (70240629)
YAGI Ichizo  Hokkaido Univ., Grad. School of Sci., Lecturer, 大学院・理学研究科, 講師 (40292776)
國松 敬二  エクォスリサーチ(株), 札幌研究室, 研究室長
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥13,100,000 (Direct Cost: ¥13,100,000)
Fiscal Year 2003: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2002: ¥2,400,000 (Direct Cost: ¥2,400,000)
Fiscal Year 2001: ¥9,100,000 (Direct Cost: ¥9,100,000)
KeywordsElectrochemistry / Atomic layer epitaxy / Nanocluster / Cadmium chalcogenides / Gold / Self-assembled monolayer / Multi-nuclear metal cluster / Second harmonic generation / 固体 / 溶液界面 / SFG / 可視光ポンプ-SFGプローブ法 / 走査型プローブ顕微鏡 / 表面X線散乱法 / エピタキシャル成長 / 超格子構造形成法 / 金単結晶電極 / in situ STM / AFM / X線回析
Research Abstract

1. To clarify the mechanism of electrochemical atomic layer epitaxy (ECACE) and the characteristics of the ECALE layer, electrodeposition of Pd on Au(111) or Au(100) electrode was followed by electrochemical transient method and second harmonic generation.
2. CdTe was epitaxially grown on Si(111) by photoassisted-electrodeposition.
3. Electrochemical growths of metals such as Au, Pt and Pd, were monitored by in situ atomic force microscopy.
4. ECALE of CdS was achieved by growing Cd and S alternately. It was then dissolved by irradiation of polarized light in oxygen-safurated water to form a stripe structure.
5. By dipping Au or ITO substrate into solutions containing Gold nanoclusters protected by thiol SAMs with methyl, carboxylate, or ferrocen terminal group, and polelectrolytes alternately, multi-layers of electroactive gold nanoclusters were constructed. Similarly, multi-layers of CdS nanoclusters prepared by reversed-micelle technique were constructed. In both cases, all nanoclusters in the multilayers were electroactive.
6. Electrochemical molecular epitaxy of multi-nuclear metal complex was achieved.

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (58 results)

All Other

All Publications (58 results)

  • [Publications] H.Naohara et al.: "Thickness Dependent Electrochemical Reactivity of Epitaxially Electrodeposited Palladium Thin Layers on Au(111) and Au(100) Surfaces"J.Electroanal.Chem.. 500,No.1-2. 435-445 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "Formation and Electrochemical Characteristics of Multilayers of Au Nanoclusters Covered by Mixed Self-Assembled Monolayers of Three Kinds of Alkanethiols with Methyl, Ferrocene, or Carboxylate Terminal Group on Au(111) Surface"Chem.Lett.. NO.9. 930-931 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Kawamura et al.: "Evidence for the Diffusion of Au Atoms into the Te UPD Layer Formed on a Au(111) Substrate"J.Electrochem.Soc.. 149(2). C83-C88 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.E.Quayum et al.: "Mechanism for Nucleation and Growth of Electrochemical Palladium Deposition on an Au(111) Electrode"J.Electroanal.Chem.. 520(1-2). 126-132 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Takahashi et al.: "Heteroepitaxial Growth of CdTe on p-Si(111) Substrate by Pulsed-light-assisted Electrodeposition"Appl.Phys.Lett.. 80(12). 2117-2119 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Awatani et al.: "Second Harmonic Generation Study on Electrochemical Deposition of Palladium on a Polycrystalline Gold Electrode"J.Electroanal.Chem.. 524-525. 184-193 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Uosaki et al.: "Electron and Ion Transfer through Multilayers of Gold Nanoclusters Covered by Self-Assembled Monolayers of Alkylthiols with Various Function Groups"Faraday Discuss. 121. 373-389 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "In situ Structural Study on Underpotential Deposition of Ag on Au(111) Electrode Using Surface X-ray Scattering Technique"J.Electroanal.Chem.. 532(1-2). 201-205 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Saito et al.: "In situ Study of Ultrathin Film Formation on Au(111) Surface in Propylene Carbonate by Scanning Tunneling Microscopy under Potential Control"J.Electrochem.Soc.. 149(8). E286-E291 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "A Novel Spectroelectrochemical Cell for in situ Surface X-ray Scattering Measurements of Single Crystal Disk Electrodes"Electrochim.Acta. 47(19). 3075-3080 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Saito et al.: "Surface Film Formation and Lithium Underpotential Deposition on Au(111) Surfaces in Propylene Carbonate - In Situ Scanning Tunneling Microscopy Study"J.Electrochem.Soc.. 150 No.4. A532-A537 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Abe et al.: "Electrochemically Controlled Layer-by-Layer Deposition of Metal Cluster Molecular Multilayers on Gold"Angewandte Chemie, International Edition. 42,No.25. 2912-2915 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Song et al.: "Electron and Ion Transport through Multilayers of Au Nanoclusters Covered by Self-Assembled Monolayers"J.Electroanal.Chem.. 554-555. 285-293 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Song et al.: "Construction and Electrochemical Characteristics of Multilayer Assemblies of A Nanoclusters Protected by Mixed Self-assembled Monolayers on Tin-doped Indium Oxide"PCCP. 5. 5279-5284 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Uosaki et al.: "Photophysical and Photoelectrochemical Characteristics of Multilayers of CdS Nanoclusters"Faraday Discuss. 125. 39-53 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: ""Underpotential Deposition. Atomically Controlled Depositon and Dissolution of Noble Metals", in Encyclopedia of Electrochemistry. Volume 1 : Thermodynamics and Electrified Interfaces (Ed. by A.Bard and M.Stratmann)"WILEY-VCH, Weinheim. 42 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Uosaki et al.: ""Electrochemical Epitaxial Growth, Structure, and Electrocatalytic Properties of Noble Metal Thin Films on Au(111) and Au(100)", in Thin Films : Preparation, Characterization, Applications (Ed. by M.P.Soriaga, J.Stickney, L.A.Bottomley and Y.-G.Kim)"Kluwer Academic/Plenum Publishers, New York. 19 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Uosaki et al.: ""Structural Study of Electrochemically Deposited Copper on p-GaAs(001) by Atomic Force Microscopy, Surface X-Ray Absorption Fine Structure and Optical Reflectance and Scattering Measurements, in Electrochemical Science and Technology of Copper, PV 2000-30 (Ed. P.Vanysek, M.Alodan, J.Lipkowski and O.M.Magnussen)"The Electrochemical Society, Pennington. 20 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Naohara et al.: "Thickness Dependent Electrochemical Reactivity of Epitaxially Electrodeposited Palladium Thin Layers on Au(111) and Au(100) Surfaces"J.Electroanal.Chem.. 500,No.1-2. 435-445 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "Formation and Electrochemical Characteristics of Multilayers of Au Nanoclusters Covered by Mixed Self-Assembled Monolayers of Three Kinds of Alkanethiols with Methyl, Ferrocene, or Carboxylate Terminal Group on Au(111) Surface"Chem.Lett.. 930-931 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Kawamura et al.: "Evidence for the Diffusion of Au Atoms into the Te UPD Layer Formed on a Au(111) Substrate"J.Electrochem.Soc.. 149(2). C83-C88 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.E.Quayum et al.: "Mechanism for Nucleation and Growth of Electrochemical Palladium Deposition on an Mechanism for Nucleation and Growth of Electrochemical Palladium Deposition on an Au(111) Electrod"J.Electroanal.Chem.. 520(1-2). 126-132 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Takahashi et al.: "Heteroepitaxial Growth of CdTe on p-Si(111) Substrate by Pulsed-light-assisted Electrodeposition"Appl.Phys.Lett.. 80,No.12. 2117-2119 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Awatani et al.: "Second Harmonic Generation Study on Electrochemical Deposition of Palladium on a Polycrystalline Gold Electrodes"J.Electroanal.Chem.. 524-525. 184-193 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Uosaki et al.: "Electron and Ion Transfer through Multilayers of Gold Nanoclusters Covered by Self-Assembled Monolayers of Alkylthiols with Various Functional Group"Faraday Discuss.. 121. 373-389 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "In situ Structural Study on Underpotential Deposition of Ag on Au(111) Electrode Using Surface X-ray Scattering Technique"J.Electroanal.Chem.. 532(1-2). 201-205 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Saito et al.: "In situ Study of Ultrathin Film Formation on Au(111) Surface in Propylene Carbonate by Scanning Tunneling Microscopy under Potential Control"J.Electrochem.Soc.. 149(8). E286-E291 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Kondo et al.: "A Novel Spectroelectrochemical Cell for in situ Surface X-ray Scattering Measurements of Single Crystal Disk Electrodes"Electrochim.Acta. 47(19). 3075-3080 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Saito et al.: "Surface Film Formation and Lithium Underpotential Deposition on Au(111) Surfaces in Propylene Carbonate -In Situ Scanning Tunneling Microscopy Study"J.Electrochem.Soc.. 150,No.4. A532-A537 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] M.Abe et al.: "Electrochemically Controlled Layer-by-Layer Deposition of Metal Cluster Molecular Multilayers on Gold"Angewandte Chemie, International Edition. 42,No.25. 2912-2915 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Song et al.: "Electron and Ion Transport through Multilayers of Au Nanoclusters Covered by Self-Assembled Monolayers"J.Electroanal.Chem.. 554-555. 385-393 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] W.Song et al.: "Construction and Electrochemical Characteristics of Multilayer Assemblies of Au Nanoclusters Protected by Mixed Self-assembled Monolayers on Tin-doped Indium Oxides"PCCP. 5. 5279-5284 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Uosaki et al.: "Photophysical and Photoelectrochemical Characteristics of Multilayers of CdS Nanoclusters"Faraday Discuss.. 125. 39-53 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye et al.: "Underpotential Deposition-Atomicaily Controlled Depositon and Dissolution of Noble Metals"Encyclopedia of Electrochemistry. Volume 1. Thermodynamics and Electrified Interfaces (Ed. by A.Bard and M.Stratmann) (WILEY-VCH, Weinheim). 471-512 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Uosaki et al.: "Electrochemical Epitaxial Growth, Structure, and Electrocatalytic Properties of Noble Metal Thin Films on Au(111) and Au(100)"Thin Films : Preparation, Characterization, Applications (Ed. by M.P.Soriaga, J.Stickney, L.A.Bottomley and Y.-G.Kim.) (Kluwer Academic/Plenum Publishers, New York). 17-35 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Uosaki et al.: "Structural Study of Electrochemically Deposited Copper on p-GaAs(001) by Atomic Force Microscopy, Surface X-Ray Absorption Fine Structure and Optical Reflectance and Scattering Measurements"Electrochemical Science and Technology of Copper (Ed. P.Vanysek, M.Alodan, J.Liakowski and O.M.Magnussen) (The Electrochemical Society, Pennington). PV 2000-30. 77-96 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Ye: "Surface Molecular Structures of Langmuir-Blodgett Films of Stearic Acid on Sol Substrates Studied by Sum Frequency Generation Spectroscopy"Langmuir. 19・6. 2238-2242 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Saito: "Surface Film Formation and Lithium Underpotential Deposition on Au(111) Surface in Propylene Carbonate - In Situ Scanning Tunneling Microscopy Study"J.Electrochem.Soc.. 150・4. A532-A537 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Abe: "Electrochemically Controlled Layer-by-Layer Deposition of Metal Cluster Molecula Multilayers on Gold"Angewandte Chemie, International Edition. 42・25. 2912-2915 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] W.Song: "Electron and Ion Transport through Multilayers of Au Nanoclusters Covered by Self-Assembled Monolayers"J.Electroanal.Chem.. 554-555. 385-393 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] W.Song: "Construction and Electrochemical Characteristics of Multilayer Assemblies of A Nanoclusters Protected by Mixed Self -assembled Monolayers on Tin-doped Indium Oxid"PCCP. 5. 5279-5284 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Uosaki: "Photophysical and Photoelectrochemical Characteristics of Multilayers of CdS Nanoclusters"Faraday Discuss.. 125. 39-53 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 魚崎浩平: "ナノテクノロジーハンドブックI編 創る(第1分冊)"オーム社. 375 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Kawamura: "Evidence for the Diffusion of Au Atoms into the Te UPD Layer Formed on a Au( 111) Substrate"Journal of Electrochemical Society. 149. E1-E5 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.E.Quayam: "Mechanism for Nucleation and Growth of Electrochemical Palladium Deposition on an Au(111) Electrode"Journal of Electroanalytical Chemistry. 520. 126-132 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.Takahashi: "Heteroepitaxial Growth of CdTe on p-Si(111) Substrate by Pulsed-Light-Assisted Electrodeposition"Applied Physics Letters. 80. 2117-2119 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Kondo: "In situ Structural Study on Underpotential Deposition of Ag on Au (111) Electrode Using Surface X-ray Scattering Technique"Journal of Electroanalytical Chemistry. 532. 201-205 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Saito: "In situ Study of Ultra-thin Film Formation on Au(111) Surface in Propylene Carbonate by Scanning Tunneling Microscopy Under Potential Control"Journal of Electrochemical Society. 149. E286-E291 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Kondo: "A Novel Spectroelectrochemical Cell for in situ Surface X-ray Scattering Measurements of Single Crystal Disk Electrodes"Electrochimica Acta. 47. 3075-3080 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Saito: "In Situ Scanning Tunneling Microscopy Study on Surface Film Formation and Lithium Underpotential Deposition Process on Au(111) Surface in Propylene Carbonate"Journal of Electrochemical Society. (in press).

    • Related Report
      2002 Annual Research Report
  • [Publications] Hideo Naohara et al.: "Thickness Dependent Electrochemical Reactivity of Epitaxially Electrodeposited Palladium Thin Layers on Au(111) and Au(100)"Journal of Electroanalytical Chemistry. 500・1-2. 435-445 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Toshihiro Kondo et al.: "Formation and Electrochemical Characteristics of Multilayers of Au Nanoclusters Covered by Mixed Self-Assembled Monolayers of.Three Kinds of Alkanethiols with Methyl, Ferrocene, or Carboxylate Terminal Group on Au(111) Surface"Chemistry Letters. 930-931 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H. Kawamura et al.: "Evidence for the Diffusion of Au Atoms into the Te UPD Layer Formed on a Au(111) Substrate"Journal of Electrochemical Society. 149・2. C83-C88 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.E. Quayam et al.: "Mechanism for Nucleation and Growth of Electrochemical Palladium Deposition on an Au(111) Electrode"Journal of Electroanalytical Chemistry. (in press).

    • Related Report
      2001 Annual Research Report
  • [Publications] Tadashi Awatani et al.: "Second Harmonic Generation Study on Electrochemical Deposition of Palladium on a Polycrystalline Gold Electrode"Journal of Electroanalytical Chemistry. (in press).

    • Related Report
      2001 Annual Research Report
  • [Publications] Toshihiro Kondo et al.: "In situ Structural Study on Underpotential Deposition of Ag on Au(111) Electrode Using Surface X-ray Scattering Technique"Journal of Electroanalytical Chemistry. (in press).

    • Related Report
      2001 Annual Research Report
  • [Publications] M. Takahashi et al.: "Heteroepitaxial Growth of CdTe on p-Si(111) Substrate by Pulsed-light Assisted Electrodeposition"Applied Physics Letters. (in press).

    • Related Report
      2001 Annual Research Report
  • [Publications] Toshiya Saito et al.: "In situ Study of Ultra-thin Film Formation on Au(111) Surface in Propylene Carbonate by Scanning Tunneling Microscopy Under Potential Control"Journal of Electrochemical Society. (in press).

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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