| Project/Area Number |
13555238
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 展開研究 |
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| Research Field |
工業物理化学
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| Research Institution | Kyushu University |
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Principal Investigator |
SHIMANOE Kengo Kyushu University, Faculty of Engineering Sciences, Department of Materials Science, Associate Professor, 大学院・総合理工学研究院, 助教授 (10274531)
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| Co-Investigator(Kenkyū-buntansha) |
NAKAHARA Takeshi Figaro Engineering Inc., Maneger, 開発部, 部長(研究職)
SAKAI Go Kyushu University, Faculty of Engineering Sciences, Department of Materials Science, Research Associate, 大学院・総合理工学研究院, 助手 (40284567)
YAMAZOE Noboru Kyushu University, Faculty of Engineering Sciences, Department of Materials Science, Professor, 大学院・総合理工学研究院, 教授 (40037817)
OGINO Kaoru Yazaki Meter Co., Ltd, Chief, ガス機器開発事業部, 課長(研究職)
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| Project Period (FY) |
2001 – 2002
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| Project Status |
Completed (Fiscal Year 2002)
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| Budget Amount *help |
¥13,700,000 (Direct Cost: ¥13,700,000)
Fiscal Year 2002: ¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 2001: ¥10,500,000 (Direct Cost: ¥10,500,000)
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| Keywords | CO_2 sensor / Planar type / Environmental monitoring / Alkoxides / glass forming component / Dependence of humidity / Thick film / BiCuVOx / 環境計器 / ガスセンサ / 二酸化炭素 / ナトリウムイオン導電体 / スクリーン印刷 / ガラス成分 / Nernst応答 / 水蒸気 |
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| Research Abstract |
A compact C0_2 sensor has been in a great demand for monitoring or controlling C0_2 in various environments. Among the various types of C0_2 sensors so far proposed, the potentiometric type combining a solid electrolyte with an auxiliary phase of metal carbonate is particularly attractive from its excellent sensing capability. From a practical point of view, however, the devices still remain prototype in structure. In this study, we tried to design planar type C0_2 sensor using NASICON thick film for the lower fabrication cost and down sizing of sensor devices.
(1) NASICON (Na_3Zr_2Si_2PO_<12>) powder was prepared by a sol-gel method and was added with α-terpineol. The resulting paste was screen-printed 30μm thick on the alumina substrate. NASICON formation in thick film was almost complete after calcination at 950 and 1000℃, although film densification was still poor. The resulting Planar device could work fairly well as a C0_2 sensor under dry conditions but was unable to work at all
… More
under humid condition.
(2) It was attempted to improve the density and mechanical strength of NASICON thick film with addition of glass forming components. The EMF of the resulting device exhibited excellent response to C0_2 not only in dry but in humid air, although the slope of the Nernstian correlations tended to be slightly less steep than the theoretical one.
(3) Densification of thick film of NASICON was explored for the use in a planar C0_2 sensor. Among the many kinds of dispersants of NASICON powder for screen printing method, ethylene glycol was found to exhibit the best densified NASICON thick film after calcination at 1000℃. The resulting planar device showed good C0_2 sensing properties under humid as well as dry conditions.
(4) In order to reduce the disturbance by humidity, applicability of an oxide ionic conductor of BiCuVOx as a counter electrode material was examined. The oxide-incorporated devices exhibited stable C0_2 sensing properties under dry as well as humid conditions. In addition, the dependence of EMF on relative humidity could be reduced considerably with the oxide-incorporated devices. Less
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