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Preparation of polymer complexes with π-conjugated polymer ligands and control of catalytic functionalities

Research Project

Project/Area Number 13555258
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 高分子合成
Research InstitutionTokyo Institute of Technology

Principal Investigator

YAMAMOTO Takakazu  Tokyo Institute of Technology, Chemical Resources Laboratory, Professor, 資源化学研究所, 教授 (10016743)

Co-Investigator(Kenkyū-buntansha) SATOH Yasushi  Daicel Chemical Industries LTD, Himeji Research Center, Researcher, 総合研究所, 研究員
FUKUMOTO Hiroki  Tokyo Institute of Technology, Chemical Resources Laboratory, Associate Professor, 資源化学研究所, 助手 (70313369)
KANBARA Takaki  Tokyo Institute of Technology, Chemical Resources Laboratory, Associate Professor, 資源化学研究所, 助教授 (90204809)
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥12,700,000 (Direct Cost: ¥12,700,000)
Fiscal Year 2003: ¥3,900,000 (Direct Cost: ¥3,900,000)
Fiscal Year 2002: ¥4,000,000 (Direct Cost: ¥4,000,000)
Fiscal Year 2001: ¥4,800,000 (Direct Cost: ¥4,800,000)
KeywordsOrganometallic chemistry / Polycondensation / π-Conjugated / Conductive polymer / Polymer ligand / Polymer metal complex / Catalytic activity / Optical functionalities / 触媒特性 / 機能制御
Research Abstract

Various it-conjugated polymer ligands have been prepared by using organometallic coupling reactions such as Ni-and Pd-complex mediated C-C coupling. The obtained polymer ligands were constituted of coordinating units such as pyridine, 2,2'-bipyridyl, 1,10-phenanthroline, biimidazole, 8-quinolinol, 2,2'-bithiaziazole, and Salen type ligand. According to expansion of the it-conjugation system, the polymers showed shifts of the UV-vis absorption peak of the unit to a longer wavelength. The it-conjugated polymer ligands form various metal complexes on addition of metal species such as Cu(II), Ni(II), Ru(II), and Zn(II) compounds. On the complex formation, changes in the UV-vis absorption spectra were observed. The metal complexes often showed photoluminescence. The metal complexes also showed functionalities such as (1)electrochemical activity which were expected to he related electrocatalytic reactions, (2)optical functionalities, and (3)electrical conductivity. Some complexes are known to serve as catalysts for photoevolution of H_2 from aqueous media and for redox reactions.

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (62 results)

All Other

All Publications (62 results)

  • [Publications] T.Yamamoto, T.Nakamura, H.Fukumoto, K.Kubota: "Preparation and Characterizarion of Regioregular Head-to-Tail pi-Conjugated Poly(pyridine)s"Chem.Lett.. 502-503 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] I.Nurulla, T.Morikita, H.Fukumoto, T.Yamamoto: "Preparation and Properties of Poly(2-alkylbenzimidazole-alt-thiophene)s with Long Alkyl Side Chans"Macromol.Chem.Phys.. 202. 2335-2340 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Morikita, T.Yamamoto: "Electrochemical Determination of Diffusion Coefficient π-Conjugated Polymers Containing Ferrocene Unit"J.Organomet.Chem.. 637-639,809-812 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Morikita, I.Yamaguchi, T.Yamamoto: "New Charge Transfer-Type π-Conjugated Poly(aryleneethynylene) Containing Benzo[2,1,2]thiadizaole as the Electron-Accepting Unit"Adv.Mater.. 13. 1862-1864 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] I.Nurulla, A.Tanimoto, K.Shiraishi, T.Yamamoto, S.Sasaki: "Preparation of Copolymers of 2-decylbenzimidazol and N-methyl-2-decylbenzimidazole with Thiophenes and Chemical Properties of the Copolymers"Polymer. 43. 1287-1293 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, B.-L.Lee: "New Soluble, Coplanar Poly(naphtahene-2,6- diyl)-Type p-Conjugated Polymer, Poly(pyrimido[5,4-d]pyrimidine-2,5- diyl), with Nitrogen Atoms at All of the o-Positions. Synthesis, Solid Structure, Optical Properties, Self-Assembling Plenamena, and Redox Behavior"Macromolecules. 35. 2993-2999 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] B.-L.Lee, T.Yamamoto: "Synthesis of Light-Emitting π-Conjugated Poly (pyrido [5,4-d]pyrimidone-2,6-diyl) with Bulky Side Chains and High Molecular Weight"Polymer. 43. 4531-4534 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] I.Yamaguchi, T.Iijima, T.Yamamoto: "Synthesis and Reactivity of Al(Et)(q')_2 (q'=2-Methylquinolilato) and Crystal Structures of [Al(Et)_2q]_2 and Al(q')_2q (q=8-quinolilato)"J.Organomet.Chem.. 654. 229-232 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Fukumoto, T.Yamamoto: "Synthesis and Properties of Trasition Metal Complexes Assembed by Coordination to Rigid π-Conjugated Aryleneethynylene Ligands"Mol.Cryst.Liq.Cryst.. 379. 437-442 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] I.T.Yamamoto, T.Uemura: "Synthesis and Characterization of New π-Conjugated Polymers Constituted of Five-Membered Rings : Poly (2,2'-biimidazole-5,5'-diyl)s"J.Polym.Sci.Part A, Polym.Chem.. 40. 2686-2688 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, K.Anzai, H.Fukumoto: "Preparation of Soluble π-Conjugated Poly(5,6-dialkoxy-1,10-phenanthroline-3,8-diyl)s. Their Stacking Behavior and Function as a π-Conjugated Polymer Ligand"Chem.Lett.. 774-775 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, M.Arai, H.Kokubo, S.Sasaki: "Comparison of Organometallic Copolymerization of Thiophene with 4-Alkylthiazole and 3-Alkylthiophene. Control of Regioregularity in the Copolymerization with 4-Alkyithiazole"J.Polym.Sci.Part A : Polym.Chem.. 41. 1449-1453 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yasuda, I.Yamaguchi, T.Yamamoto: "New Soluble 1,10- Phenanthrolin- Containing π-Conjugated Polymer : Synthesis and Effect of Metal Complexation on Its Optical Properties"Adv.Mater.. 15. 293-296 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] B.-K.Choi, T.Yamamoto: "Synthesis and properties of new n-type π-conjugated polybipyridines and polybiphenylenes with various bridging units"Electrochem.Commun.. 5. 566-570 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, I.Yamaguchi: "Enzymatic Synthesis of Poly(quinolinol) and Its Fluorescent Aluminum Complex"Polym.Bull.. 50. 55-60 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, Y.Saitoh, K.Anzai, H.Fukumoto, T.Yasuda, Y.Fujiwara, B.-K.Choi, K.Kubota, T.Miyamae: "Poly(1,10-phenanthroline-3,8-diyl) and Its Derivatives. Preparation, Optical and Electrochemical Properties, Solid Structure, and Their Metal Complexes"Macromolecules. 36. 6722-6729 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yasuda, T.Yamamoto: "Synthesis and Characterization of New Luminscent 1,10-Phenanthroline-and Pyridine-Containing π-Conjugated Polymers. Their Optical Response to Protic Acid, M^<n+>, and Solvents"Macromolecules. 36. 7513-7519 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, M.Arai, H.Kokubo, S.Sasaki: "Copolymers of Thiophene and Thiazole. Regioregulation in Synthesis, Stacking Structure, and Optical Properties"Macromolecules. 36. 7986-7993 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Anzai, H.Fukumoto, T.Yamamoto: "Direct Alkylation and Phenylation of 3,8-Dibromo-1,10-phenanthroline with Grignard Reagents"Chem.Lett.. 33. 252-253 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Iijima, T.Yamamoto: "Preparation of Main-Chain Type Quinolinol Polymers via Organometallic Polyconsation"Macromol.Rapid Commun.. 25. 669-672 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, K.Anzai, T.Iijima, H.Fukumoto: "Alkylation of 3,8- Dibromo- 1,10 -phenanthroline-3,8-diyl)s Derived from the Alkylated Monomers"Macromolecules. 37. 3064-3067 (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, T.Nakamura, H.Fukumoto, K.Kubota: "Preparation and Characterizarion of Regioregular Head-to-Tail pi-Conjugated Poly(pyridine)s"Chem. Lett.. 502-503 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] I.Nurulla, T.Morikita, H.Fukuinoto, T.Yamamoto: "Preparation and Properties of Poly(2-alkylbenzimidazole-alt-thiophene)s with Long Alkyl Side Chans"Macromol. Chem. Phys. 202. 2335-2340 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Morikita, T.Yamamoto: "Electrochemical Determination of Diffusion Coefficient it-Conjugated Polymers Containing Ferrocene Unit"J. Organomet. Chem.. 637-369. 809-812 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Morikita, I.Yainaguchi, T.Yamamoto: "New Charge Transfer-Type π-Conjugated Poly(aryleneethynylene) Containing Benzo[2,1,2]thiadizaole as the Electron-Accepting Unit"Adv. Mater.. 13. 1862-1864 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] I.Nurulla, A.Tanimoto, K.Shiraishi, T.Yamamoto, S.Sasaki: "Preparation of Copolymers of 2-decylbenzimidazol and N-methyl-2-decylbenzimidazole with Thiophenes and Chemical Properties of the Copolymers"Polymer. 43. 1287-1293 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, B.-L.Lee: "New Soluble, Coplanar Poly(naphtahene-2,6-diyl)-Type p-Conjugated Polymer, Poly(pyrimido[5,4-d]pyrimidme-2,5-diyl), with Nitrogen Atoms at All of the o-Positions. Synthesis, Solid Structure, Optical Properties, Self-Assembling Plenamena, and Redox Behavior"Macromolecules. 35. 2993-2999 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] B.-L.Lee, T.Yamamoto: "Synthesis of Light-Emitting it-Conjugated Poly (pyrido [5,4-d]pyrirnidone-2,6-diyl) with Bulky Side Chains and High Molecular Weight"Polymer. 43. 4531-4534 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] I.Yamaguchi, T.Iijima, T.Yamamoto: "Synthesis and Reactivity of Al(Et)(q')_2 (q'=2-Methylquinolilato) and Crystal Structures of [Al(Et)_2q]_2 and Al(q')_2q (q=8-quinolilato)"J. Organomet. Chem.. 654. 229-232 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Fukumoto, T.Yamamoto: "Synthesis and Properties of Trasition Metal Complexes Assembed by Coordination to Rigid it-Conjugated Aryleneethynylene Ligands"Mol. Cryst. Liq. Cryst.. 379. 437-442 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, T.Uemura: "Synthesis and Characterization of New it-Conjugated Polymers Constituted of Five-Membered Rings : Poly (2,2'-biimidazole-5,5'-diyl)s"J. Polym. Sci. Part A, Polym. Chem.. 40. 2686-2688 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, K.Anzai, H.Fukumoto: "Preparation of Soluble it-Conjugated Poly(5,6-dialkoxy-l,10-phenanthroline-3,8-diyl)s. Their Stacking Behavior and Function as a it-Conjugated Polymer Ligand"Chem. Lett.. 774-775 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, M.Arai, H.Kokubo, S.Sasaki: "Comparison of Organometallic Copolymerization of Thiophene with 4-Alkylthiazole and 3-Alkylthiophene. Control of Regioregularity in the Copolymerization with 4-Alkylthiazole"J. Polym. Sci. Part A : Polym. Chem.,. 41. 1449-1453 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yasuda, I.Yamaguchi, T.Yamamoto: "New Soluble 1,10-Phenanthrolin-Containing it-Conjugated Polymer : Synthesis and Effect of Metal Complexation on Its Optical Properties"Adv. Mater.. 15. 293-296 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] B.-K.Choi, T.Yamamoto: "Synthesis and properties of new n-type it-conjugated polybipyridines and polybiphenylenes with various bridging units"Electrochem. Commun.. 5. 566-570 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, I.Yamaguchi: "Enzymatic Synthesis of Poly(quinolinol) and Its Fluorescent Aluminum Complex"Polym. Bull.. 55-60 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, Y.Saitoh, K.Anzai, H.Fukumoto, T.Yasuda, Y.Fujiwara, B.-K Choi, K.Kubota, T.Miyamae: "Poly(1,10-phenanthroline-3,8-diyl) and Its Derivatives. Preparation, Optical and Electrochemical Properties, Solid Structure, and Their Metal Complexes"Macromolecules. 36. 6722-6729 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yasuda, T.Yamamoto: "Synthesis and Characterization of New Luminscent 1,10-Phenanthroline-and Pyridine-Containing π-Conjugated Polymers. Their Optical Response to Protic Acid, M^<n+>and Solvents"Macromolecules. 36. 7513-7519 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, M.Arai, H.Kokubo, S.Sasaki: "Copolymers of Thiophene and Thiazole. Regioregulation in Synthesis, Stacking Structure, and Optical Properties"Macromolecules. 36. 7986-7993 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Anzai, H.Fukumoto, T.Yamamoto: "Direct Alkylation and Phenylation of 3,8-Dibromo-1,10-phenanthroline with Grignard Reagents"Chem. Lett.. 33. 252-253 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.IIjima, T.Yamamoto: "Preparation of Main-Chain Type Quinolinol Polymers via Organometallic Polyconsation"Macromol. Rapid Commun.. 25. 669-672 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Yamamoto, K.Anzai, T.Iijima, H.Fukumoto: "Alkylation of 3,8-Dibromo-1,10 -phenanthroline-3,8-diyl)s Derived from the Alkylated Monomers"Macromolecules. 37. 3064-3067 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Takakazu Yamamoto: "Synthesis of pi-Conjugated Polymers Bearing Electronic and Optical Functionalities by Organometallic Polycondensations and Chemical Properties and Applications of the pi-Conjugated Polymers"Synlett. (4). 425-450 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Takakazu Yamamoto: "Synthesis and Chemical Properties of pi-Conjugated Poly(imidazole-2,5-diyl)s"Macromolecules. 36. 1047-1053 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Takakazu Yamamoto: "Poly(1,10-phenanthroline-3,8-diyl) and Its Derivatives. Preparation, Optical and Electrochemical Properties, Solid Structure, and Their Metal Complexes"Macromolecules. 36. 6722-6729 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Takuma Yasuda: "Synthesis and Characterization of New Luminscent 1,10-Phenanthroline-and Pyridine-Containing pi-Conjugated Polymers. Their Optical Response to Protic Acid, Mn+, and Solvents"Macromolecules. 36. 7513-7519 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Byoung-Ki Choi: "Synthesis and properties of new n-type pi-conjugated polybipyridines and polybiphenylenes with various bridging units"Electrochemistry Communications. 5. 566-570 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Takaki Kanbara: "Preparation of Poly(arylenediphosphine)s by Palladium-Catalyzed Polycondensation : Formation of Polymer Transition-Metal Complexes and Catalytic Reaction"J. Polym. Sci. Part A. Polym. Chem.. 40. 2637-2647 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Takakazu Yamamoto: "Synthesis and Chemical Properties of π-Conjugated Poly(Imidazole-2.5-diyl)s"Macromolecules. 36. 1047-1053 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Isao Yamaguchi: "Synthesis and Reactivity of AI(Et)q_2' (q'= 2-methyl-8-quinolinolato) and Crystal Structures of [Al(Et)2q]2 and Alq2'q (q=2-quinolinolato)"J. Organometal. Chem.. 654. 229-232 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Chi-han Lee: "Synthesis of Novel Nematic Liquid Crystals 3,3'-dimethyl-2.2'-bipyridyl"Liquid Crystals. 29. 67-70 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Takakazu Yamamoto: "Neutral Poly(3.4-ethylenedioxythiophene-2,5-diyl)s : Preparation by Organometallic Polycondensation and their Unique p-doping Behavior"Polymer. 43. 711-719 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Yukiko Muramatsu: "Combinatorial Synthesis and Screening for Blue Luminescent π-Conjugated Polymer Thin Film"Applied Surface Science. 189. 319-326 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Takakazu Yamamoto: "Cross-coupling Reactions for Preparation of π-Conjugated Polymers"J. Organometal. Chem.. 653. 195-199 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Kouichi Shiraishi: "New π-Conjugated Polymers Constituted of Dialkoxybenzodithiophene Units : Synthesis and Electronic Properties"Synthetic Metals. 130. 139-147 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Bang-Lin Lee: "Synthesis of Light-emitting π-Conjugated Poly(pyrimido[5,4-d]-pyrimidine-2.6-diyl) with Bulky Side Chains and High Molecular Weight"Polymer. 43. 4531-4534 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Yamamoto: "Molecular Alignment of Head-to-Tail-Type Poly(3-hexylthiophene -2, 5-diy) and Related Polymers and Compounds on Substrates"J. Polym. Sci. B, Polym. Phys.. 39. 1713-1718 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] I.Nurulla: "Preparation and Properties of Poly [(2-alkylbenzimidazole)-alt-thiophene]s with Long Alkyl Side Chain"Macromol. Chem. Phys.. 202. 2335-2340 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Yamamoto: "Neutral Poly(3, 4-ethylenedioxythiophene-2, 5-diyl)s : Preparation by Organometallic Polycondensation and Their Unique p-doping Behavior"Polymer. 43. 711-719 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Shiraishi: "Preparation of a Soluble and Neutral Alkyl Derivative of Poly(3, 4-ethylenedioxythiophene) and its Optical Properties"Polymer. 42. 7229-7232 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Yamamoto: "Organometallic C-N Coupling between N, N'-dichloro-p-benzoquinone Diimine and Grignard Reagents and its Application to Synthesis of Polyanilines"Tetrahedron Lett.. 42. 8653-8656 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Morikita: "Electrochemical Determination of Diffusion Coefficient of π-Conjugated Polymers Containing Ferrocene Unit"J. Organometal. Chem.. 637-639. 809-812 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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