| Project/Area Number |
13640375
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
固体物性Ⅱ(磁性・金属・低温)
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| Research Institution | Okazaki National Research Institutes |
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Principal Investigator |
NAKAMURA Toshikazu Okazaki National Research Institutes, Institute for Molecular Science, Associate Professor, 分子科学研究所, 助教授 (50245370)
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| Co-Investigator(Kenkyū-buntansha) |
FUJIYAMA Shigeki Okazaki National Research Institutes, Institute for Molecular Science, Research Associate, 助手 (00342634)
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| Project Period (FY) |
2001 – 2003
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| Project Status |
Completed (Fiscal Year 2003)
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| Budget Amount *help |
¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 2003: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 2002: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2001: ¥1,800,000 (Direct Cost: ¥1,800,000)
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| Keywords | Organic Conductors / NMR / ESR / SDW / Charge Order / 電荷秩序 |
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| Research Abstract |
In this project, we performed the microscopic investigation to clarify the low temperature electronic states of one-dimensional organic conductors.
(EDT-TTF)2AuBr2 is a one-dimensional 1/4-filled system. We carried out SQUID, EPR, and 1H-NMR measurements. We found that(EDT-TTF)2AuBr2 which undergoes an SDW transition at 16K. We observed an anomalous second-peak of the NMR spin-lattice relaxation rate in the magnetic phase, indicating a successive SDW phase transitions. Moreover. the 1H-NMR line shape changes with the second phase transition. It is likely that the origin of the successive SDW phase transitions is a reconstruction of the magnetic structure.
Magnetic resonance investigations were performed for a series of one-dimensional organic conductors, (TMTTF)2X. We found that the (TMTTF)2X salts are roughly divided into three groups according to the anisotropy of the ESR linewidth at low temperatures. We concluded their origins due to the three types of charge configurations. We also performed 13C NMR study for typical (TMTTF)2X salts. In (TMTTF)2SCN, we found anomalous spin relaxation process. Possible competition between the anion ordering and 4kF CDW is likely.
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