Synthesis, Structure, and Reactivities of Germylborates
| Project/Area Number |
13640542
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Gakushuin University |
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Principal Investigator |
MOCHIDA Kunio Faculty of Science, Professor, 理学部, 教授 (20118772)
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| Co-Investigator(Kenkyū-buntansha) |
NANJO Masto Faculty of Science, Assistant Professor, 理学部, 助手 (50302352)
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| Project Period (FY) |
2001 – 2002
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| Project Status |
Completed (Fiscal Year 2002)
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| Budget Amount *help |
¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 2002: ¥700,000 (Direct Cost: ¥700,000)
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| Keywords | Germylborate / Ate complex / X-ray diffraction analysis / Catalytic reaction / X-線構造解析 / ゲルマニウム / ホウ素 / X線結晶構造 / 水溶性 / 反応特異性 |
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| Research Abstract |
The structure and reactivity of lithium(germyl)triphenylborates, prepared from unsolvated germyllithium and triphenylboran, with organic substrates in methanol were investigated. The germylborates reacted with acetylenes, organic halides, and acyl halides to give the corresponding germyl-substituted compounds. From the reaction with carbonyl compounds, esters, carboxylic acids, and alkenes, germylborates were completely recovered.
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Report
(3 results)
Research Products
(5 results)
