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Improvement of Sentivity and Speed of the Determination of Trace Elements by High Power Microwave Induced Plasma Atomic Emission Spectrometry

Research Project

Project/Area Number 13650872
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 工業分析化学
Research InstitutionOsaka Prefecture University

Principal Investigator

NAKAHARA Taketoshi  Osaka Prefecture University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (20081309)

Co-Investigator(Kenkyū-buntansha) ABE Iwao  Osaka Prefecture University, Graduate School of Engineering, Assistant Professor, 大学院・工学研究科, 講師 (60081311)
Project Period (FY) 2001 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2003: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 2002: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 2001: ¥1,600,000 (Direct Cost: ¥1,600,000)
KeywordsHigh Power Microwave Induced Plasma / Atomic Emission Spectrometry / Analytical Atomic spectrometry / Trace Element Analysis / Simultaneous Muli-Element Determination / Hydride Generation Method / Iron and Steel analysis / Sensitive Analytical Method / マイクロ波誘導プラズマ / 鉄鉱分析 / 高出力マクロ波誘導プラズマ / 分析の高感度化 / 分析の高速化 / 多元素同時定量 / 水素化物生成元素
Research Abstract

This project has been performed over the last three years to establish a new system of high-power micro-wave-induced plasma (MIP)-atomic emission spectrometry (AES) and to improve the sensitivity and speed of MIP-AES determination of trace elements. The results are as follows.
1.In this work, a new system of high-power MIP-AES has been designed and constructed as such an instrument is not available in the marketplace. It consists of a new type of resonant cavity and a computer-controlled spectrometer system for the multi-element determination. For the improvement of response time, the electronic circuit in the computing system was replaced with a rapidly working one.
2.In contrast with a common low-power MIP, this high-power nitrogen N/HP can have a great tolerance to continuous nebulization of sample solutions. Furthermore, the constructed system has been modified to combine this MIP with a hydride generation technique as a highly efficient sample introduction.
3.With the use of this new … More ly constructed MIP-AES system coupled with a conventional solution nebulization, background emission spectra have been measured. As a result, some typical molecular band emissions were observed in the spectral range of 200-400 nm. In addition, analytical characteristics of this high-power nitrogen MIP were examined at many emission lines of a number of elements.
4.For the sensitive determination of arsenic, antimony and selenium, their gaseous hydrides generated by the reaction with sodium tetrahydroborate were continuously conveyed into the MIP with no trouble. The hyphenated method has been successfully applied to the determination of arsenic, antimony or selenium in copper metals and steels with satisfactory results. Furthermore, the simultaneous multi-element determination system was developed and it application to steel analysis has been very successful.
5.For a future prospect of this project, a newly developed high-power nitrogen MIP-AES system should be more and more examined and applied to the much wider range of practical samples. If this system can be coupled with other analytical techniques, chemical speciation might be possible and useful, for example, in environmental chemistry. In addition, this technique can be extended to a great extent by the use of a number of sample introduction methods, i.e., ultrasonic nebulization, electrothermal vaporization, slurry sample introduction, laser ablation, spark & arc sampling and glow discharge. Less

Report

(4 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • Research Products

    (70 results)

All Other

All Publications (70 results)

  • [Publications] 松本明弘: "水素化物生成-高出力窒素マイクロ波誘導プラズマ発光分光分析による鉄鋼中のアンチモンの高感度定量"鉄と鋼. 87. 449-453 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Determination of Tellurium in Steels by High Power Nitrogen Microwave Induced Plasma Atomic Emission Spectrometry Coupled with Hydride Generation Technique"Analytical Sciences. 17(Suppl.). 963-966 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Nakahara: "High Power Nitrogen Microwave Induced Plasma for the Determination of Some Trace Elements in Steels by Atomic Emission Spectrometry"ISIJ International. 42(Suppl.). 114-121 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] I.Abe: "N-Pivaloyl Methyl Ester Derivatives of Amino Acyds for Separation of Enantio-mers by Chiral-Phase Capillary Gas Chromatography"Journal of Separation Sciences. 25. 661-664 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 松本明弘: "水素化物生成-高出力窒素マイクロ波誘導プラズマ発光分光分析による鉄鋼と高純度銅中のヒ素およびアンチモンの同時定量"鉄と鋼. 88. 270-276 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 内原 博: "予備加熱表面酸化膜除去/スズ添加法による鋼中微量酸素の定量"分析化学. 52. 27-33 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Determination of Carbon in Aqueous Solutions by Atmospheric-Pressure Helium Microwave Induced Plasma Atomic Emission Spectrometry with Gas-Phase Sample Introduction Technique"Analytical Sciences. 19. 395-400 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Wagatsuma: "Comparative Study on Excitation Mechanism of Chromium Emission Lines in Radio-Frequency Inductively Coupled Plasma, Nitrogen Microwave Induced Plasma, and Argon or Nitrogen Glow Discharge Plasmas"Spectroscopy Letters. 36. 99-115 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 松本明弘: "水素化物生成-高出力窒素マイクロ波誘導プラズマ発光文講分析による鉄鋼中のヒ素、ビスマスおよびアンチモンの同時定量"鉄と鋼. 89. 587-592 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 松本明弘: "水素化物生成-高出力窒素マイクロ波誘導プラズマ発光文講分析による鉄鋼中のヒ素、ビスマス、アンチモンおよびセレンの同時定量"分析化学. 52. 597-604 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 松本明弘: "水素化物生成-高出力窒素マイクロ波誘導プラズマ発光文講分析による鉄鋼中のヒ素、ビスマスの定量"鉄と鋼. 89. 953-957 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 内原 博: "密閉系・表面酸化膜除去/スズ浴による鋼中の微量酸素定量法の開発"鉄と鋼. 89. 988-993 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Uchihara: "Quantitative Analysis of Trace Bulk Oxygen in Silicon Wafers Using an Inert Gas Fusion Method"Analytical Sciences. 19. 1545-1547 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Determination of Cadmium in Polyethylene by Analytical Atomic Spectrometry with Gas-Phase Sample Introduction Techniques"Microchemical Journal. 77(印刷中). (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Simultaneous Determination of Bismuth and Tellurium in Steels by High Power Nitrogen Microwave Induced Plasma Atomic Emission Spectrometry Coupled with Hydride Generation Technique"Analytical and Bioanalytical Chemistry. 378(印刷中). (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Determination of Tin in Steels by High Power Nitrogen Microwave induced Plasma Atomic Emission Spectrometry Coupled with Hydride Generation Technique"Canadian Journal of Analytical Sciences and Spectroscopy. 49(印刷中). (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Determination of Lead in Steels by High Power Nitrogen Microwave Induced Plasma Atomic Emission Spectrometry Coupled with Hydride Generation Technique"Analytical Sciences. 20(印刷中). (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Imai: "Surface Modulation of Electrothermal Atomizer for Atomic Absorption Spectrometry"Applied Spectroscopy Reviews. 39(印刷中). (2004)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 中原武利: "機器分析実験(分担執筆)"東京化学同人. 387 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Tao: "Advances in Atomic Spectroscopy, Volume 7(分担執筆)"Elsevier Science B.V.(オランダ). 406 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Itabashi: "Sample Preparation for Trace Element Analysis(分担執筆)"Elsevier Science B.V.(オランダ). 1251 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Sensitive determination of antimony in steels by high power nitrogen microwave induced plasma atomic emission spectrometry coupled with hydride generation technique"Tetsu to Hagane. 87. 449-453 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Determination of Tellurium in Steels by High Power Nitrogen Microwave Induced Plasma Atomic Emission Spectrometry Coupled with Hydride Generation Technique"Analytical Sciences. 17 (Supplement). 963-966 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Nakahara: "High Power Nitrogen Microwave Induced Plasma Atomic Emission Spectrometry with Hydride Generation Technique"ISIJ International. 42 (Supplement). 114-121 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] I.Abe: "N-Pivaloyl Methyl Ester Derivatives of Amino Acids for Separation of Enantiomers by Chiral-Phase Capillary Gas Chromatography"Journal of Separation Sciences. 25. 661-664 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Simultaneous Determination of Arsenic and Antimony in Steels by High Power Nitrogen Microwave Induced Plasma Atomic Emission Spectrometry Coupled with Hydride Generation Technique"Tetsu to Hagane. 88. 270-276 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Uchihara: "Determination of Trace Oxygen in Steel Using Tin after Removing Surface Oxide by Preheating"Bunseki Kagaku. 52. 27-33 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Determination of carbon in aqueous solutions by atmospheric-pressure helium microwave induced plasma atomic emission spectrometry with gas-phase sample introduction technique"Analytical Sciences. 19. 395-400 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] K.Wagatsuma: "Comparative study on excitation mechanism of chromium emission lines in argon radio-frequency inductively-coupled plasma, nitrogen microwave induced plasma, and argon or nitrogen glow discharge plasmas"Spectroscopy Letters. 36. 99-115 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Simultaneous determination of arsenic, bismuth and antimony in steels by high power nitrogen microwave induced plasma atomic emission spectrometry coupled with hydride generation method"Tetsu to Hagane. 89. 587-592 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Simultaneous determination of arsenic, bismuth and antimony in steels by high power nitrogen microwave induced plasma atomic emission spectrometry coupled with hydride generation method"Bunseki Kagaku. 52. 597-604 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matusmoto: "Determination of Bismuth in steels by High Power Nitrogen Microwave Induced Plasma Atomic Emission Spectrometry Coupled with Hydride Generation Technique"Tetsu to Hagane. 89. 953-957 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Uchihara: "Development Determination of Trace Oxygen in Steel Using Molten Tin After Removing Surface Oxide under the Closed System"Tetsu to Hagane. 89. 988-993 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Uchihara: "Quantitative Analysis of Trace Bulk Oxygen in Silicon Wafers Using an Inert Gas Fusion Method"Analytical Sciences. 19. 1545-1547 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "determination of Cadmium in Polyethylene by Analytical Atomic Spectrometry with Gas-Phase Sample Introduction Techniques"Microchemical Journal. (in press). 77 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Simultaneous determination of bismuth and tellurium in steels by high power nitrogen microwave induced plasma atomic emission spectrometry coupled with the hydride generation technique"Analytical and Bioanalytical Chemistry. (in press). 378 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Determination of tin in steels by high power nitrogen microwave induced plasma atomic emission spectrometry with hydride generation technique"Canadian Journal of Analytical Sciences and Spectroscopy. (in press). 49 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] A.Matsumoto: "Determination of Lead in Steels by High Power Nitrogen Microwave Induced Plasma Atomic Emission Spectrometry Coupled with Hydride Generation Technique"Analytical Sciences. (in press). (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] S.Imai: "Surface Modulation of Electrothermal Atomizer for Atomic Absorption Spectrometry"Applied Spectroscopy Reviews. (in press). 39 (2004)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] T.Nakahara: "Instrumental analytical Chemistry Experiments"Tokyo Kagaku Dojin. 387 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Tao: "Advances in Atomic Spectroscopy, Volume 7"Eslvier Science B.V. (The Netherlands). 406 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] H.Itabashi: "Sample Preparation for Trace Element Analysis"Elsevier Science B.V. (The Netherlands). 1251 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] 内原 博: "予備加熱表面酸化膜除去/スズ添加法による鋼中微量酸素の定量"分析化学. 52・1. 27-33 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Matsumoto: "Determination of Carbon In Aqueous Solutions by Atmospheric Pressure Helium Microwave Induced Plasma Atomic Emission Spectrometry with Gas-Phase Sample Introduction Technique"Analytical Sciences. 19・3. 395-400 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Wagatsuma: "Comparative Study on Excitation Mechanism of Chromium Emission Lines in Radio-Frequency Inductively Coupled Plasma, Nitrogen Microwave Induced Plasma, and Argon or Nitrogen Glow Discharges"Spectroscopy Letters. 36・1&2. 99-115 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 松本 明弘: "水素化物生成-高出力窒素マイクロ波誘導プラズマ発光分光分析による鉄鋼中のヒ素、ビスマス、アンチモンおよびセレンの同時定量"鉄と鋼. 89・5. 587-592 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 松本 明弘: "水素化物生成-高出力窒素マイクロ波誘導プラズマ発光分光分析による鉄鋼中のヒ素、ビスマス、アンチモンおよびセレンの同時定量"分析化学. 52・8. 597-604 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 松本 明弘: "水素化物生成-高出力窒素マイクロ波誘導プラズマ発光分光分析によるビスマスの定量"鉄と鋼. 89・9. 953-957 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 内原 博: "密閉系・表面酸化膜除去/スズ浴による鋼中の微量酸素定量法の開発"鉄と鋼. 89・9. 988-993 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Uchihara: "Quantitative Analysis of Trace Bulk Oxygen in Silicon Wafers Using an Inert Gas Fusion Method"Analytical Sicences. 19・11. 1545-1547 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Matsumoto: "Determination of Cadmium in Polyethylene by Analytical Atomic Spectrometry with Gas-Phase Sample Introduction Technique"Microchemical Journal. 77(印刷中). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Matsumoto: "Simultaneous Determination of Bismuth and Tellurium in Steels by High Power Nitrogen Microwave Induced Plasma Atomic Emission Spectrometry Coupled with Hydride Generation Technique"Analytical and Bloanalytical Chemistry. 378(印刷中). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] A.Matsumoto: "Determination of Tin in Steels by High Power Nitrogen Microwave Induced Plasma Atomic Emission Spectrometry Coupled with Hydride Generation Technique"Canadian Journal of Analytical Sciences and Spectroscopy. 49(印刷中). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.Imai: "Surface Modulation in Electrothermal Atomizer for Atomic Absorption Spectrometry"Applied Spectroscopy Reviews. 39(印刷中). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] 中原 武利: "機器分析実験(分担執筆)"東京化学同人. 387 (2002)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Itabashi: "Sample Preparation for Trace Element Analysis(分担執筆)"Elsevier Science B>V>(オランダ). 1251 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] T.Nakahara: "High Power Nitrogen Microwave Induced Plasama for the Determination of Some Trace Elements in Steels by Atomic Emission Spectrometry with Hydride Generation Technique"ISIJ International. 42・Suppl.. 114-121 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 松本明弘: "水素化物生成-高出力窒素マイクロ波誘導プラズマ発光分光分析による鉄鋼と高純度銅中のヒ素およびアンチモンの同時定量"鉄と鋼. 88・5. 270-276 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] I.Abe: "N-Pivaloyl Methyl Ester Derivatives of Amino Acids for Separation of Enantiomers by Chiral-Phase Capillary Gas Chromatography"Journal of Separation Science. 25・7. 661-664 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 松本明弘: "気相試料導入-誘導結合プラズマ発光分光分析による鉄鋼中の銅の定量"鉄と鋼. 89・2. 315-320 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.Matsumoto: "Determination of Carbon in Aqueous Solutions by Atmospheric-Pressure Helium Microwave Induced Plasma Atomic Emission Spectrometry with Gas-Phase Sample Introduction Technique"Analytical Sciences. 19・3. 395-400 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] 松本明弘: "水素化物生成-高出力窒素マイクロ波誘導プラズマ発光分光分析による鉄鋼中のヒ素、ビスマス、アンチモンおよびセレンの同時定量"鉄と鋼. 89・5(印刷中). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Nakahara: "Advances in Atomic Spectroscopy, Volume 7 (Chapter 2 : New Developments in Hydride Generation-Atomic Spectrometry 執筆)"Elsevier Science B.V.. 406 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 竹田菊男: "Inductively Coupled Plasma Mass Spectrometric Determination of Ultra-Trace Elements in Electronic-Grade Water and Chemicals Using Dulcitol"Analytica Chimica Acta. 426・1. 105-109 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Takeda: "Evaluation of Outgassing Compounds from Cleanroom Construction Materials"Journal of the Institute of Environmental Science and Technology. 44・1. 28-32 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 松本明弘: "水素化物生成-高出力窒素マイクロ波誘導プラズマ発光分光分析による鉄鋼中のアンチモンの高感度定量"鉄と鋼. 87・6. 449-453 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] A.Matsumoto: "Determination of Tellurium in Steels by High Power Nitrogen Microwave Induced Plasma Atomic Emission Spectrometry Coupled with Hydride Generation Technique"Analytical Sciences. 18・3(印刷中). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Nakahara: "High Power Nitrogen Microwave Induced Plasma for the Determination of Some Trace Elements in Steels by Atomic Emission Spectrometry with Hydride Generation Technique"ISIJ International. 43・3(印刷中). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 松本明弘: "水素化物生成-高出力窒素マイクロ波誘導プラズマ発光分光分析による鉄鋼中のヒ素およびアンチモンの同時定量"鉄と鋼. 88・5(印刷中). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 中原武利: "改訂五版 分析化学便覧(分担執筆)"丸善. 839 (2001)

    • Related Report
      2001 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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