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Research on Phetoreduction System for Supercritical Carbon Dioxide

Research Project

Project/Area Number 13650912
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionSaitama University

Principal Investigator

HIROSE Takuji  Faculty of Engineering, Dept. Appl. Chem., Assoc. Professor, 工学部・応用化学科, 助教授 (80292647)

Project Period (FY) 2001 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥3,700,000 (Direct Cost: ¥3,700,000)
Fiscal Year 2002: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2001: ¥3,100,000 (Direct Cost: ¥3,100,000)
KeywordsRuthenium Polypyridine Complex / Cobalt Polypyridine Complex / Visible Light / Photoreduction of CO_2 / Cation Exchange Polymer / Supercritical CO_2 / Two phase system / 超臨界二酸化炭素 / 光還元 / 光触媒 / ルテニウム錯体 / コバルト錯体 / 一酸化炭素 / ターンオーバー数 / CO / H_2選択性
Research Abstract

In order to develop the molecular system, which can efficiently and practically reduce CO_2 to CO as a chemical resource using visible light, new ruthenium (Ru) and cobalt (Co) polypyridine complex-system was investigated from the following three points.
1. Development of efficient metal complex catalysts
In order to develop efficient photo-induced electron transfer metal complex systems, Ru and Co complex units were connected by conjugated carbon chain and the new bimolecular complex was investigated. As a result, fast electron transfer was observed but back electron transfer was also accelerated and no improvement of CO_2 reduction efficiency was attained.
2. Improvement of metal complex life time and development of solid catalytic system
Cationic Ru and Co complexes were fixed to ion exchange polymer and its photo-induced CO_2 reduction ability was investigated. As a result, the followings were found : 1) Solid catalytic system is easy to handle and recover the metal complexes ; 2) Although the efficiency was not improved for each photoirradiation, the life time of the complex system became long and the total amount of CO produced was increased.
3. Development of supercritical CO_2 reaction system
In order to establish a reaction system under high pressure or supercritical CO_2, a reaction vessel was developed and reaction conditions were investigated for photo-reduction. As a result, high CO_2 reduction rate was obtained under organic solvent-supercritical CO_2 two phase system. Now the reproducibility is examined in detail and investigation of a new system under supercritical CO_2 phase is also on going.

Report

(3 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • Research Products

    (2 results)

All Other

All Publications (2 results)

  • [Publications] Takuji Hirose, Yoshihito Maeno, Yuichiro Himeda: "Photocatalytic carbon dioxide photoreduction by Co(boy)_3^<2+> sensitized by Ru(bpy)_3^<2+> fixed to cation exchage polymer"Journel of Molecular Catalysis A : Chemistry. 193. 27-32 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 広瀬卓司, 前野義人, 姫田雄一郎: "Photocatalytic carbon dioxide photoreduction by Co(bpy)_3^<2+> sensitized by Ru(bpy)_3^<2+> fixed to cation exchange polymer"Journal of Molecular Catalysis A : Chemistry. 193. 27-32 (2003)

    • Related Report
      2002 Annual Research Report

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Published: 2001-04-01   Modified: 2016-04-21  

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