| Project/Area Number |
13650924
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kinki University |
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Principal Investigator |
KASHIMURA Shigenori Kinki University, Department of Metallurgy, Associate Professor, 理工学部, 助教授 (50152632)
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| Co-Investigator(Kenkyū-buntansha) |
ISHIFUNE Manabu Kinki University, Department of Applied Chemistry, Assistant Professor, 理工学部, 講師 (40268462)
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| Project Period (FY) |
2001 – 2002
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| Project Status |
Completed (Fiscal Year 2002)
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| Budget Amount *help |
¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 2002: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2001: ¥1,300,000 (Direct Cost: ¥1,300,000)
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| Keywords | Electroreduction / Polysilannes / opticlly activel / Chemically reactive electrode / Coupling reaction |
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| Research Abstract |
It has been found in this study that, in the electroreduction of optically active dichlorosilanes with chemically reactive Mg electrode led to the formation of optically active polysilanes in high yields. In addition it was also found in this study that partial trnsfomation of phenyl group of phenylmethylpolysilane synthesized by the electroreduction to chloro group followed by the reaction with optically active Grignard reagents led to the formation of optiaclly active polysilanes with high yields. The reaction of above mentioned chlorosilane with optically active alcohols such as menthol also gave optically active polysilanes in reasonable yields. These methods can be carried out at room temperature and under ordinal pressure without using dangerous metal, and hence, the methods are practical for the synthesis of optically active polysilanes.
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