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Development of time-resolved photoelectron imaging for studies on hydrated electron

Research Project

Project/Area Number 14204063
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionRIKEN (2003-2004)
Okazaki National Research Institutes (2002)

Principal Investigator

SUZUKI Toshinori  RIKEN, Chemical Dynamics Laboratory, Chief Scientist, 鈴木化学反応研究室, 主任研究員 (10192618)

Project Period (FY) 2002 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥56,940,000 (Direct Cost: ¥43,800,000、Indirect Cost: ¥13,140,000)
Fiscal Year 2004: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2003: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2002: ¥47,840,000 (Direct Cost: ¥36,800,000、Indirect Cost: ¥11,040,000)
Keywordsphotoelectron spectroscopy / femtosecond / ultrafast spectroscopy / imaging / droplet / solvated electron / hydrated electron / time-resolved charged particle imaging / フェムト秒 / 光電子
Research Abstract

The aim of this work was to develop an atomization technique of bulk liquids to form a nano-scale droplets, allowing detailed laser photoelectron spectroscopy on hydrated electron in the droplet. An atomization process using Rayleigh instability I continuous liquid flow was examined and a new way of efficient disintegration of liquid was investigated through development of new nozzles. Two major types of a crossed liquid-gas jets and coaxial expansion of liquid and gas were tested, in which good performance was confirmed for the coaxial type. Laser-assisted particle image velocimetry was employed to measure the velocities of droplets, and Mie light scattering to measure the size distribution in micrometer scale. In addition, the size distribution in nano-scale was examined using a differential mobility analyzer(DMA). The DMA indicated that nano-scale droplets are efficiently formed by using our nozzles. Furthermore, time-of-flight mass analysis characterized the droplet size distribution produced by atomization in high vacuum, and nano-scale droplets were observed to confirm the results of DMA.

Report

(4 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (20 results)

All 2005 2004 Other

All Journal Article (14 results) Publications (6 results)

  • [Journal Article] Ultrafast dissociation processes in the NO dimer studied with time-resolved photoelectron imaging2005

    • Author(s)
      M.Tsubouchi, C.A.de Lange, T.Suzuki
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena 142

      Pages: 193-205

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Photoionization of Homo-Nuclear Diatomic Molecules Aligned by an Intense Femtosecond Laser Pulse2005

    • Author(s)
      M.Tsubouchi, T.Suzuki
    • Journal Title

      Physics Review A (submitted)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Ultrafast dissociation processes in the NO dimer studied with time-resolved photoelectron imaging2005

    • Author(s)
      M.Tsubouchi
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena 142

      Pages: 193-205

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photoionization of Homo-Nuclear Diatomic Molecules Aligned by an Intense Femtosecond Laser Pulse2005

    • Author(s)
      M.Tsubouchi
    • Journal Title

      Physics Review A (submitted)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Femtosecond photoelectron imaging on Pyrazine : (1+2') REMPI of deuterated Pyrazine2004

    • Author(s)
      T.Suzuki, L.Wang, M.Tsubouchi
    • Journal Title

      Journal of Physical Chemistry A 108

      Pages: 5764-5769

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Photodissociation of Nitorous Oxide revisited by high-resolution photofragment imaging : energy partitioning2004

    • Author(s)
      T.Nishide, T.Suzuki
    • Journal Title

      Journal of Physical Chemistry A 108

      Pages: 7863-7870

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Femtosecond photoelectron imaging on Pyrazine : S_1-T_1 intersystem crossing and rotational coherence transfer2004

    • Author(s)
      M.Tsubouchi, B.J.Whitaker, T.Suzuki
    • Journal Title

      Journal of Physical Chemistry A 108

      Pages: 6823-6835

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photoelectron kinetic energy dependence in near threshold ionization of NO from A state studied by time-resolved photoelectron imaging2004

    • Author(s)
      M.Tsubouchi, T.Suzuki
    • Journal Title

      Journal of Chemical Physics 121

      Pages: 8846-8853

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Femtosecond photoelectron imaging on Pyrazine : (1+2') REMPI of deuterated Pyrazine2004

    • Author(s)
      T.Suzuki
    • Journal Title

      Journal of Physical Chemistry A 108

      Pages: 5764-5769

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photodissociation of Nitorous Oxide revisited by high-resolution photofragment imaging : energy partitioning2004

    • Author(s)
      T.Nishide
    • Journal Title

      Journal of Physical Chemistry A 108

      Pages: 7863-7870

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Femtosecond photoelectron imaging on Pyrazine : S_1-T_1 intersystem crossing and rotational coherence transfer2004

    • Author(s)
      M.Tsubouchi
    • Journal Title

      Journal of Physical Chemistry A 108

      Pages: 6823-6835

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Photoelectron kinetic energy dependence in near threshold ionization of NO from A state studied by time-resolved photoelectron imaging2004

    • Author(s)
      M.Tsubouchi
    • Journal Title

      Journal of Chemical Physics 121

      Pages: 8846-8853

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Femtosecond photoelectron imaging on pyridine : electronic dephasing from the S1(n,π^*) state and Rydberg state energetics2004

    • Author(s)
      M.Tsubouchi, T.Suzuki
    • Journal Title

      Journal of Physical Chemistry A 107

      Pages: 10897-10904

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Femtosecond photoelectron imaging on Pyrazine : S1-T1 intersystem crossing and rotational coherence transfer2004

    • Author(s)
      M.Tsubouchi, B.J.Whitaker, T.Suzuki
    • Journal Title

      Journal of Physical Chemistry A 108

      Pages: 6823-6835

    • Related Report
      2004 Annual Research Report
  • [Publications] M.Tsubouchi, T.Suzuki: "Femtosecond time-resolved charged particle imaging studies of the ultraviolet photodissociation of the NO dimer"Journal of Chemical Physics. 119. 11728-11739 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Tsubouchi, T.Suzuki: "Excitation energy dependence in the electronic dephasing time of the NO dimer"Chemical Physics Letters. 382. 418-425 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Tsubouchi, T.Suzuki: "Femtosecond photoelectron imaging on Pyridine : ultrafast electronic dephasing from the S1 state and Rydberg state energetics"Journal of Physical Chemistry A. 107. 10897-10903 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Matsumoto et al.: "Femtosecond photoelectron imaging of pyridazine : S1 lifetime and 3s(n-1) 3p(n-1) Rydberg state energetics"Journal of Chemical Physics. 119. 300-303 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] H.Katayanagi et al.: "One- and two-color photoelectron imaging of the CO molecule via the B state"Journal of Chemical Physics. 119. 3737-3744 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 鈴木俊法: "化学反応の実時間追跡"日本物理学会誌. 58. 765-769 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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