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Development of ultra-precision processing technology of novel semiconductor substrate applied to devices with nano-structure

Research Project

Project/Area Number 14205026
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field 機械工作・生産工学
Research InstitutionKumamoto University

Principal Investigator

WATANABE Junji  Kumamoto University, Faculty of Engineering, Professor, 工学部, 教授 (40281076)

Co-Investigator(Kenkyū-buntansha) TOUGE Mutsumi  Kumamoto University, Faculty of Engineering, Assistant Professor, 工学部, 助教授 (00107731)
MATSUMOTO Yasumichi  Kumamoto University, Graduate school of Science and Technology, Professor, 大学院・自然科学研究科, 教授 (80114172)
KURODA Noritaka  Kumamoto University, Faculty of Engineering, Professor, 工学部, 教授 (40005963)
OBUCHI Yoshifumi  Fukuoka Institute of Technology, Faculty of Engineering, Assistant Professor, 工学部, 助教授 (10176993)
SHIMADA Shoichi  Osaka Electrical Communication University, Faculty of Engineering, Professor, 工学部, 教授 (20029317)
ERYU Osamu  Nagoya Institute of Technology, Faculty of Engineering, Assistant Professor, 電気情報, 助教授 (10223679)
Project Period (FY) 2002 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥50,180,000 (Direct Cost: ¥38,600,000、Indirect Cost: ¥11,580,000)
Fiscal Year 2004: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
Fiscal Year 2003: ¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2002: ¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
KeywordsPolishing machine with UV rays / TiO_2 photocatalyst / Quartz plate / GaAs semiconductor / Silicon carbide single crystal / Diamond single crystal / X-ray photo spectroscopy / Surface roughness / TiO_2固体光触媒 / 紫外光線 / SiC単結晶 / 酸化膜 / 研磨加工 / 分子動力学シミュレーション / FT-IR分析
Research Abstract

The research target in this project is to develop the ultra-precision machining technology of novel semiconductor substrates, such as GaAs, silicon carbide and diamond single crystal, applied to future devices with nano-structure. The basic concept of the technology is application of solid catalysis and ultra-violet rays in polishing technology. The results obtained are as follows.
(1)Ultra-precision polishing of GaAs substrate
Ultra-violet rays was irradiated on the GaAs wafer on which TiO_2 photocatalyst powder was dispersed for ten minutes. It is found that oxide film composed from Ga_2O_3 and As_2O_3 was detected by evaluation method of XPS. It is possible to polish GaAs by means of removing the oxide film with safety and high quality. On the other hand, hydroxyl-radical generated from H_2O_2 is also available for GaAs polishing.
(2)Ultra-precision polishing of silicon carbide substrate
Silicon terminated surface of SiC single crystal is polished with Cr_2O_3-grinding wheel to high quality and high efficiency. The stock removal rate of it achieves to 3 micrometer per hour and the surface roughness polished is below Ra 0.3nm. It was found that there is no sub-surface damage from the evaluation by CAICISS method.
It was found that SiC single crystal can be polished with quartz disk under ultra-violet rays irradiation. The polishing mechanism of this based on photochemical reaction of SiC semiconductor.
(3)Ultra-precision polishing of diamond single crystal
The (100) surface of diamond single crystal can be polished with quartz disk under ultra-violet rays irradiation. The stock removal rate is achieved to 2 micrometers per hour under the condition of polishing pressure of 70 MPa. The surface roughness of the surface polished is below Ra 0.5nm.

Report

(4 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • 2002 Annual Research Report
  • Research Products

    (46 results)

All 2006 2005 2004 2003 2002 Other

All Journal Article (30 results) Book (2 results) Patent(Industrial Property Rights) (4 results) Publications (10 results)

  • [Journal Article] Infrared Study on Graded Lattice Quality in Thin GaN Crystals Grown on Sapphire2006

    • Author(s)
      N.Kuroda, T.Kitayama, Y.Nishi, K.Saiki, H.Yokoi, J.Watanabe, M.Cho, T.Egawa, H.Ishikawa
    • Journal Title

      Jpn. J. Appl. Phys. Vol.45 No.2A

      Pages: 646-650

    • NAID

      40007140203

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Infrared Study on Graded Lattice Quality in Thin GaN Crystals Grown on Sapphire2006

    • Author(s)
      N.Kuroda, T.Kitayama, Y.Nishi, K.Saiki, H.Yokoi, J.Watanabe, M.Cho, T.Egawa, H.Ishikawa
    • Journal Title

      Jpn.J.Appl.Phys. Vol.45 No.2A

      Pages: 646-650

    • NAID

      40007140203

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Thinning Technology of Patterned Silicon Wafer for Micro Pressure Sensor2005

    • Author(s)
      T.Nagano, M.Touge, J.Watanabe
    • Journal Title

      Proceedings of the Eighth International Symposium on Advances in Abrasive Technology (発表予定)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Investigation of Chemical Mechanical Polishing of GaAs Wafer by the Effect of a Photocatalyst2005

    • Author(s)
      S.H.Hong, H.Ishii, M.Touge, J.Watanabe
    • Journal Title

      Proceedings of the Eighth International Symposium on Advances in Abrasive Technology (発表予定)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] High precision chemical mechanical polishing of highly-boron-doped Si wafer used for epitaxial substrate2005

    • Author(s)
      J.Watanabe, G.Yu, O.Eryu, I.Koshiyama, K.Izumi, M.Umeno, K.Nakashima
    • Journal Title

      Precision Engineering 29巻2号

      Pages: 151-156

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Investigation of Chemical Mechanical Polishing of GaAs Wafer by the Effect of a Photocatalyst2005

    • Author(s)
      S.H.Hong, H.Ishii, M.Touge, J.Watanabe
    • Journal Title

      Proceedings of the Eighth International Symposium on Advances in Abrasive Technology

      Pages: 381-384

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] High precision chemical mechanical polishing of highly-boron-doped Si wafer used for epitaxial substrate2005

    • Author(s)
      J.Watanabe, G.Yu, O.Eryu, I.Koshiyama, K.Izumi, M.Umeno, K.Nakashima
    • Journal Title

      Precision Engineering Vol.29 No.2

      Pages: 151-156

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] The atomic scale removal mechanism during chemomechanical polishing of Silicon : An atomic force microscopy study2005

    • Author(s)
      F.Katsuki, J.Watanabe
    • Journal Title

      Mater.Res.Soc.Symp.Proc. Vol.841

      Pages: 253-258

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] エアー浮上式精密ベルト研削による高精度加工面の形成 第1報、第2報2004

    • Author(s)
      豊浦 茂, 峠 睦, 渡邉 純二
    • Journal Title

      砥粒加工学会誌 47巻、5号 48巻、4号

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] 長寿命パッドドレッサーの開発2004

    • Author(s)
      藤田 隆, 渡邉 純二
    • Journal Title

      砥粒加工学会誌 48巻3号

      Pages: 147-152

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] SiC単結晶の光化学反応とその研磨2004

    • Author(s)
      横峯和幸, 渡邉純二, 峠 睦
    • Journal Title

      2004年度砥粒加工学会学術講演会講演論文集

      Pages: 67-68

    • Related Report
      2004 Annual Research Report
  • [Journal Article] SiC単結晶の固体触媒応用研磨技術の検討2004

    • Author(s)
      渡邉純二, 横峯和幸, 川向尚, 峠 睦, 黒田規敬, 江龍 修
    • Journal Title

      2004年度砥粒加工学会学術講演会講演論文集

      Pages: 69-70

    • Related Report
      2004 Annual Research Report
  • [Journal Article] ダイヤモンド単結晶の光照射研磨の可能性2004

    • Author(s)
      渡邉純二, 横峯和幸, 川向尚, 洪 錫享, 峠 睦
    • Journal Title

      2004年度砥粒加工学会学術講演会講演論文集

      Pages: 71-72

    • Related Report
      2004 Annual Research Report
  • [Journal Article] GaAs基板の光触媒研磨技術の検討2004

    • Author(s)
      洪 錫亨, 石井秀明, 渡邉純二, 峠 睦
    • Journal Title

      2004年度砥粒加工学会学術講演会講演論文集

      Pages: 73-74

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 光化学反応を応用したGaAsの精密加工技術2004

    • Author(s)
      石井秀明, 渡邉純二, 峠 睦, 洪 錫亨
    • Journal Title

      2004年度精密工学会秋季学術講演会講演論文集

      Pages: 659-660

    • NAID

      130004655684

    • Related Report
      2004 Annual Research Report
  • [Journal Article] シリコン基板の前処理技術とCVDダイヤモンド膜の特性の関係2004

    • Author(s)
      財部 剛, 清水正寛, 峠 睦, 渡邉純二
    • Journal Title

      2004年度精密工学会秋季学術講演会講演論文集

      Pages: 633-634

    • NAID

      130004655669

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 超LSIプロセスにおける平坦化CMP技術と装置の開発2003

    • Author(s)
      渡邊純二, 藤田 隆, 稲村豊四郎, 別府敏保
    • Journal Title

      精密工学会誌 69巻、2号

      Pages: 263-267

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Effect of Pre-Thin-Surface Grinding on Copper Chemical Mechanical Polishing2003

    • Author(s)
      J.Watanabe, T.Hisamatsu, M.Hirano
    • Journal Title

      Proceedings of the Sixth International Symposium on Advances in Abrasive Technology

      Pages: 407-412

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Development of Ultra Thin Quartz by Abrasive Machining2003

    • Author(s)
      M.Touge, J.Watanabe, Y.Ohbuchi, H.Sakamoto, N.Ueda
    • Journal Title

      Proceedings of the Sixth International Symposium on Advances in Abrasive Technology

      Pages: 123-128

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Surface Treatment of Silicon Carbide Using TiO2(IV) Photocatalyst2003

    • Author(s)
      Y.Ishikawa, Y.Matsumoto, Y.Nishida, S.Taniguchi, J.Watanabe
    • Journal Title

      J. Am. Chem. Soc. 125巻、21号

      Pages: 6558-6562

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Infrared Attenuated Total Reflection by Chemomechanically Polished (0001) Surface of 6H-SiC2003

    • Author(s)
      N.Kuroda, Y.Iida, T.Shigeta, Hasanudin, J.Watanabe
    • Journal Title

      Jpn. J. Appl. Phys. 42巻、10B

    • NAID

      10012450251

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] 超LSIプロセスにおける平坦化CMP技術と装置の開発(第2報)パッドドレッシング均一化技術の開発-2003

    • Author(s)
      藤田 隆, 渡邉 純二, 佐口 明彦
    • Journal Title

      精密工学会誌 69巻、11号

      Pages: 1610-1614

    • NAID

      110001368363

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Surface Treatment of Silicon Carbide Using TiO2(IV) Photocatalyst2003

    • Author(s)
      Y.Ishikawa, Y.Matsumoto, Y.Nishida, S.Taniguchi, J.Watanabe
    • Journal Title

      J.Am.Chem.Soc. Vol.125, No.21

      Pages: 6558-6562

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Infrared Attenuated Total Reflection by Chemomechanically Polished (0001) Surface of 6H-SiC2003

    • Author(s)
      N.Kuroda, Y.Iida, T.Shigeta, Hasanudin, J.Watanabe
    • Journal Title

      Jpn.J.Appl.Phys. Vol.42 10B

    • NAID

      10012450251

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] エアー浮上式精密ベルト研削による高精度加工面の形成 第1報、第2報2003

    • Author(s)
      豊浦 茂, 峠 睦, 渡邉 純二
    • Journal Title

      砥粒加工学会誌 47巻、5号, 48巻、4号

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Evaluation of Surfaces of Single SiC Crystal Polished with Various Kinds of Particles2002

    • Author(s)
      J.Watanabe, M.Fujimoto, Y.Matsumoto, N.Kuroda, O.Eryu
    • Journal Title

      Proceedings of the Fifth International Symposium on Advances in Abrasive Technology

      Pages: 175-180

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] The Atomic-Scale Removal Mechanism during Si Tip Scratching on Si and SiO2 Surfaces in Aqueous KOH with an Atomic Force Microscope2002

    • Author(s)
      F.Katsuki, A.Saguchi, W.Takahashi, J.Watanabe
    • Journal Title

      Jpn. J. Appl. Phys. Vol. 41, Part 1, No. 7B

      Pages: 4919-4923

    • NAID

      210000051818

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] High Removal Rate Polishing of Glass Substrate Using Epoxy Resin Plate2002

    • Author(s)
      M.TOUGE, J.WATANABE, H.SAKAMOTO, H.WAN, T.MURAKAMI
    • Journal Title

      Proceeding of 6th International Conference on Progress of Machining Technology (ICPMT'2002)

      Pages: 357-362

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] 加工表面の分析評価に基づいたSiC半導体の加工メカニズムの研究2002

    • Author(s)
      渡邉純二, 黒田規敬, 藤本誠, 江龍修
    • Journal Title

      2002年度精密工学会秋季大会学術講演会講演論文集

      Pages: 140-140

    • NAID

      130007001948

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] The Atomic-Scale Removal Mechanism during Si Tip Scratching on Si and SiO2 Surfaces in Aqueous KOH with an Atomic Force Microscope2002

    • Author(s)
      F.Katsuki, A.Saguchi, W.Takahashi, J.Watanabe
    • Journal Title

      Jpn.J.Appl.Phys. Vol.41, Part1, No.7B

      Pages: 4919-4923

    • NAID

      210000051818

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Book] CMPの実践的基礎技術(石井久男)2004

    • Author(s)
      渡邊 純二
    • Total Pages
      86
    • Publisher
      EDリサーチ社
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Book] CMPの実践的基礎技術2004

    • Author(s)
      渡邉 純二
    • Total Pages
      86
    • Publisher
      EDリサーチ社 石井久男
    • Related Report
      2004 Annual Research Report
  • [Patent(Industrial Property Rights)] 半導体基板の超精密研磨装置2005

    • Inventor(s)
      渡邉純二, 横峯和幸, 石井秀明
    • Industrial Property Rights Holder
      熊本大学
    • Industrial Property Number
      2005-041950
    • Filing Date
      2005-02-16
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 半導体基板の超精密研磨装置2005

    • Inventor(s)
      渡邉 純二, 横峯 和幸, 石井 秀明
    • Industrial Property Rights Holder
      熊本大学
    • Industrial Property Number
      2005-041950
    • Filing Date
      2005-02-16
    • Related Report
      2004 Annual Research Report
  • [Patent(Industrial Property Rights)] 研削装置および研削方法2004

    • Inventor(s)
      渡邊 純二
    • Industrial Property Rights Holder
      財・熊本テクノ産業財団
    • Industrial Property Number
      2004-165577
    • Filing Date
      2004-06-03
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 研削装置および研削方法2004

    • Inventor(s)
      渡邉 純二
    • Industrial Property Rights Holder
      財・熊本テクノ産業財団
    • Industrial Property Number
      2004-165577
    • Filing Date
      2004-06-03
    • Related Report
      2004 Annual Research Report
  • [Publications] J.Watanabe, T.Hisamatsu, M.Hirano: "Effect of Pre-Thin-Surface Grinding on Copper Chemical Mechanical Polishing"Proceedings of the Sixth International Symposium on Advances in Abrasive Technology. 407-412 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Touge, J.Watanabe, Y.Ohbuchi, H.Sakamoto, N.Ueda: "Development of Ultra Thin Quartz by Abrasive Machining"Proceedings of the Sixth International Symposium on Advances in Abrasive Technology. 123-128 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Y.Ishikawa, Y.Matsumoto, Y.Nishida, S.Taniguchi, J.Watanabe: "Surface Treatment of Silicon Carbide Using TiO2(IV) Photocatalyst"J.Am.Chem.Soc.. 125巻、21号. 6558-6562 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] N.Kuroda, Y.Iida, T.Shigeta, Hasanudin, J.Watanabe: "Infrared Attenuated Total Reflection by Chemomechanically Polished (0001) Surface of 6H-SiC"Jpn.J.Appl.Phys.. 42巻 10B. L1241-L1243 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 藤田 隆, 渡邉 純二, 佐口明彦: "超LSIプロセスにおける平坦化CMP技術と装置の開発(第2報)-パッドドレッシング均一化技術の開発-"精密工学会誌. 69巻11号. 1610-1614 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] J.Watanabe, M.Fujimoto, Y.Matsumoto, N.Kuroda, O.Eryu: "Evaluation of Surfaces of Single SiC Crystal Polished with Various Kinds of Particles"Proceedings of the Fifth International Symposium on Advances in Abrasive Technology. 175-180 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] F.Katsuki, A.Saguchi, W.Takahashi, J.Watanabe: "The Atomic-Scale Removal Mechanism during Si Tip Scratching on Si and SiO2 Surfaces in Aqueous KOH with an Atomic Force Microscope"Jpn. J. Appi. Phys.. Vol.41, Part1, No.7B. 4919-4923 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 渡邉純二, 藤田 隆, 稲村豊四郎, 別府敏保: "超LSIプロセスにおける平坦化CMP技術と装置の開発"精密工学会誌. 69巻2号. 263-267 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] M.TOUGE, J.WATANABE, H.SAKAMOTO, H.WAN, T.MURAKAMI: "High Removal Rate Polishing of Glass Substrate Using Epoxy Resin Plate"Proceeding of 6th International Conference on Progress of Machining Technology (ICPMT'2002). 357-362 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 渡邉純二, 黒田規敬, 藤本誠, 江龍修: "加工表面の分析評価に基づいたSiC半導体の加工メカニズムの研究"2002年度精密工学会秋季大会学術講演会講演論文集. 140 (2002)

    • Related Report
      2002 Annual Research Report

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Published: 2002-04-01   Modified: 2016-04-21  

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