非食性バイオマスからの化成品生産に向けた固体触媒グリーンエンジニアリングの構築
| Project/Area Number |
14J12396
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| Research Category |
Grant-in-Aid for JSPS Fellows
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| Allocation Type | Single-year Grants |
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| Section | 国内 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Japan Advanced Institute of Science and Technology |
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Principal Investigator |
CHOUDHARY HEMANT (2015) 北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 特別研究員(DC2)
CHOUDHARY Hemant (2014) 北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 特別研究員(DC2)
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| Project Period (FY) |
2014-04-25 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2015: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2014: ¥1,000,000 (Direct Cost: ¥1,000,000)
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| Keywords | Biomass / Metal Organic Framework / Heterogeneous Catalyst / Organic transformation / Acid Catalyst / Proton Conductivity / Organic Transformation |
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| Outline of Annual Research Achievements |
In the event of engineering greener methodologies for converting inedible-biomass into commodity chemicals over heterogeneous catalysts, various heterogeneous catalysts were developed. The preparation of metal-organic framework (MOF) based acid catalyst were successfully achieved through post-synthetic modification methodology. The prepared catalyst possessed acidic properties and catalytic activity for esterification and hydrolysis reaction comparable to the commercially known acid catalysts such as Amberlyst-15 and Nafions. In addition to the catalysis, the prepared acidic materials had potential for applications in fuel cells with high proton conductivity.
The research also proposed the functionalization of MOFs to afford not only acid catalysts but also to immobilize metals like palladium (Pd) through amine functionalization. The successful incorporation of amine functionality was achieved through ligand design methodology and Pd was grafted on such material to afford a potent heterogeneous catalyst. Such catalyst demonstrated remarkable stability and catalytic performances for Mizoroki-Heck reaction. Surfactant-treated and/or stabilized monometallic and bimetallic nanoparticle based catalysts were also developed for various selective transformations including hydrogenation of olefins, oxidation of diols and cross-coupling reaction of aryl chloride.
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| Research Progress Status |
27年度が最終年度であるため、記入しない。
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| Strategy for Future Research Activity |
27年度が最終年度であるため、記入しない。
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Report
(2 results)
Research Products
(15 results)
