Study on Multielectron Effect Near Molecular Inner-Shell Photoionization Thresholds
| Project/Area Number |
15340135
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
原子・分子・量子エレクトロニクス・プラズマ
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| Research Institution | Institute for Molecular Science (2004-2005)
Okazaki National Research Institutes (2003) |
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Principal Investigator |
SHIGEMASA Eiji Institute for Molecular Science, UVSOR facility, Associate professor, 極端紫外光研究施設, 助教授 (90226118)
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| Co-Investigator(Kenkyū-buntansha) |
GEJO Tatsuo University of Hyogo, School of Science, Associate professor, 理学部, 助教授 (20290900)
KOSUGI Nobuhiro Institute for Molecular Science, Dep.of VUV Photoscience, Professor, 極端紫外光科学研究系, 教授 (20153546)
HATSUI Takaki Institute for Molecular Science, Dep.of VUV Photoscience, Research associate, 極端紫外光科学研究系, 助手 (40332176)
HIKOSAKA Yasumasa Institute for Molecular Science, UVSOR facility, Research associate, 極端紫外光研究施設, 助手 (00373192)
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| Project Period (FY) |
2003 – 2005
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| Project Status |
Completed (Fiscal Year 2005)
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| Budget Amount *help |
¥11,100,000 (Direct Cost: ¥11,100,000)
Fiscal Year 2005: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 2004: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 2003: ¥7,400,000 (Direct Cost: ¥7,400,000)
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| Keywords | Inner-shell electron / Synchrotron radiation / Polarization dependence / Dissociation / Non-dipolar effect / Electron correlation / Post collision effect / Many-electron effect / シンクロトロン放射光 / PCl効果 |
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| Research Abstract |
The double toroidal analyzer (DTA) at UVSOR, which has been originally developed by a French group, has been under conditioning. The imaging detection without any exit slit enables us to observe electrons within an energy range more than 10% of the pass energy, and their angular distributions simultaneously. Recently it was confirmed that the performance of the analyzer has been improved considerably, after re-assembling of DTA and its careful tuning. The introduction of an ion time-of-flight spectrometer with a two dimensional detector is in the planning stage, to perform energy-selected-electron-ion coincidence experiments.
Parallel to the research and development of new experimental setups, some trial experiments have been made for observing minor products, such as highly excited neutral species and anions after the molecular inner-shell excitations. A strong enhancement due to the N^* formation has been observed around the 1s threshold of N_2 molecules. It has been found that the highly excited N_2^<+^*> states leading to the N^* formation are populated by spectator Auger decay from the core-excited states, as well as by the recapture of slow photoelectrons into the Rydberg orbitals. It turns out that the metastable observation is a new and sensitive tool to study the decay dynamics of core-excited states and the photoelectron recapture due to the post-collision interaction. Concerning the anion imaging detection after the molecular inner-shell excitations, we have confronted difficulty in eliminating a large background noise by electrons, which may be fixed by performing time-resolved experiments.
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Report
(4 results)
Research Products
(12 results)
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[Journal Article] Photofragmentation study of hexamethyldisiloxane following core ionization and direct double ionization2005
Author(s)
D.Ceolin, C.Miron, K.Le Guen, R.Guillemin, P.Morin, E.Shigemasa, P.Mille, M.Ahmad, P.Lablanquie, F.Penent, M.Simon
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Journal Title
Description
「研究成果報告書概要(欧文)」より
Related Report
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