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Development of impact-resistant polymeric materials by nano structure control

Research Project

Project/Area Number 15360059
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Materials/Mechanics of materials
Research InstitutionKYUSHU UNIVERSITY

Principal Investigator

ARAKAWA Kazuo  KYUSHU UNIVERSITY, Research Institute for Applied Mechanics, Professor, 応用力学研究所, 教授 (00151150)

Co-Investigator(Kenkyū-buntansha) TODO Mistugu  KYUSHU UNIVERSITY, Research Institute for Applied Mechanics, Associate Professor, 応用力学研究所, 助教授 (80274538)
MORITA Yasuyuki  KYUSHU UNIVERSITY, Research Institute for Applied Mechanics, Research Associate, 応用力学研究所, 助手 (90380534)
高橋 淳  電気化学工業株式会社, 千葉工場研究部, 主任研究員
Project Period (FY) 2003 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥13,800,000 (Direct Cost: ¥13,800,000)
Fiscal Year 2005: ¥2,700,000 (Direct Cost: ¥2,700,000)
Fiscal Year 2004: ¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2003: ¥7,500,000 (Direct Cost: ¥7,500,000)
KeywordsPolymers and composite materials / Nano- and micro-structure / Impact resistance / Mechanical property / Fracture behavior / Fracture toughness / Morphology / Fracture mechanism / 高分子材料 / ナノ構造制御 / 耐衝撃性評価 / 力学物性計測 / 破壊靭性 / 耐衝撃性評 / モルホロジー
Research Abstract

New experimental techniques for evaluating the impact fracture toughness of polymers and composite materials were developed. The validity and adaptability of the techniques were then examined by testing the various materials including biodegradable polymers and composites. The techniques were also applied to these materials which changed their structures in the nano- and micro-scopic level. The impact fracture mechanism was then investigated.
The impact fracture mechanism was studied by measuring the dynamic response and residual deformation of the specimen materials after fracture. The dynamic and non-elastic effects were analyzed, because the fracture toughness of polymers is generally dependent on both the viscosity of material and the dynamic effect due to the crack propagation. These two effects were taken into consideration in the impact analysis. The external work applied to the specimen was partitioned into three components : the elastic energy, non-elastic energy, and fracture energy for creating a new fracture surface. The energy release rate was estimated to examine the impact fracture mechanism in detail.
The structures of biodegradable polymers and composite materials were modified by annealing, blending and/or mixing with different biodegradable materials. The fracture toughness of the specimens was measured under static and impact loadings, and the morphology of the fracture surfaces and damage zone ahead of the crack front were also examined using polarizing microscopy and scanning electron microscopy. As a fracture parameter that controls crack growth, the energy release rate was determined using a load and displacement diagram, and it was shown that the fracture toughness can be clearly improvable by controlling the structures by nano- and micro-scopic level.

Report

(4 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • 2003 Annual Research Report
  • Research Products

    (50 results)

All 2006 2005 2004 Other

All Journal Article (44 results) Publications (6 results)

  • [Journal Article] Effect of crystallinity and loading-rate on node I fracture behavior of poly(latic acid)2006

    • Author(s)
      S.D.Park, M.Todo, K.Arakawa, M.Koganemaru
    • Journal Title

      polymer 46

      Pages: 923-929

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Experimental Study on the Thermo-Mechanical Effects of Underfill and Low-CTE Suvstrate in a Flip-Chip Device2006

    • Author(s)
      Y.Morita, K.Arakawa, M.Todo, M.Kaneto
    • Journal Title

      Microelectronics Reliability 46

      Pages: 923-929

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Measuring Fracture Energy in a Brittle Polymeric Material2006

    • Author(s)
      Kazuo Arakawa, Toshio Mada
    • Journal Title

      Experimental Mechanics 46・3(印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 非定常高速き裂進展挙動の実験解析2006

    • Author(s)
      新川和夫, 馬田俊雄
    • Journal Title

      実験力学 6・2(印刷中)

    • NAID

      10018147233

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of crystallinity and loading-rate on mode I fracture behavior of poly(lactic acid)2006

    • Author(s)
      S.D.Park, M.Todo, K.Arakawa, M.Koganemaru
    • Journal Title

      Polymer 47

      Pages: 1357-1363

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Experimental Study on the Thermo-Mechanical Effects of Underfill and Low-CTE Substrate in a Flip-Chip Device2006

    • Author(s)
      Y.Morita, K.Arakawa, M.Todo, M.Kaneto
    • Journal Title

      Microelectronics Reliability 46

      Pages: 923-929

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Measuring Fracture Energy in a Brittle Polymeric Material2006

    • Author(s)
      K.Arakawa, T.Mada
    • Journal Title

      Experimental Mechanics 46-3(in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Experimental Analysis of Unstable Dynamic Crack Propagation Behavior2006

    • Author(s)
      K.Arakawa, T.Mada
    • Journal Title

      Journal of the Japanese Society for Experimental Mechanics 6-2(in press)

    • NAID

      10018147233

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 安定・不安定き裂進展を伴う高分子材料の破壊エネルギ計測2005

    • Author(s)
      新川和夫, 馬田俊雄, 朴相玳, 東藤貢
    • Journal Title

      実験力学 5・2

      Pages: 125-129

    • NAID

      10016443256

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] ウェッジガラス板を用いた位相シフトモアレ干渉法による電子パッケージの熱変位場・熱ひずみ場の計測2005

    • Author(s)
      森田康之, 新川和夫, 東藤貢
    • Journal Title

      計測自動制御学会論文集 41・8

      Pages: 625-629

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] ハイドロキシアパタイト粒子分散ポリL乳酸の破壊挙動に及ぼす粒子形状の影響2005

    • Author(s)
      東藤 貢, 朴 相玳, 新川和夫, 竹之下康治
    • Journal Title

      日本複合材料学会誌 31・14

      Pages: 31-37

    • NAID

      10016629448

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Mixing Process on the Fracture Behavior of HA/PLLA Composite Material2005

    • Author(s)
      S.D.Park, M.Todo, K.Arakawa, Y.Takenoshita
    • Journal Title

      Key Engineering Materials 2.297-300

      Pages: 2453-2458

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Fracture Energy Measurement in Polymer with Stable and Unstable Crack Propagation2005

    • Author(s)
      K.Arakawa, T.Mada, S.-D.Park, M.Todo
    • Journal Title

      Journal of the Japanese Society for Experimental Mechanics 5-2

      Pages: 125-129

    • NAID

      10016443256

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Thermal Displacement and Strain Fields Measurement of Electronic Package, Stacked-MCP, by Phase-Shifting Moire Interferometry using Wedged Glass Plate2005

    • Author(s)
      Y.Morita, K.Arakawa, M.Todo
    • Journal Title

      Transactions of the Japan Society of Instrument and Control Engineers 41-8

      Pages: 625-629

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Particle Shape on the Fracture behavior of HA/PLLA Composite2005

    • Author(s)
      M.Todo, S.-D.Park, K.Arakawa, Y.Takenoshita
    • Journal Title

      Journal of the Japan Society for Composite Materials 31-14

      Pages: 177-1839

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Mixing Process on the Fracture Behavior of HA/PLLA Composite Material2005

    • Author(s)
      S.D.Park, M.Todo, K.Arakawa, Y.Takenoshita
    • Journal Title

      Key Engineering Materials 12.297-300

      Pages: 2453-2458

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 安定・不安定き裂進展を伴う高分子材料の破壊エネルギ計測2005

    • Author(s)
      新川和夫, et al.
    • Journal Title

      実験力学 5・2

      Pages: 125-129

    • NAID

      10016443256

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Dynamic and Viscoplasitic Effects in Brittle Fracture in PMMA2005

    • Author(s)
      K.Arakawa, et al.
    • Journal Title

      Proceedings of the International Congress on Experimental Mechanics 4・1(CD-ROM)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Finite Element Modeling of Damage Formation in Rubber-Toughened Polymer2005

    • Author(s)
      M.Todo, et al.
    • Journal Title

      Key Engineering Materials 297・300

      Pages: 1019-1024

    • Related Report
      2005 Annual Research Report
  • [Journal Article] ハイドロキシアパタイト粒子分散ポリL乳酸の破壊挙動に及ぼす粒子形状の影響2005

    • Author(s)
      東藤 貢, et al.
    • Journal Title

      日本複合材料学会誌 31・4

      Pages: 31-37

    • NAID

      10016629448

    • Related Report
      2005 Annual Research Report
  • [Journal Article] ウェッジガラス板を用いた位相シフトモアレ干渉法による電子パッケージの熱変位場・熱ひずみ場の計測2005

    • Author(s)
      森田康之, et al.
    • Journal Title

      計測自動制御学会論文集 41・8

      Pages: 625-629

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Effect of Mixing Process on the Fracture Behavior of HA/PLLA Composite Material2005

    • Author(s)
      S.D.Park, et al.
    • Journal Title

      Journal of Materials Science 40

      Pages: 1055-1058

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Effect of Mixing Process on the Fracture Behavior of HA/PLLA Composite Material2005

    • Author(s)
      S.D.Park, et al.
    • Journal Title

      Key Engineering Materials 97・300

      Pages: 2453-2458

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Dynamic optical visualization on the interaction between propagating crack and stationary crack2005

    • Author(s)
      X.F.Yao, et al.
    • Journal Title

      Optics and Lasers in Engineering 43

      Pages: 195-207

    • Related Report
      2005 Annual Research Report
  • [Journal Article] ゴルフボールの斜め衝撃挙動に関する実験解析2005

    • Author(s)
      新川和夫, et al.
    • Journal Title

      実験力学 5・4

      Pages: 351-355

    • NAID

      10017152384

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 斜め衝突ゴルフボールの動的接触計測2005

    • Author(s)
      新川和夫, et al.
    • Journal Title

      実験力学 5・4

      Pages: 356-360

    • NAID

      10017152402

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Fracture Energy Measurements of Biodegradable Poly(Lactic Acid)2005

    • Author(s)
      K.Arakawa, et al.
    • Journal Title

      Proceedings of the 2005 SEM Annual Conference and Exposition on Experimental and Applied Mechanics (CD-ROM)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Dependence of Loading-Rate on the Fracture Mechanism of MBS Polymer Blend2005

    • Author(s)
      M.Todo, et al.
    • Journal Title

      Proceedings of the 5th International Conference on Mechanics of Time Dependent Materials (CD-ROM)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Microscopic observation and modeling of toughening mechanism in rubber-modified polymer2005

    • Author(s)
      M.Todo, et al.
    • Journal Title

      Proceedings of 11th International Conference on Fracture (CD-ROM)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Characterization of Fracture Mechanism of PLLA/PCL Polymer Blend2005

    • Author(s)
      S.D.Park, et al.
    • Journal Title

      Proceedings of the 5th Japan-Korea Joint Symposium on Composite Materials

      Pages: 45-46

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Effects of Isothermal Crystallization on Fracture Toughness and Crack Growth Behavior of Poly(lactic acid)2005

    • Author(s)
      S.D.Park, et al.
    • Journal Title

      Journal of Materials Science 40

      Pages: 1055-1058

    • Related Report
      2005 Annual Research Report
  • [Journal Article] メタクリル樹脂の脆性破壊エネルギの計測(第2報,高速度変位計の応用)2004

    • Author(s)
      新川和夫, 馬田俊雄
    • Journal Title

      日本機械学会論文集(A編) 70・695

      Pages: 936-940

    • NAID

      110004998782

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] GM充填エボキシ樹脂の破壊靭性に及ぼすゴム変性の影響2004

    • Author(s)
      東藤貢, 米田真介, 新川和夫
    • Journal Title

      材料 53・9

      Pages: 950-955

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Annealing on the Fracture Toughness of Poly(lactic acid)2004

    • Author(s)
      S.-D.Park, M.Todo, K.Arakawa
    • Journal Title

      Journal of Materials Science 39

      Pages: 1113-1116

    • NAID

      110002489515

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of annealing on fracture mechanism of biodegradable2004

    • Author(s)
      S.D.Park, M.Todo, K.Arakawa
    • Journal Title

      Key Engineering Materials 261・263

      Pages: 105-110

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Measurement of Brittle Fracture Energy in PMMA (2nd Report, Application of High-Speed Extensometer)2004

    • Author(s)
      K.Arakawa, T.Mada
    • Journal Title

      Transactions of the Japan Society of Mechanical Engineers, (Series A) 70-695

      Pages: 936-940

    • NAID

      110004998782

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Rubber Modification on the Fracture Properties of GM Filled Epoxy Resin2004

    • Author(s)
      M.Todo, S.Komeda, K.Arakawa
    • Journal Title

      Journal of the Society of Materials and Sciences Japan 53-9

      Pages: 950-955

    • NAID

      110006266352

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Effect of Annealing on the Fracture Mechanism of Biodegradable Poly(Lactic Acid)2004

    • Author(s)
      S.-D.Park, M.Todo, K.Arakawa
    • Journal Title

      Key Engineering Materials 261-263

      Pages: 105-110

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] GM充填エポキシ樹脂の破壊特性に及ぼすゴム変性の影響2004

    • Author(s)
      東藤 貢, et al.
    • Journal Title

      材料 53・9

      Pages: 950-955

    • NAID

      110006266352

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 合わせガラスの衝撃エネルギー吸収機構2004

    • Author(s)
      東藤 貢, et al.
    • Journal Title

      実験力学 4・2

      Pages: 120-127

    • NAID

      10013274356

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Effect of annealing on fracture mechanism of biodegradable poly(lactic acid)2004

    • Author(s)
      S.D.Park, et al.
    • Journal Title

      Key Engineering Materials 261・263

      Pages: 105-110

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Effect of Annealing on the Fracture Toughness of Poly(lactic acid)2004

    • Author(s)
      S.D.Park, et al.
    • Journal Title

      Journal of Materials Science 39

      Pages: 1113-1116

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Toughening Mechanism of Bioabsorbable PLA/PCL Polymer Blend2004

    • Author(s)
      M.Todo, et al.
    • Journal Title

      Proceedings of the SEM X International Congress and Exposition on Experimental and Applied Mechanics (CD-ROM)

      Pages: 55-55

    • Related Report
      2004 Annual Research Report
  • [Journal Article] メタクリル樹脂の脆性破壊エネルギの計測(第2報,高速度変位計の応用)2004

    • Author(s)
      新川和夫, et al.
    • Journal Title

      日本機械学会論文集(A編) 70・695

      Pages: 936-940

    • NAID

      110004998782

    • Related Report
      2004 Annual Research Report
  • [Publications] 東藤 貢, et al.: "ポリ(L-乳酸)の破壊挙動に及ぼす加水分解の影響"高分子論文集. 60・11. 644-651 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 森田康之, et al.: "位相シフトモアレ干渉法によるSOJ電子パッケージの熱ひずみ解析"実験力学. 3・1. 28-33 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] K.Arakawa, et al.: "Dynamic Measurements of the Fracture Behavior of Polymeric Material"Proc.of the SEM Annual Conference & Exposition on Experimental Mechanics and Applied Mechanics. (CD-ROM). (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] 篠原信之, et al.: "ポリ乳酸のモードI破壊挙動に及ぼす微視構造と負荷速度の影響"日本機械学会論文集(A編). 69・677. 95-101 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] S.-D.Park, et al.: "Fracture Properties of Bioabsorbable HA/PLLA Composite Material"Proc.of The 4th Korea-Japan Joint Symposium on Composite Materials. 35-36 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] M.Todo, et al.: "Loading-Rate Dependence of Mode I Fracture Behavior of Biodegradable Poly(Lactic Acid)"Proc.of the 12th Int.Conf.on Deformation, Yield and Fracture of Polymers, Cambridge. 241-244 (2003)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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