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Formation mechanism of self-organized nanostructured -metallic glass composite

Research Project

Project/Area Number 15510096
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionTohoku University

Principal Investigator

SAIDA Junji  Tohoku University, Center for interdisciplinary Research, Associate professor, 学際科学国際高等研究センター, 助教授 (20359540)

Project Period (FY) 2003 – 2004
Project Status Completed (Fiscal Year 2004)
Budget Amount *help
¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 2004: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2003: ¥2,300,000 (Direct Cost: ¥2,300,000)
Keywordsmetallic glass / nanostructured material / transformation / mechanical properties / local structure / cluster / nano icosahedral quasicrystal / 透過電子顕微鏡 / 小角散乱X線回折 / 変形
Research Abstract

(1)The formation pf nanostructured-metallic glass composite has been found in the rapidly quendied Cu-(Zr or Hf)-Ti alloys.
(2)The nanocrystalline particles have a fine grain size of 5 to 10 nm in diameter and are dispersed homogeneously in the glassy matrix.
(3)The nanocrystalline particles have a metastable cubic structure with Cu-rich composition, which are brought us the formation mechanism of the stable Cu-rich clusters in the supercooled liquid state.
(4)The primary transformation process is clarified in both the alloy systems, where another metastable CuZr phase is formed remaining the nanocrystalline cubic phase in the as-quenched state in the Cu-Zr-Ti alloy. However, the glassy and metastable cubic phases are transformed into the Cu8Hf3 phase in the Cu-Hf-Ti alloy.
(5)The high mechanical strength is exhibited in the nanostructured-metallic glass composite in the Cu-Zr-Ti alloy and it is improved in the primary crystallized state. It is due to the formation of two different nanocrystalline phases.
(6)Nano icosahedral quasicrystalline phase formation is found in the primary stage in the Zr65Al7.5Cu27.5 metallic glass, where the icosahedral cluster has a high stability in the supercooled liquid state.
(7)The fracture mechanism of the nano icosahedral quasicrystal dispersed Zr-Pt binary amorphous alloy is investigated. We have found that the fracture takes place in the glassy region among the dispersed icosahedral particles.
(8)In these studies, we can conclude that the nanoscale structure control based on the metallic glasses using the stable duster and/or local structure is very effective on the improvement of mechanical properties as well as is very important on the investigation of fundamental properties such as the formation mechanism and transformation process in the materials.

Report

(3 results)
  • 2004 Annual Research Report   Final Research Report Summary
  • 2003 Annual Research Report
  • Research Products

    (30 results)

All 2005 2004 2003 Other

All Journal Article (24 results) Patent(Industrial Property Rights) (2 results) Publications (4 results)

  • [Journal Article] Primary precipitation of icosahedral quasicrystal with rearrangement of constitutional elements in Zr_<65>Al_<7.5>Cu_<27.5> glassy alloy with low oxygen impurity2005

    • Author(s)
      J.Saida et al.
    • Journal Title

      Journal of Materials Research 20

      Pages: 303-306

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Novel nanostructure and deformation behavior in rapidly quenched Cu-(Zr or Hf)-Ti alloys2005

    • Author(s)
      J.Saida et al.
    • Journal Title

      Advanced Engineering Materials 7

      Pages: 39-43

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Comparative study of local structure in Zr70Al10Ni20 and quasicrystal-forming Zr70Al9Ni20Pd1 metallic glasses2005

    • Author(s)
      J.Saida et al.
    • Journal Title

      Philosophical Magazine Letters (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Primary precipitation of icosahedral quasicrystal with rearrangement of constitutional elements in Zr_<65>Al_<7.5>Cu_<27.5> glassy alloy with low oxygen impurity2005

    • Author(s)
      J.Saida et al.
    • Journal Title

      J.Mater.Res. 20

      Pages: 303-306

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Novel nanostructure and deformation behavior in rapidly quenched Cu-(Zr or Hf)-Ti alloys2005

    • Author(s)
      J.Saida et al.
    • Journal Title

      Adv.Eng.Mater. 7

      Pages: 39-43

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Comparative study of local structure in Zr_<70>Al_<10>Ni_<20> and quasicrystal-forming Zr_<70>Al_9Ni_<20>Pd_1 metallic glasses2005

    • Author(s)
      J.Saida et al.
    • Journal Title

      Phil.Mag.Lett. (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Synthesis and fundamental properties of Cu-based bulk glassy alloys in binary and multi-component systems2004

    • Author(s)
      A.Inoue et al.
    • Journal Title

      Materials Transactions 45

      Pages: 1153-1162

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Pressure effect on crystallization temperature in Zr70Pd30 metallic glass2004

    • Author(s)
      J.Z.Jiang et al.
    • Journal Title

      Journal of Applied Physics 95

      Pages: 4651-4654

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Microstructure of tensile fracture in nanoicosahedral quasicrystal dispersed Zr80Pt20 amorphous alloy2004

    • Author(s)
      J.Saida et al.
    • Journal Title

      Scripta Materialia 50

      Pages: 1297-1301

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Crystallization behavior of Cu60Zr30Ti10 bulk glassy alloy2004

    • Author(s)
      M.Kasai et al.
    • Journal Title

      Materials Science and Engineering A 375-377

      Pages: 744-748

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Influence of hydrostatic pressure during casting and Pd content on as-cast phase in Zr-Al-Ni-Cu-Pd bulk alloys2004

    • Author(s)
      H.Kato et al.
    • Journal Title

      Applied Physics Letters 85

      Pages: 2205-2207

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Annual Research Report 2004 Final Research Report Summary
  • [Journal Article] Influence of hydrostatic pressure during casting on as-cast structure and mechanical properties in Zr65A17.5Ni10Cu17.5-xPdx (x=0,17.5) alloys2004

    • Author(s)
      H.Kato et al.
    • Journal Title

      Scripta Materialia 51

      Pages: 1063-1068

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Synthesis and fundamental properties of Cu-based bulk glassy alloys in binary and multi-component systems.2004

    • Author(s)
      A.Inoue, W.Zhang, J.Saida
    • Journal Title

      Mater.Trans. 45

      Pages: 1153-1162

    • NAID

      10012905798

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Pressure effect on crystallization temperature in Zr_<70>Pd_<30> metallic glass.2004

    • Author(s)
      J.Z.Jiang, J.Saida et al.
    • Journal Title

      J.Appl.Phys. 95

      Pages: 4651-4654

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Microstructure of tensile fracture in nanoicosahedral quasicrystal dispersed Zr_<80>Pt_<20> amorphous alloy2004

    • Author(s)
      J.Saida, A.Inoue
    • Journal Title

      Scripta Mater. 50

      Pages: 1297-1301

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Crystallization behavior of Cu_<60>Zr_<30>Ti_<10> bulk glassy alloy2004

    • Author(s)
      M.Kasai et al.
    • Journal Title

      Mater.Sci.Eng.A 375-377

      Pages: 744-748

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Influence of hydrostatic pressure during casting and Pd content on as-east phase in Zr-Al-Ni-Cu-Pd bulk alloys.2004

    • Author(s)
      H.Kato et al.
    • Journal Title

      Appl.Phys.Lett. 85

      Pages: 2205-2207

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Influence of hydrostatic pressure during casting on as-cast structure and mechanical properties in Zr_<65>Al_<7.5>Ni_<10>Cu_<17.5-x>Pd_x (x=0, 17.5) alloys2004

    • Author(s)
      H.Kato et al.
    • Journal Title

      Scripta Mater. 51

      Pages: 1063-1068

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Synthesis and fundamental properties of Cu-based bulk glassy alloys on binary and multi-component systems2004

    • Author(s)
      A.Inoue et al.
    • Journal Title

      Materials Transactions 45

      Pages: 1153-1162

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Influence of hydrostatic pressure during casting on as-cast structure and mechanical properties in Zr65A17.5Ni10Cu17.5-xPdx(x=0,17.5)alloys2004

    • Author(s)
      H.Kato et al.
    • Journal Title

      Scripta Materialia 51

      Pages: 1063-1068

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Origin of nanodetectable x-ray diffraction peaks in nanocomposite CuTiZr alloys2003

    • Author(s)
      J.Z.Jiang et al.
    • Journal Title

      Applied Physics Letters 83

      Pages: 3299-3301

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Nano structure of rapidly quenched Cu-(Zr or Hf)-Ti alloys2003

    • Author(s)
      J.Saida et al.
    • Journal Title

      Science and Technology of Advanced Materials 4

      Pages: 311-318

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Origin of nanodetectable x-ray diffraction peaks in nanocomposite CuTiZr alloys.2003

    • Author(s)
      J.Z.Jiang, J.Saida, et al.
    • Journal Title

      Appl.Phys.Lett. 83

      Pages: 3299-3301

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Journal Article] Nano structure of rapidly quenched Cu-(Zr or Hf)-Ti alloys.2003

    • Author(s)
      J.Saida et al.
    • Journal Title

      Sci.Tech.Adv.Mater. 4

      Pages: 311-318

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 非晶質合金の製造方法2004

    • Inventor(s)
      才田 淳治, 他2名
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2004-253092
    • Filing Date
      2004-08-31
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2004 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 非晶質合金の製造方法2004

    • Inventor(s)
      加藤 秀実, 才田 淳治, 井上 明久
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2004-253092
    • Filing Date
      2004-08-31
    • Related Report
      2004 Annual Research Report
  • [Publications] J.Saida et al.: "Evaluation of nanoscale inhomogeneity in as-quenched state of Cu-Hf-Ti alloys"Journal of Materials Research. 18. 2013-2016 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] J.Z.Jiang et al.: "Origin of nanodetectable x-ray diffraction peaks in nanocomposite CuTiZr alloys"Applied Physics Letters. 83. 3299-3301 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] J.Saida et al.: "Nano structure of rapidly quenched Cu-(Zr or Hf)-Ti alloys and their devitrification process"Science and Technology of Advanced Materials. 4. 311-318 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] J.Saida et al.: "Microstructure of tensile fracture in nanoicosahedral quasicrystal dispersed Zr80Pt20 amorphous alloy"Scripta Materialia. 50. 1297-1301 (2004)

    • Related Report
      2003 Annual Research Report

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Published: 2003-04-01   Modified: 2016-04-21  

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