Mixed-valence Sate of Binuclear Ruthenium Complexes Linked by Polyyne-Cumulene Resonance Spacer
| Project/Area Number |
15550052
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nagasaki University |
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Principal Investigator |
HOSHINO Yoshimasa Nagasaki University, Faculty of Education, Natural Science, Associate Professor, 教育学部, 助教授 (50219177)
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| Co-Investigator(Kenkyū-buntansha) |
YUKAWA Yasuhiko Nagasaki University, Institute of Natural Science and Technology, Professor, 自然科学系, 教授 (50200861)
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| Project Period (FY) |
2003 – 2004
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| Project Status |
Completed (Fiscal Year 2004)
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| Budget Amount *help |
¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 2004: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2003: ¥3,200,000 (Direct Cost: ¥3,200,000)
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| Keywords | mixed-valence complex / polyyne / density-functional theory / spectroelectrochemistry / ruthenium complexes / inter-valence charge transfer / magnetic susceptibility / β-diketonato complexes / 混合原始錯体 / 電子スピン共鳴スペクトル / オキサラト錯体 / クムレン / 四核錯体 |
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| Research Abstract |
1.Geometry optimization (with no symmetry constraint) of some oxidized species of the model complex of a C_4-bridged binuclear β-diketonatoruthenium complex was successful, using the ADF program. The excitation energy was calculated by time-dependent DFT(TDDFT) using the Gaussian 98 program. The result of the TDDFT calculation of the Ru^<IV>-Ru^<III> species reproduces an intense absorption band at near 1620 nm (6170 cm^<-1>) with an oscillator strength (f=0.440) assigned as a mixture of MMCT and MLCT transitions.
2.Low-temperature spectroelectrochemical cell was made. The Ru^<IV>-Ru^<III> state of C_6 and C_8-bridged binuclear β-diketonatoruthenium complexes in CH_2Cl_2 could be characterized by low-temperature spectroelectrochemistry. A relatively intense broad IVCT band in the near-IR region was observed for both complexes. Analyses of the IVCT bands indicate that wavenumber at absorption maximum is shifted to higher wavenumber and intensity of the band reduces with increasing the number of acetylene linkers.
3.Temperature dependence of the magnetic susceptibility of CH_2Cl_2 solution of C_4-bridged binuclear β-diketonatoruthenium complex indicates that spin-spin interaction is antiferromagnetic below 20K and therefore ground state of the complex is singlet.
4.Spectroelectrochemistry of binuclear β-diketonatoruthenium complexes bridged by tetraacetylethanato containing no spacer exhibits no significant IVCT band.
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Report
(3 results)
Research Products
(9 results)
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[Journal Article] Synthesis, Characterization, and Detailed Electrochemistry of Binuclear Ruthenium(III) Complexes Bridged by Bisacetylacetonate. Crystal and Molecular Structures of [{Ru(acac)_2}_2(tae)](acac=2,4-Pentanedionate Ion, tae=1,1,2,2-Tetraacetylethanate Dianion)2004
Author(s)
Tomohiro Koiwa, Yuki Masuda, Junpei Shono, Yuji Kawamoto, Yoshimasa Hoshino, Takeshi Hashimoto, Karuppannan Natarajan, Kunio Shimizu
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Journal Title
Inorganic Chemistry 43(20)
Pages: 6215-6223
Description
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