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カリクサレンを骨格とした光学活性な超分子の創成とSPring-8を用いた構造解析

Research Project

Project/Area Number 15F15342
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section外国
Research Field Polymer chemistry
Research InstitutionThe University of Kitakyushu

Principal Investigator

櫻井 和朗  北九州市立大学, 国際環境工学部, 教授 (70343431)

Co-Investigator(Kenkyū-buntansha) LEE JI HA  北九州市立大学, 国際環境工学部, 外国人特別研究員
Project Period (FY) 2015-11-09 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2017: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 2016: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2015: ¥700,000 (Direct Cost: ¥700,000)
Keywordsカリクサレン / プラトニックミセル / 小角X線散乱 / ドラッグデリバリーシステム
Outline of Annual Research Achievements

本研究の目的は、カリクサレン分子を基に単分散な正多面体構造をもったミセル粒子、キラル増幅能がある有機ゲル化剤など合成し、その構造に関して、放射光を用いて解析し、構造と物性の相関を調べることである。
本年度は、カリクサレン系ミセル以外での単分散ミセルを探索し、一般系のミセルにおいてもその親水部に非常に嵩高い親水性基を導入すると、単分散でかつプラトンの正多面体の頂点数に会合数が一致するプラトニックミセル性を示すことを見出した。この系においてミセル構造を固定化することを試みた結果、ミセルの疎水部に二官能性疎水性モノマーを添加し、重合反応を実行することでミセル構造を鋳型にした新たな粒子を調製可能であることを見出した。その粒子構造体の内部構造については小角X線散乱法に基づいて評価し、その粒子の単分散性について検討を行った。

Research Progress Status

29年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

29年度が最終年度であるため、記入しない。

Report

(3 results)
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (17 results)

All 2018 2017 2016 2015 Other

All Journal Article (5 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 5 results,  Open Access: 3 results,  Acknowledgement Compliant: 3 results) Presentation (11 results) (of which Int'l Joint Research: 10 results) Remarks (1 results)

  • [Journal Article] A tetramer micelle: the smallest aggregation number corresponding to the vertex number of regular polyhedra in platonic micelles2018

    • Author(s)
      Fujii Shota、Takahashi Rintaro、Ha Lee Ji、Sakurai Kazuo
    • Journal Title

      Soft Matter

      Volume: 14 Issue: 6 Pages: 875-878

    • DOI

      10.1039/c7sm02028g

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Ultraviolet Patterned Calixarene-Derived Supramolecular Gels and Films with Spatially Resolved Mechanical and Fluorescent Properties2017

    • Author(s)
      Ji Ha Lee, Sung Ho Jung, Shim Sung Lee, Ki-Young Kwon, Kazuo Sakurai, Justyn Jaworski, and Jong Hwa Jung
    • Journal Title

      ACS Nano

      Volume: 11(4) Issue: 4 Pages: 4155-4164

    • DOI

      10.1021/acsnano.7b00997

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Chiral Supramolecular Gels with Lanthanide Ions: Correlation between Luminescence and Helical Pitch2017

    • Author(s)
      Chaelin Kim*, Ka Young Kim*, Ji Ha Lee*, Junho Ahn, Kazuo Sakurai, Shim Sung Lee, and Jong Hwa Jung
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 9(4) Issue: 4 Pages: 3799-3807

    • DOI

      10.1021/acsami.6b13916

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Self-Assembled Tb3+ Complex Probe for Quantitative Analysis of ATP during Its Enzymatic Hydrolysis via Time-Resolved Luminescence in Vitro and in Vivo2016

    • Author(s)
      Sung Ho Jung, Ka Young Kim, Ji Ha Lee, Cheol Joo Moon, Noh Soo Han, Su-Jin Park, Dongmin Kang, Jae Kyu Song, Shim Sung Lee, Myong Yong Choi, Justyn Jaworski, and Jong Hwa Jung
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 9(1) Issue: 1 Pages: 722-729

    • DOI

      10.1021/acsami.6b12857

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Metallogel of bis(tetrazole)-appended pyridine derivative with CoBr2 as a chemoprobe for volatile gases containing chloride atom2016

    • Author(s)
      J.H.Jung, Ji Ha Lee, Yeong Eun Baek, Ka Young Kim, Heekyoung Choi
    • Journal Title

      Supramolecular Chemistry

      Volume: in press Issue: 11-12 Pages: 870-873

    • DOI

      10.1080/10610278.2016.1142088

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] UV Patterned calixarene-derived supramolec-ular gels with spatially resolved mechanical and fluorescent proper-ties2017

    • Author(s)
      Ji Ha Lee
    • Organizer
      253rd American Chemical Society NATIONAL MEETING & EXPOSITION
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] UV Patterned Calixarene-Derived Supramolecular Gels and Films with Spatially Resolved Mechanical and Fluorescent Properties2017

    • Author(s)
      Ji Ha Lee
    • Organizer
      91st ACS Colloid & Surface Science Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Calix[4]arene based protein micellar structure analysis by SAXS measurement2017

    • Author(s)
      Ji Ha Lee
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] UV Patterned Calixarene-Derived Supramolecular Gels2016

    • Author(s)
      Ji Ha Lee
    • Organizer
      The 11th SPSJ International Polymer Conference(IPC2016)
    • Place of Presentation
      福岡国際会議場(福岡市博多区)
    • Year and Date
      2016-12-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] UV Patterned Calixarene-Derived Supramolecular Gels2016

    • Author(s)
      Ji Ha Lee
    • Organizer
      3rd International Conference on Biomaterials Science in Tokyo(ICBS2016)
    • Place of Presentation
      東京大学伊藤ホール(東京都文京区)
    • Year and Date
      2016-11-28
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] UV Patterned Calixarene-Derived Supramolecular Gels and Films with Spatially Resolved Mechanical and Fluorescent Properties2016

    • Author(s)
      Ji Ha Lee
    • Organizer
      65th symposium on macromolecules
    • Place of Presentation
      神奈川大学横浜キャンパス(神奈川県横浜市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reversibly Tunable Helix Inversion in Supramolecular Gels2016

    • Author(s)
      Ji Ha Lee
    • Organizer
      The 28th International Symposium on Chiral Discrmination (Chirality 2016)
    • Place of Presentation
      Heidelberg, Germany
    • Year and Date
      2016-07-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Calix[4]arene-Derived Supramolecular Gels by Hydrazone Reaction: Control of Mechanical and Fluorescent2016

    • Author(s)
      Ji Ha Lee
    • Organizer
      6th International Colloids Conference
    • Place of Presentation
      Berlin, Germany
    • Year and Date
      2016-06-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Calix[4]arene-based supramolecular gel by hydrazone reaction and the control of gelation ability2016

    • Author(s)
      Ji Ha Lee
    • Organizer
      65th Japan polymer science conference2016
    • Place of Presentation
      神戸国際会議場(兵庫県神戸市)
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Calix[4]arene-based supramolecular gel by hydrazone reaction and the control of gelation ability2016

    • Author(s)
      Ji Ha Lee
    • Organizer
      Korea polymer science conference
    • Place of Presentation
      Daejeon, Korea
    • Year and Date
      2016-04-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Supramolecular Gels with High Strength by Tuning of Calix[4]arene-Derived2015

    • Author(s)
      Ji Ha Lee
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Hawaii Convention Center, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 櫻井望月研究室ホームページ

    • URL

      http://www.sakurai-lab.jp/

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2015-11-26   Modified: 2024-03-26  

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