ＮＭＲ検出のためペリレンジイミド由来の薬剤を素にした新たなディスコティック液晶
| Project/Area Number |
15F15773
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| Research Category |
Grant-in-Aid for JSPS Fellows
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| Allocation Type | Single-year Grants |
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| Section | 外国 |
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| Research Field |
Organic and hybrid materials
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| Research Institution | National Institute for Materials Science |
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Principal Investigator |
HILL Jonathan 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主席研究員 (30421431)
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| Co-Investigator(Kenkyū-buntansha) |
ECHUE GERALDINE 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 外国人特別研究員
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| Project Period (FY) |
2015-11-09 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2017: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2016: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2015: ¥400,000 (Direct Cost: ¥400,000)
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| Keywords | Perylene diimide / Chirality / Self-assembly / NMR Spectroscopy / NMR spectroscopy / perylene diimide / chirality |
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| Outline of Annual Research Achievements |
Synthesis and purification of several classes of chiral perylene diimide (highly colored pigments) including amionic and cationic compounds was completed. Physical properties of the compounds were investigated revealing their assembly into chiral structures in solutions and formation of cholesteric liquid crystals in aqueous solvent mixtures. The effects of solvent and concentration were investigated. The liquid crystal compounds were applied in NMR experiments for the determination of enantiomeric excess. Chiral self-assemblies of the materials were metallated forming chiral coordination complexes suitable for possible catalytic applications.Two manuscripts in preparation.
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| Research Progress Status |
29年度が最終年度であるため、記入しない。
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| Strategy for Future Research Activity |
29年度が最終年度であるため、記入しない。
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Report
(3 results)
Research Products
(4 results)
