| Budget Amount *help |
¥42,250,000 (Direct Cost: ¥32,500,000、Indirect Cost: ¥9,750,000)
Fiscal Year 2018: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
Fiscal Year 2017: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2016: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2015: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
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| Outline of Final Research Achievements |
We have advanced through this project the frontier of organic chemistry and developed functions aiming at applications to new materials by focusing on novel organic compounds bearing unpreceded electronic configurations or unknown molecular structures that have not been investigated before. The first targets are open-shell singlet diradicaloids with unique electronic configurations. A few topologically new molecules of non-benzenoid, antiaromatic types were synthesized and their remarkable structures and unprecedented physical properties were unveiled. The second targets, materials of unknown molecular structures, are two-dimensional polymers which are single layer membrane with an atomic-level periodicity. A few of this type of novel materials were synthesized based on self-assembled monolayers formed at the interfaces of solid-liquid and air-liquid.
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