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Development of high performance thin film fabrication process for proton conductive oxide by precise reaction control

Research Project

Project/Area Number 15H02311
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making/Resorce production engineering
Research InstitutionKyoto University

Principal Investigator

Uda Tetsuya  京都大学, 工学研究科, 教授 (80312651)

Co-Investigator(Renkei-kenkyūsha) HAN DONGLIN  京都大学, 工学研究科, 特定准教授 (40727567)
HATADA NAOYUKI  京都大学, 工学研究科, 助教 (00712952)
Research Collaborator MAJIMA MASATOSHI  
OTANI Yuki  
UENO KATSUHIRO  
ONISHI TAKAYUKI  
NODA YOHEI  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥45,240,000 (Direct Cost: ¥34,800,000、Indirect Cost: ¥10,440,000)
Fiscal Year 2017: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥12,350,000 (Direct Cost: ¥9,500,000、Indirect Cost: ¥2,850,000)
Fiscal Year 2015: ¥27,950,000 (Direct Cost: ¥21,500,000、Indirect Cost: ¥6,450,000)
Keywords燃料電池 / セラミックスプロセス / プロトン伝導体 / プロトン伝導性酸化物 / 水素ポンプ / セラミックス / セラミックプロセス
Outline of Final Research Achievements

Y-doped BaZrO3 is expected for next generation fuel cells. However, Ni diffusion during co-sintering with the electrode material is now serious problem. We studied various diffusion prevention method. As the results, the promising method is recovering the performance by diffusing Ni out to the grain boundary after co-sintering by reduction treatment, because Ni works as a sintering aid. In addition, it is clarified that 20% of Y-doped BaZrO3, which is often used, does not equilibrate with NiO was obtained.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (7 results)

All 2017 2016

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (6 results)

  • [Journal Article] A high temperature reduction cleaning (HTRC) process: a novel method for conductivity recovery of yttrium-doped barium zirconate electrolytes2016

    • Author(s)
      Donglin Han, Junji Iihara, Shigeaki Uemura, Kenji Kazumi, Chihiro Hiraiwa, Masatoshi Majima, Tetsuya Uda
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 4 Issue: 27 Pages: 10601-10608

    • DOI

      10.1039/c6ta03552c

    • NAID

      120006554794

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Phase Equilibria in the BaO-ZrO2-Y2O3-NiO System at 1500 C2017

    • Author(s)
      Katsuhiro Ueno, Naoyuki Hatada, Donglin Han, Yuki Otani, Akiko Kuramitsu, and Tetsuya Uda
    • Organizer
      The 12th Workshop on Reactive Metal Processing
    • Place of Presentation
      Massachusetts Institute of Technology, USA
    • Year and Date
      2017-03-03
    • Related Report
      2016 Annual Research Report
  • [Presentation] Y-doped BaZrO3 固溶体領域の調査2017

    • Author(s)
      植野雄大、畑田直行、韓東麟、倉満晶子、豊浦和明、宇田哲也
    • Organizer
      固体イオニクスセミナー
    • Related Report
      2017 Annual Research Report
  • [Presentation] 1500 CにおけるBaO-ZrO2-Y2O3-NiO擬四元系の相平衡2016

    • Author(s)
      植野雄大、畑田直行、韓東麟、宇田哲也
    • Organizer
      第42固体イオニクス討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2016-12-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] 高温還元による BaZr0.8Y0.2O3-δ 電解質に拡散した Ni の除去と電気伝導度の回復2016

    • Author(s)
      韓東麟、大谷祐基 、飯原順次、上村重明、鹿住健司、平岩千尋、真嶋正利、宇田哲也
    • Organizer
      第42固体イオニクス討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2016-12-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Phase Equilibria in the BaO-ZrO2-Y2O3-NiO System at 1500 C2016

    • Author(s)
      Naoyuki Hatada, Katsuhiro Ueno, Donglin Han, and Tetsuya Uda
    • Organizer
      18th International Conference on Solid State Protonic Conductors
    • Place of Presentation
      Soria Moria hotell og konferansesenter, Norway
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] BaZr0.8Y0.2O3-d (BZY20) 電解質における遷移金属元素の拡散挙動2016

    • Author(s)
      大谷祐基 , 韓東麟 , 宇田哲也
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-12-27  

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