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Fabrication of High-Performance Oxygen Reduction Electrode Catalysts Using Ionic Liquid-Quantum Beam Irradiation Method

Research Project

Project/Area Number 15H03591
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Quantum beam science
Research InstitutionOsaka University

Principal Investigator

Tsuda Tetsuya  大阪大学, 工学研究科, 准教授 (90527235)

Co-Investigator(Kenkyū-buntansha) 清野 智史  大阪大学, 工学研究科, 准教授 (90432517)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2017: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2016: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2015: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
Keywords量子ビーム / 電極触媒 / 燃料電池 / イオン液体
Outline of Final Research Achievements

The nanoparticle fabrication method by the quantum beam (accelerated electron beam, gamma ray, etc.) irradiation to ionic liquid (IL) can produce a wide variety of nanoparticles including unstable metals in aqueous solution without a reducing agent and a stabilizing agent for the produced nanoparticles. However, because IL is usually more expensive than other solvents, using cost-effective ILs like choline-based ones, we investigated the condition for obtaining the nanoparticles similar to those produced in conventional ILs and finally succeeded in finding it. In addition, the method for producing platinum-nickel alloy nanoparticles, which are expected to be one of next-generation oxygen reduction electrocatalysts, and the approach for supporting such nanoparticles to the carbon black surface were successfully established.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (34 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (4 results) Journal Article (10 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 10 results,  Open Access: 5 results,  Acknowledgement Compliant: 4 results) Presentation (17 results) (of which Int'l Joint Research: 8 results,  Invited: 7 results) Remarks (3 results)

  • [Int'l Joint Research] Kaohsiung Medical University/Soochow University(Taiwan)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] NIST/ORNL/The University of Mississippi(米国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] The University of Mississippi/NIST(米国)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] Kaohsiung Medical University/National Sun Yat-sen University(Taiwan)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Physicochemical Properties and Electrochemical Behavior of Systematically Functionalized Aryltrifluoroborate-Based Room-Temperature Ionic Liquids2018

    • Author(s)
      Iwasaki Kazuki、Tsuzuki Seiji、Tsuda Tetsuya、Kuwabata Susumu
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 6 Pages: 3286-3294

    • DOI

      10.1021/acs.jpcc.7b12274

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] SEM as a Facile Tool for Real-Time Monitoring of Microcrystal Growth during Electrodeposition: The Merit of Ionic Liquids2017

    • Author(s)
      Hsieh Yi-Ting、Tsuda Tetsuya、Kuwabata Susumu
    • Journal Title

      Analytical Chemistry

      Volume: 89 Issue: 13 Pages: 7249-7254

    • DOI

      10.1021/acs.analchem.7b01596

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Physicochemical properties of phenyltrifluoroborate-based room temperature ionic liquids2017

    • Author(s)
      Iwasaki Kazuki、Yoshii Kazuki、Tsuda Tetsuya、Kuwabata Susumu
    • Journal Title

      Journal of Molecular Liquids

      Volume: 246 Pages: 236-243

    • DOI

      10.1016/j.molliq.2017.09.067

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pt-Nanoparticle-Supported Carbon Electrocatalysts Functionalized with a Protic Ionic Liquid and Organic Salt2017

    • Author(s)
      Izumi Reiko、Yao Yu、Tsuda Tetsuya、Torimoto Tsukasa、Kuwabata Susumu
    • Journal Title

      Advanced Materials Interfaces

      Volume: 5 Issue: 3 Pages: 1701123-1701123

    • DOI

      10.1002/admi.201701123

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Boron and nitrogen co-doped ordered microporous carbons with high surface areas2017

    • Author(s)
      Alberto Castro-Muniz, Hirotomo Nishihara, Tetsuya Hirota, Mao Ohwada, Li-Xiang Li, Tetsuya Tsuda, Susumu Kuwabata, Jun Maruyama, Takashi Kyotani
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 100 Pages: 13348-13351

    • DOI

      10.1039/c7cc08390d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Highly Durable Pt Nanoparticle-supported Carbon Catalysts for the Oxygen Reduction Reaction Tailored by Using an Ionic Liquid Thin Layer2016

    • Author(s)
      Kazuki Yoshii, Keisuke Yamaji, Tetsuya Tsuda, Hiroaki Matsumoto, Takeshi Sato, Reiko Izumi, Tsukasa Torimoto, and Susumu Kuwabata
    • Journal Title

      J. Mater. Chem. A

      Volume: 4 Issue: 31 Pages: 12152-12157

    • DOI

      10.1039/c6ta04859e

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Novel Alkali Metal Salts with Designable Aromatic Trifluoroborate Anions2016

    • Author(s)
      Iwasaki, K.; Yoshii, K.; Tsuzuki, S.; Matsumoto, H.; Tsuda, T.; Kuwabata, S.
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 120 Issue: 35 Pages: 9468-9476

    • DOI

      10.1021/acs.jpcb.6b06990

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Multifunctional Electropolymerizable Carbazole-based Ionic Liquids2016

    • Author(s)
      Kirankumar, R.; Tsuda, T.; Chen, C.-Y.; Lu, C.-Y.; Kuwabata S.; Chen, P.-Y.
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 19 Pages: 15735-15744

    • DOI

      10.1039/c5ra23896j

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] In situ Scanning Electron Microscope Observation of Silicon Anode Reactions in Lithium-Ion Battery during Charge-Discharge Processes2016

    • Author(s)
      Chen, C.-Y.; Sano, T.; Tsuda, T.; Ui, K.; Oshima, Y.; Yamagata, M.; Ishikawa, M.; Haruta, M.; Doi, T.; Inaba, M.; Kuwabata, S.
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 36153-36153

    • DOI

      10.1038/srep36153

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Electrodeposition of Al-W-Mn Ternary Alloys from the Lewis Acidic Aluminum Chloride-1-Ethyl-3-methylimidazolium Chloride Ionic Liquid2015

    • Author(s)
      Tetsuya Tsuda, Yuichi Ikeda, Akihito Imanishi, Shohei Kusumoto, Susumu Kuwabata, Gery R. Stafford, and Charles L. Hussey
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 162 Issue: 9 Pages: D405-D411

    • DOI

      10.1149/2.0051509jes

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] プロトン性イオン液体により高機能化されたPtナノ粒子担持炭素触媒2017

    • Author(s)
      泉 礼子、Yu Yao、津田哲哉、鳥本 司、桑畑 進
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      八王子市、首都大学東京
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] In situ electron microscope techniques for a Li metal deposition/stripping process2017

    • Author(s)
      Tetsuya Tsuda, Chih-Yao Chen, and Susumu Kuwabata
    • Organizer
      9th Kyoto International Forum for Environment and Energy (KIFEE)
    • Place of Presentation
      Doshisha University, Kyoto (Japan)
    • Year and Date
      2017-03-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Chemical reactions in ionic liquid with an epoxy group2017

    • Author(s)
      Tetsuya Tsuda, Kazuki Iwasaki, Kohei Kumagai, and Susumu Kuwabata
    • Organizer
      3rd International Conference on Ionic Liquids in Separation and Purification Technology
    • Place of Presentation
      Kuala Lumpur (Malaysia)
    • Year and Date
      2017-01-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In situ Electron Microscope Observation for High Capacity Anodes in Next-Generation IL-Based Li Batteries2017

    • Author(s)
      Tetsuya Tsuda, Chih-Yao Chen, Yoshifumi Oshima, Susumu Kuwabata
    • Organizer
      68th Annual Meeting of the International Society of Electrochemistry, Providence
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Systematic Consideration of Physicochemical Properties on Aryltrifluoroborate-Based Room-Temperature Ionic Liquids2017

    • Author(s)
      Kazuki Iwasaki, Hajime Matsumoto, Tetsuya Tsuda, and Susumu Kuwabata
    • Organizer
      232nd ECS Meeting
    • Related Report
      2017 Annual Research Report
  • [Presentation] Preparation of Aryltrifluoroborate-based Alkali Meal Salts and Evaluation of the Basic Physicochemical Properties2017

    • Author(s)
      Kazuki Iwasaki, Seiji Tsuzuki, Tetsuya Tsuda, and Susumu Kuwabata
    • Organizer
      Taiwan-Japan Bilateral Workshop 2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] One-Pot Preparation of Pt-Ni Alloy Nanoparticles-Supported MWCNTs and Their Electrocatalytic Properties2016

    • Author(s)
      Yu Yao, Reiko Izumi, Tetsuya Tsuda, and Susumu Kuwabata
    • Organizer
      第7回イオン液体討論会
    • Place of Presentation
      金沢市、金沢市文化ホール
    • Year and Date
      2016-10-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] プロトン性イオン液体を用いて作製したPtナノ粒子担持炭素材料の酸素還元触媒特性2016

    • Author(s)
      泉 礼子、Yu Yao、津田哲哉、鳥本 司、桑畑 進
    • Organizer
      第7回イオン液体討論会
    • Place of Presentation
      金沢市、金沢市文化ホール
    • Year and Date
      2016-10-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] Carbon Material-Based Positive Electrodes for Aluminum Secondary Battery with a Chloroaluminate Ionic Liquid2016

    • Author(s)
      Tetsuya Tsuda, Yuya Uemura, Chih-Yao Chen, Itsuki Kokubo, and Susumu Kuwabata
    • Organizer
      PRiME2016
    • Place of Presentation
      Honolulu, HI (USA)
    • Year and Date
      2016-10-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Pt-Ni Nanoparticle-Supported Multiwalled Carbon Nanotube Prepared By One-Pot Pyrolysis Method in Room-Temperature Ionic Liquids2016

    • Author(s)
      Yu Yao, Reiko Izumi, Tsuyoshi Sakamoto, Tetsuya Tsuda, and Susumu Kuwabata
    • Organizer
      PRiME2016
    • Place of Presentation
      Honolulu, HI (USA)
    • Year and Date
      2016-10-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Carbon Material-Based Positive Electrodes for Aluminum Secondary Battery with a Chloroaluminate Ionic Liquid2016

    • Author(s)
      Tetsuya Tsuda, Yuya Uemura, Chin-Yao Chen, Itsuki Kokubo, and Susumu Kuwabata
    • Organizer
      PRiME2016
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2016-10-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Aluminum Electrodeposition from a Chloroaluminate Ionic Liquid with Lanthanum Chloride2016

    • Author(s)
      Tetsuya Tsuda and Toshiyuki Nohira
    • Organizer
      Rare Earths 2016
    • Place of Presentation
      Sapporo, Hokkaido University (Japan)
    • Year and Date
      2016-06-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ALUMINUM ELECTEODEPOSITION FROM A CHLOROALUMINATE IONIC LIQUID WITH LANTHANUM CHLORIDE2016

    • Author(s)
      Tetsuya Tsuda and Toshiyuki Nohira
    • Organizer
      Rare Earths 2016
    • Place of Presentation
      Hokkaido University (Sapporo), Japan
    • Year and Date
      2016-06-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] アルミニウム二次電池用合材正極の開発2015

    • Author(s)
      津田哲哉、小久保 樹、橋本 佑、上村祐也、桑畑 進
    • Organizer
      第56回電池討論会
    • Place of Presentation
      愛知県産業労働センター(愛知県名古屋市)
    • Year and Date
      2015-11-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] 炭素材料を用いたアルミニウム二次電池用正極2015

    • Author(s)
      津田哲哉、桑畑 進
    • Organizer
      第93回新電池構想部会
    • Place of Presentation
      大阪府立大学I-siteなんば(大阪府大阪市)
    • Year and Date
      2015-10-30
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] イオン液体を用いた電子顕微鏡観察法 ~ バイオフィルム観察への応用 ~2015

    • Author(s)
      津田哲哉
    • Organizer
      日本鉄鋼協会評価・分析・解析部会 「バイオファウリング、バイオフィルム評価分析解析研究」フォーラム 平成27年度第1回講演会
    • Place of Presentation
      鈴鹿高等工業専門学校(三重県鈴鹿市)
    • Year and Date
      2015-09-01
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 量子ビームとイオン液体を利用したナノ・マイクロ材料プロセッシング2015

    • Author(s)
      津田哲哉
    • Organizer
      第71回マテリアルズ・テーラリング研究会
    • Place of Presentation
      (公益財団法人)加藤山崎教育基金 軽井沢研修所(長野県軽井沢市)
    • Year and Date
      2015-08-07
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Remarks] 研究室ホームページ

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~elechem/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 研究室Webpage

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~elechem/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 研究室webpage

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~elechem/

    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2022-08-26  

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