| Budget Amount *help |
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2017: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2016: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
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| Outline of Final Research Achievements |
In this project, we aimed to create quantum condensed phases of confined molecules or atoms and to elucidate their behavior and properties, in nano-sized porous space of porous coordination polymers. During the research period, we mainly carried out the following; (1) elucidation of behavior of confined NO and I2 molecules in the pore, (2) induction of ortho-para quantum phase transition of nuclear spin isomers of H2 using inner electric field of the pore, and (3) creation of high-temperature quantum condensed phase of He. Dynamics and physical properties of confined guest molecules or atoms and guest-guest or host-guest interactions were examined in detail, by using in situ measurements of temperature dependences of magnetization, X-ray diffraction, and Raman and IR spectra under pressure-controlled guest atmosphere.
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