Development of doubly-bonded species between heavier group 14 elements and oxygen and their application for activation of small molecules

• Project/Area Number: 15H03788
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: Kindai University
• Principal Investigator: Matsuo Tsukasa 近畿大学, 理工学部, 准教授 (90312800)
• Project Period (FY): 2015-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000); Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2015: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
• Keywords: 高周期14族元素 / シラノン / ゲルマノン / スタンナノン / シリレン / ゲルミレン / スタンニレン / 立体保護基 / 高周期１４族元素 / プルンバノン / 小分子活性化

Outline of Final Research Achievements

Doubly-bonded species between heavier group 14 elements and oxygen atom have been studied by the introduction of the fused-ring bulky "Rind" groups. A series of diaryltetrylenes have been synthesized, whose molecular structures and electronic properties have been elucidated by the experimental and computational studies. Novel tin-oxygen doubly-bonded species, stannanone, have been successfully obtained by the reaction of the corresponding stannylene with nitrous oxide gas. The reactions of stannanone with small molecules such as water and carbon dioxide have been investigated.

Research Products

• [Int'l Joint Research] Toulouse University(France)
• [Journal Article] π-Electron Systems Containing Si=Si Double Bonds (2018)
  • Author(s): T. Matsuo, N. Hayakawa
  • Journal Title: Science and Technology of Advanced Materials Volume: 19 Issue: 1 Pages: 108-129
  • DOI: 10.1080/14686996.2017.1414552
  • Peer Reviewed
• [Journal Article] 1,2-Dihalodigermenes bearing bulky Eind groups: synthesis, characterization, and conversion to halogermylenoids (2018)
  • Author(s): Hayakawa, N.; Sugahara, T.; Numata, Y.; Kawaai, H.; Yamatani, K.; Nishimura, S.; Goda, S.; Suzuki, Y.; Tanikawa, T.; Nakai, H.; Hashizume, D.; Sasamori, T.; Tokitoh, N.; Matsuo, T.
  • Journal Title: Dalton Trans. Volume: 47 Issue: 3 Pages: 814-822
  • DOI: 10.1039/c7dt03819d
  • Peer Reviewed
• [Journal Article] A stable free tetragermacyclobutadiene incorporating fused-ring bulky EMind groups (2018)
  • Author(s): K. Suzuki, Y. Numata, N. Fujita, N. Hayakawa, T. Tanikawa, D. Hashizume, K. Tamao, H. Fueno, K. Tanaka, T. Matsuo
  • Journal Title: Chem. Commun. Volume: 54 Issue: 18 Pages: 2200-2203
  • DOI: 10.1039/c7cc09443d
  • Peer Reviewed
• [Journal Article] Synthesis and Characterization of N-Heterocyclic Carbene-Coordinated Silicon Compounds Bearing a Fused-Ring Bulky Eind Group (2018)
  • Author(s): Hayakawa Naoki、Sadamori Kazuya、Mizutani Shinsuke、Agou Tomohiro、Sugahara Tomohiro、Sasamori Takahiro、Tokitoh Norihiro、Hashizume Daisuke、Matsuo Tsukasa
  • Journal Title: Inorganics Volume: 6 Issue: 1 Pages: 30-30
  • DOI: 10.3390/inorganics6010030
  • NAID: 120006501344
  • Peer Reviewed / Open Access
• [Journal Article] Thermally Stable Monosubstituted Thiophene 1-Oxide and 1-Imides Stabilized by a Bulky Rind Group at Their 3-Position: Synthesis, Structure and Inversion Barriers on the Sulfur Atom (2017)
  • Author(s): Takashi Otani, Mayu Miyoshi, Takanori Shibata, Tsukasa Matsuo, Daisuke Hashizume, Kohei Tamao
  • Journal Title: Bulletin of Chemical Sciety of Japan Volume: 90 Issue: 6 Pages: 697-705
  • DOI: 10.1246/bcsj.20170042
  • NAID: 130006770650
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Cleavage of a P=P Double Bond Mediated by N-Hetrocyclic Carbenes (2017)
  • Author(s): N. Hayakawa, K. Sadamori, S. Tsujimoto, M. Hatanaka, T. Wakabayashi, T. Matsuo
  • Journal Title: Angew. Chem. Int. Ed. Volume: 印刷中 Issue: 21 Pages: 5765-5769
  • DOI: 10.1002/anie.201701201
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] π-Conjugation between a Si=Si Double Bond and Thiophene Rings: Synthesis, Structural Characteristics, and Photophysical Properties of 1,2-Bis(thiophen-2-yl)disilene and 1,2-Bis(2,2'-bithiophene-5-yl)disilene (2017)
  • Author(s): N. Hayakawa, S. Nishimura, N. Kazusa, N. Shintani, T. Nakahodo, H. Fujihara, M. Hoshino, D. Hashizume, T. Matsuo
  • Journal Title: Organometallics Volume: 36 Issue: 17 Pages: 3226-3233
  • DOI: 10.1021/acs.organomet.7b00370
  • Peer Reviewed
• [Journal Article] Synthesis and Magnetic Properties of Linear Two-Coordinate Monomeric Diaryliron(II) Complexes Bearing Fused-Ring Bulky “Rind” Groups (2016)
  • Author(s): Shun Goda, Masanori Nikai, Mikinao Ito, Daisuke Hashizume, Kohei Tamao, Atsushi Okazawa, Norimichi Kojima, Hiroyuki Fueno, Kazuyoshi Tanaka, Yoshio Kobayashi, and Tsukasa Matsuo
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 印刷中 Issue: 6 Pages: 636-638
  • DOI: 10.1246/cl.160216
  • NAID: 130005155021
  • Peer Reviewed / Open Access
• [Journal Article] Unsymmetircal PNP-Pincer Type Phosphaalkene Ligands Protected by a Fused- Ring Bulky Eind Group: Synthesis and Applications to Rh(I) and Ir(I) Complexes (2016)
  • Author(s): H. Taguchi, D. Sasaki, K. Takeuchi, S. Tsujimoto, T. Matsuo, H. Tanaka, K. Yoshizawa, F. Ozawa
  • Journal Title: Organometallics Volume: 35 Issue: 10 Pages: 1526-1533
  • DOI: 10.1021/acs.organomet.6b00113
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis and Structural Characterization of Lithium and Titanium Complexes Bearing a Bulky Aryloxide Ligand Based on a Rigid Fused-Ring s-Hydrindacene Skeleton (2016)
  • Author(s): Shoya Kanazawa, Taishi Ohira, Shun Goda, Naoki Hayakawa, Tomoharu Tanikawa, Daisuke Hashizume, Yutaka Ishida, Hiroyuki Kawaguchi, Tsukasa Matsuo
  • Journal Title: Inorganic Chemistry Volume: 55 Issue: 13 Pages: 6643-6652
  • DOI: 10.1021/acs.inorgchem.6b00762
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species (2016)
  • Author(s): K. Nagata, T. Murosaki, T. Agou, T. Sasamori, T. Matsuo, N. Tokitoh
  • Journal Title: Angew. Chem. Int. Ed. Volume: 55 Issue: 41 Pages: 12877-12880
  • DOI: 10.1002/anie.201606684
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis and Structural Characteristics of Discrete Organoboron and Organoaluminum Hydrides Incorporating Bulky Eind Groups (2016)
  • Author(s): Takahiro Murosaki, Shohei Kaneda, Ryota Maruhashi, Kazuya Sadamori, Yoshiaki Shoji, Kohei Tamao, Daisuke Hashizume, Naoki Hayakawa, Tsukasa Matsuo
  • Journal Title: Organometallics Volume: 35 Issue: 19 Pages: 3397-3405
  • DOI: 10.1021/acs.organomet.6b00633
  • Peer Reviewed / Open Access
• [Journal Article] A Silylyne Tungsten Complex Having an Eind Group on Silicon: Its Dimer-Monomer Equilibrium and Cycloaddition Reactions with Carbodiimide and Diaryl Ketones (2016)
  • Author(s): T. Yoshimoto, H. Hashimoto, N. Hayakawa, T. Matsuo, H. Tobita
  • Journal Title: Organometallics Volume: 35 Issue: 20 Pages: 3444-3447
  • DOI: 10.1021/acs.organomet.6b00670
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] A Square Planar Complex of Platinum(0) (2016)
  • Author(s): K. Takeuchi, H. Taguchi, I. Tanigawa, S. Tsujimoto, T. Matsuo, H. Tanaka, K. Yoshizawa, F. Ozawa
  • Journal Title: Angew. Chem. Int. Ed. Volume: 55 Issue: 49 Pages: 15347-15350
  • DOI: 10.1002/anie.201609515
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis and Structures of Sterically Congested Diarylsilanes Bearing Two Bulky Rind Groups (2016)
  • Author(s): N. Hayakawa, T. Morimoto, A. Takagi, T. Tanikawa, D. Hashizume, T. Matsuo
  • Journal Title: Chem. Lett. Volume: 45 Issue: 4 Pages: 409-411
  • DOI: 10.1246/cl.151191
  • NAID: 130005143979
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] (Z)-1,2-Di(1-pyrenyl)disilene: Synthesis, Structure, and Intramolecular Charge-Transfer Emission (2016)
  • Author(s): M. Kobayashi, N. Hayakawa, T. Matsuo, B. Li, T. Fukunaga, D. Hashizume, H. Fueno, K. Tanaka, K. Tamao
  • Journal Title: J. Am. Chem. Volume: 138 Issue: 3 Pages: 758-761
  • DOI: 10.1021/jacs.5b11970
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] 炭素とケイ素の不思議（14族元素） (2016)
  • Author(s): 松尾 司
  • Journal Title: 月刊うちゅう（大阪市立科学館） Volume: 32 Pages: 4-9
  • Open Access
• [Journal Article] Coplanar Oligo(p-phenylenedisilenylene)s as Si=Si Analogues of Oligo(p-phenylenevinylene)s: Evidence for Extended π-Conjugation through the Carbon and Silicon π-Frameworks (2015)
  • Author(s): L. Li, T. Matsuo, D. Hashizume, H. Fueno, K. Tanaka, K. Tamao
  • Journal Title: J. Am. Chem. Volume: 137 Issue: 47 Pages: 15026-15035
  • DOI: 10.1021/jacs.5b10113
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Fused-Ring Bulky "Rind" Groups Producing New Possibilities in Elemento-Organic Chemistry (2015)
  • Author(s): T. Matsuo, K. Tamao
  • Journal Title: Bull. Chem. Soc. Jpn Volume: 88 Issue: 9 Pages: 1201-1220
  • DOI: 10.1246/bcsj.20150130
  • NAID: 130005099097
  • Peer Reviewed / Open Access
• [Presentation] かさ高いRind基を有するジアリールプルンビレンの合成と反応性 (2018)
  • Author(s): 小中重明・早川直輝・松尾司
  • Organizer: 日本化学会第98春季年会
• [Presentation] テトラゲルマシクロブタジエンの合成と反応性 (2018)
  • Author(s): 沼田泰幸・早川直輝・松尾司
  • Organizer: 日本化学会第98春季年会
• [Presentation] かさ高いカルボキシラート配位子を有する高周期14族元素二価化学種の合成と構造 (2018)
  • Author(s): 山下凌汰・宮本優・西谷誠寿・早川直輝・松尾司
  • Organizer: 日本化学会第98春季年会
• [Presentation] π共役系ジゲルメン化合物の合成と物性 (2018)
  • Author(s): 早川直輝・沼田泰幸・河合穂高・山谷健太・橋爪大輔・松尾司
  • Organizer: 日本化学会第98春季年会
• [Presentation] かさ高いMPind基を有する高周期14族元素不飽和結合化学種の合成 (2018)
  • Author(s): 大野稜真・眞上晃輔・小中重明・沼田泰幸・早川直輝・松尾司
  • Organizer: 日本化学会第98春季年会
• [Presentation] かさ高いEind基を有するヒドロシリレン・NHC付加体の合成 (2018)
  • Author(s): 貞森和也・早川直輝・松尾司
  • Organizer: 日本化学会第98春季年会
• [Presentation] かさ高いRind基を有するジアリールテトリレン (2017)
  • Author(s): 小中重明・沼田泰幸・谷川智春・森本達人・早川直輝・橋爪大輔・松尾司
  • Organizer: 第44回有機典型元素化学討論会
• [Presentation] かさ高いカルボキシラート配位子を有するテトリレノイドの合成と構造 (2017)
  • Author(s): 山下凌汰・宮本優・鈴木誠寿・早川直輝・松尾司
  • Organizer: 第44回有機典型元素化学討論会
• [Presentation] かさ高いEMind基を有するジハロジゲルメンの合成と反応 (2017)
  • Author(s): 沼田泰幸・谷川智春・早川直輝・松尾司
  • Organizer: 第44回有機典型元素化学討論会
• [Presentation] かさ高いRind基を有するジホスフェンの反応 (2017)
  • Author(s): 貞森和也・辻本祥太・早川直輝・畑中美穂・橋爪大輔・松尾司
  • Organizer: 第44回有機典型元素化学討論会
• [Presentation] かさ高いMPind基を有する14族元素化合物の合成 (2017)
  • Author(s): 大野稜真・眞上晃輔・小中重明・沼田泰幸・早川直輝・松尾司
  • Organizer: 第21回ケイ素化学協会シンポジウム
• [Presentation] 種々のかさ高いRind基を有するジアリールプルンビレンの合成と構造 (2017)
  • Author(s): 小中重明・早川直輝・松尾司
  • Organizer: 第21回ケイ素化学協会シンポジウム
• [Presentation] かさ高いRind基を有するシリレン・NHC付加体の合成 (2017)
  • Author(s): 貞森和也・早川直輝・松尾司
  • Organizer: 第21回ケイ素化学協会シンポジウム
• [Presentation] 種々のかさ高いRind基を有するブロモスタンニレンの合成と構造 (2017)
  • Author(s): 沼田泰幸・早川直輝・谷川智春・小中重明・松尾司
  • Organizer: 第21回ケイ素化学協会シンポジウム
• [Presentation] かさ高いRind基を有するジハロジゲルメンの反応性の調査 (2017)
  • Author(s): 早川直輝・菅原知紘・沼田泰幸・河合穂高・山谷健太・橋爪大輔・笹森貴裕・時任宣博・松尾司
  • Organizer: 第21回ケイ素化学協会シンポジウム
• [Presentation] かさ高いカルボキシラート配位子を有するゲルミレノイドの合成と構造 (2017)
  • Author(s): 山下凌汰・宮本優・鈴木誠寿・早川直輝・松尾司
  • Organizer: 第21回ケイ素化学協会シンポジウム
• [Presentation] Synthesis of NHC-Silylene Adducts with the Rind Groups (2017)
  • Author(s): K. Sadamori, N. Hayakawa, T. Matsuo
  • Organizer: The 18th International Symposium on Silicon Chemistry (ISOS XVIII)
  • Int'l Joint Research
• [Presentation] Synthesis, Structural Characterization, and Electronic Properties of Diaryl-substituted Tetrylenes, (Rind)2E: (E = Si, Ge, Sn, and Pb) (2017)
  • Author(s): Y. Numata, N. Hayakawa, S. Konaka, K. Hara, N. Fujita, T. Morimoto, T. Tanikawa, D. Hashizume, T. Matsuo
  • Organizer: The 18th International Symposium on Silicon Chemistry (ISOS XVIII)
  • Int'l Joint Research
• [Presentation] π-Conjugated Ditetrenes Bearing the Rind Groups (2017)
  • Author(s): N. Hayakawa, S. Nishimura, H. Kawaai, K. Yamatani, T. Fukawa, M. Kobayashi, K. Tamao, D. Hashizume, H. Fueno, K. Tanaka, T. Matsuo
  • Organizer: The 18th International Symposium on Silicon Chemistry (ISOS XVIII)
  • Int'l Joint Research
• [Presentation] Synthesis, Structural Characterization, and Electronic Properties of Diaryl-substituted Tetrylenes, (Eind)2E: (E = Si, Ge, Sn, and Pb) (2017)
  • Author(s): Tsukasa Matsuo
  • Organizer: 感応性化学種が拓く新物質科学 第２回国際シンポジウム
  • Place of Presentation: 広島大学（東広島市）
  • Int'l Joint Research
• [Presentation] Dihalodigermenes Stabilized by the Bulky Rind Groups (2017)
  • Author(s): . Hayakawa, Y. Numata, H. Kawaai, K. Yamatani, S. Goda, D. Hashizume, T. Sugahara, T. Sasamori, N. Tokitoh, T. Matsuo
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶應義塾大学（横浜市）
• [Presentation] かさ高いRind 基を有するスタンニレンの合成 (2017)
  • Author(s): 沼田泰幸・小中重明・早川直輝・原光平・谷川智春・松尾司
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶應義塾大学（横浜市）
• [Presentation] かさ高いRind 基を有するプルンビレンの合成 (2017)
  • Author(s): 小中重明・早川直輝・松尾司
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶應義塾大学（横浜市）
• [Presentation] Fused-Ring Bulky Rind Groups Producing New Possibilities in Organoelement Chemistry (2016)
  • Author(s): T. Matsuo
  • Organizer: Institute for Chemical Research International Symposium 2016 (ICRIS’16)
  • Place of Presentation: 京都大学化学研究所
  • Year and Date: 2016-03-07
  • Int'l Joint Research / Invited
• [Presentation] sp2ケイ素のビルドアップ技術の開発 (2016)
  • Author(s): 松尾 司
  • Organizer: ケイ素材料の新展開：環境共生スマート材料研究拠点講演会
  • Place of Presentation: 広島大学
  • Year and Date: 2016-02-29
  • Invited
• [Presentation] π-Conjugated Disilenes Stabilized by Bulky Rind Groups (2016)
  • Author(s): Tsukasa Matsuo
  • Organizer: 第70回藤原セミナー
  • Place of Presentation: ザ・ルイガンズ（福岡市）
  • Int'l Joint Research / Invited
• [Presentation] かさ高いEind基で安定化されたジハロジゲルメン (2016)
  • Author(s): 早川直輝・河合穂高・山谷健太・合田舜・谷川智春・橋爪大輔・松尾司
  • Organizer: 第十一回有機元素化学セミナー
  • Place of Presentation: 京都大学化学研究所（宇治市）
• [Presentation] Germanone and Related Compounds (2016)
  • Author(s): Tsukasa Matsuo, Naoko Fujita, Tastuto Morimoro, Naoki Hayakawa, Tomoharu Tanikawa, Daisuke Hashizume, Hiroyuki Fueno, Kazuyoshi Tanaka
  • Organizer: International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (GTL 2016)
  • Place of Presentation: Pardubice, Czech Republic
  • Int'l Joint Research
• [Presentation] Dihalodigermenes Stabilized by the Bulky Rind Groups (2016)
  • Author(s): Naoki Hayakawa, Yasuyuki Numata, Hotaka Kawaai, Kenta Tamatani, Shun Goda, Tomoharu Tanikawa, Daisuke Hashizume, Tsukasa Matsuo
  • Organizer: International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (GTL 2016)
  • Place of Presentation: Pardubice, Czech Republic
  • Int'l Joint Research
• [Presentation] かさ高いRind基によって安定化されたジハルジゲルメン (2016)
  • Author(s): 早川直輝・沼田泰幸・河合穂高・山谷健太・合田舜・谷川智春・橋爪大輔・松尾司
  • Organizer: 第63回有機金属化学討論会
  • Place of Presentation: 早稲田大学（東京都新宿区）
• [Presentation] ジハロジゲルメンの合成と反応 (2016)
  • Author(s): 早川直輝・沼田泰幸・河合穂高・山谷健太・合田舜・谷川智春・橋爪大輔・松尾司
  • Organizer: 第20回ケイ素化学協会シンポジウム
  • Place of Presentation: 安芸グランドホテル（廿日市市）
• [Presentation] かさ高いRind基を有するスタンニレンの合成 (2016)
  • Author(s): 沼田泰幸・小中重明・早川直輝・原光平・谷川智春・松尾司
  • Organizer: 第20回ケイ素化学協会シンポジウム
  • Place of Presentation: 安芸グランドホテル（廿日市市）
• [Presentation] かさ高いRind基を有するプルンビレンの合成 (2016)
  • Author(s): 小中重明・早川直輝・松尾司
  • Organizer: 第20回ケイ素化学協会シンポジウム
  • Place of Presentation: 安芸グランドホテル（廿日市市）
• [Presentation] ジハロジゲルメンの合成と反応 (2016)
  • Author(s): 早川直輝・沼田泰幸・河合穂高・山谷健太・合田舜・谷川智春・橋爪大輔・松尾司
  • Organizer: 第43回有機典型元素化学討論会
  • Place of Presentation: 仙台市民会館（仙台市）
• [Presentation] ゲルマニウムを含むケトン関連化合物の合成 (2015)
  • Author(s): 藤田直子・李 良春・橋爪大輔・玉尾皓平・笛野博之・田中一義・松尾 司
  • Organizer: 第19回ケイ素化学協会シンポジウム
  • Place of Presentation: ラフォーレ琵琶湖（滋賀県）
  • Year and Date: 2015-10-23
• [Presentation] Germanium Ketone Analogues, (Rind)2Ge=E (E = O, S, Se): Synthesis, Structures, and Bonding Properties (2015)
  • Author(s): Naoko Fujita, Liangchun Li, Daisuke Hashizume, Kohei Tamao, Hiroyuki Fueno, Kazuyoshi Tanaka, Tsukasa Matsuo
  • Organizer: The 5th Asian Silicon Symposium (ASiS-5)
  • Place of Presentation: Lotte City Hotel Jeju, Korea
  • Year and Date: 2015-10-19
  • Int'l Joint Research
• [Presentation] Diarylsilylenes Bearing the Bulky Rind Groups (2015)
  • Author(s): Tsukasa Matsuo, Tatsuto Motimoto, Naoki Hayakawa, Daisuke Hashizume, Hiroyuki Fueno, Kazuyoshi Tanaka
  • Organizer: The 5th Asian Silicon Symposium (ASiS-5)
  • Place of Presentation: Lotte City Hotel Jeju, Korea
  • Year and Date: 2015-10-19
  • Int'l Joint Research
• [Presentation] 高周期14族元素－酸素二重結合化学種の創製 (2015)
  • Author(s): 松尾 司
  • Organizer: 東京工業大学講演会
  • Place of Presentation: 東京工業大学
  • Year and Date: 2015-07-28
  • Invited
• [Presentation] 炭素とケイ素の不思議（14族元素） (2015)
  • Author(s): 松尾 司
  • Organizer: 元素検定2015
  • Place of Presentation: 大阪市立科学館
  • Year and Date: 2015-06-28
  • Invited
• [Presentation] Fused-Ring Bulky Rind Groups Producing New Possibilities in Organoelement Chemistry (2015)
  • Author(s): T. Matsuo
  • Organizer: The 10th Organoelement Chemistry Seminar
  • Place of Presentation: 京都大学化学研究所
  • Year and Date: 2015-06-08
  • Int'l Joint Research / Invited
• [Presentation] Germanium Ketone Analogues, (Rind)2Ge=E (E = O, S, and Se): Synthesis, Structures, and Bonding Properties (2015)
  • Author(s): aoko Fujita, Liangchun Li, Daisuke Hashizume, Kohei Tamao, Hiroyuki Fueno, Kazuyoshi Tanaka, Tsukasa Matsuo
  • Organizer: The 10th Organoelement Chemistry Seminar
  • Place of Presentation: 京都大学化学研究所
  • Year and Date: 2015-06-08
  • Int'l Joint Research
• [Remarks] 近畿大学応用元素化学研究室
  • URL: http://www.apch.kindai.ac.jp/element-folder/index.html
• [Remarks] 近畿大学理工学部・総合理工学研究科 最先端研究
  • URL: http://www.kindai.ac.jp/sci/research/forefront_research/matsuo_tsukasa.html