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Processing and property of hydrophobic oxide ceramics without using organic compounds

Research Project

Project/Area Number 15H04120
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionTokyo Institute of Technology

Principal Investigator

Nakajima Akira  東京工業大学, 物質理工学院, 教授 (00302795)

Co-Investigator(Kenkyū-buntansha) 磯部 敏宏  東京工業大学, 物質理工学院, 助教 (20518287)
松下 祥子  東京工業大学, 物質理工学院, 准教授 (50342853)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2017: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
Keywords撥水 / 合成空気 / 希土類 / 乾燥空気 / セラミックス / 有機物 / 酸化物
Outline of Final Research Achievements

Sintered bodies of Gd2O3 were prepared by uniaxial pressing of an oxide powder, followed by firing in a synthesized air atmosphere. Samples were initially hydrophilic after firing. However, their water contact angles increased during storage in ambient air. The surface hydrophobicity was non-existent after ozonation, but it recovered during two weeks of ambient air storage. It corresponded to the carbon concentration ratio on the surface. Fourier-transform infrared spectroscopy revealed a difference in stretching vibrations of the OH group at around 3400 cm-1 and 3600 cm-1 between Gd2O3 and other oxides. Results suggest that this hydrophobicity originated from the adsorption of organic substances from ambient air onto the surface. Similar effect was confirmed also on ZnO nanorod samples. Based on these results, we have successfully prepared an oxide ceramics with self-hydrophobicity, antibacterial and antivirus properties.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (19 results)

All 2018 2017 2016 2015

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 2 results) Presentation (15 results) (of which Int'l Joint Research: 4 results,  Invited: 6 results)

  • [Journal Article] Comparative study of the dynamic hydrophobicity of fluoroalkylsilane coatings tilted at acute and obtuse angles2018

    • Author(s)
      Y. Higashino, H. Takahashi, M. Sakai, T. Isobe, S. Matsushita, A. Nakajima
    • Journal Title

      J. Coatings Tech. Res.

      Volume: 印刷中 Issue: 4 Pages: 891-898

    • DOI

      10.1007/s11998-018-0064-5

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sliding of water/glycerol mixture droplets on hydrophobic solid?liquid bulk composites using Ti plates with a fibrous TiO2 layer2017

    • Author(s)
      Takahashi Hirokazu、Higashino Yuta、Sakai Munetoshi、Isobe Toshihiro、Matsushita Sachiko、Nakajima Akira
    • Journal Title

      J. Mater. Sci.

      Volume: 53 Issue: 2 Pages: 1157-1166

    • DOI

      10.1007/s10853-017-1582-8

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Droplet viscosity effects on dynamic hydrophobicity of a solid/liquid bulk composite prepared from porous glass2017

    • Author(s)
      K. Yokoyama, M. Sakai, T. Isobe, S. Matsushita, A. Nakajima
    • Journal Title

      J. Mater. Sci.

      Volume: 52 Issue: 1 Pages: 595-604

    • DOI

      10.1007/s10853-016-0356-z

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Comparison of photocatalytic activity and surface friction force variation on Ti-doped hydroxyapatite and anatase under UV illumination2015

    • Author(s)
      Ayumi Tsuruoka, Toshihiro Isobe(研究分担者), Sachiko Matsushita(研究分担者), Masato Wakamura, Akira Nakajima(研究代表者)
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry

      Volume: 311 Pages: 160-165

    • DOI

      10.1016/j.jphotochem.2015.07.001

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 固体表面の動的撥水性に関する最近の話題2017

    • Author(s)
      中島章
    • Organizer
      日本セラミックス協会2017年年会資源・環境材料部会特別講演
    • Place of Presentation
      日本大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] マイナスアングルに傾斜させたシラン表面での動的撥水性2017

    • Author(s)
      東野悠太、磯部敏宏、松下祥子、中島章
    • Organizer
      日本セラミックス協会2017年年会サテライトプログラム
    • Place of Presentation
      日本大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] 固体/液体複合撥水性材料上での水-グリセリン混合液体の転落2017

    • Author(s)
      高橋宏和、酒井宗寿、磯部敏宏、松下祥子、中島章
    • Organizer
      日本セラミックス協会2017年年会
    • Place of Presentation
      日本大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] Evaluation and control of droplet motion on various hydrophobic silane coatings2017

    • Author(s)
      A. Nakajima, M. Sakai
    • Organizer
      The 3rd Symposium of the Center for Nature-derived Materials & 4th GRIP2017, September 26, 2017, Jappan Advanced Institure of Science and Technology (北陸先端大), Ishikawa, Japan.
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 撥水性シランコーティングの静的・動的撥水性とその応用2017

    • Author(s)
      中島章
    • Organizer
      日本分析化学会, 高分子分析研究懇談会、明治大学、4月21日(2017)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 固体表面の動的撥水性に関する最近の話題2017

    • Author(s)
      中島章
    • Organizer
      第33回日本イオン交換学会研究発表会, 特別講演,山梨大学、10月26日(2017)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Comparative Study of the Dynamic Hydrophobicity of Fluoroalkylsilane Coatings Tilted at Acute and Obtuse Angles2017

    • Author(s)
      Y. Higashino, H. Takahashi, M. Sakai T. Isobe, S. Matsushita, A. Nakajima
    • Organizer
      90th JSCM Anniversary Conference, October 17-18 (presented on 17th), 2017, Gakushi-Kaikan, Tokyo, JAPAN.
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation and Evaluation of Hydrophobic ZnO Nanorod Arrays2017

    • Author(s)
      T. Kano, T. Isobe, S. Matsushita, A. Nakajima
    • Organizer
      90th JSCM Anniversary Conference, October 17-18 (presented on 18th), 2017, Gakushi-Kaikan, Tokyo, JAPAN.
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ZnOナノロッドアレイを用いた撥水材料の作製と評価2017

    • Author(s)
      叶野貴大、磯部敏宏、松下祥子、中島章
    • Organizer
      日本セラミックス協会第30回秋季シンポジウム, 1Q06 (2017)、9月19日、神戸大学
    • Related Report
      2017 Annual Research Report
  • [Presentation] ぬれの基礎と評価法2016

    • Author(s)
      中島章
    • Organizer
      第14回(平成28年度)『界面活性剤評価・試験法』セミナー
    • Place of Presentation
      油脂工業会館
    • Year and Date
      2016-11-21
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 多孔質ガラスを用いた固体/液体複合材料の動的撥水性に及ぼす液滴の粘性の影響2016

    • Author(s)
      横山広大、酒井宗寿、磯部敏宏、松下祥子、中島章
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] 撥水性希土類酸化物の作製と評価2016

    • Author(s)
      谷本怜美, 磯部敏宏(研究分担者), 松下祥子(研究分担者), 中島章(研究代表者)
    • Organizer
      第63 回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学 (東京都)
    • Year and Date
      2016-03-20
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ti板・メッシュを用いた撥水性機能材料の作製と評価2016

    • Author(s)
      高橋宏和、磯部敏宏(研究分担者)、松下祥子(研究分担者)、中島章(研究代表者)
    • Organizer
      日本セラミックス協会2016年年会
    • Place of Presentation
      早稲田大学 (東京都)
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] Evaluation and control of droplet motion on various hydrophobic silane coatings2015

    • Author(s)
      Akira Nakajima(研究代表者)
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      ハワイコンベンションセンター(米国)
    • Year and Date
      2015-12-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 酸化チタンとチタンアパタイトの紫外線照射下での表面摩擦力変化2015

    • Author(s)
      鶴岡あゆみ、磯部敏宏(研究分担者)、松下祥子(研究分担者)、中島章(研究代表者)
    • Organizer
      日本セラミックス協会第28回秋季シンポジウム
    • Place of Presentation
      富山大学 (富山県)
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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