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Influences of oxygen partial pressure and additive elements on flux-free brazing of aluminum alloys

Research Project

Project/Area Number 15H04136
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Composite materials/Surface and interface engineering
Research InstitutionChiba Institute of Technology

Principal Investigator

Ozawa Shumpei  千葉工業大学, 工学部, 教授 (80404937)

Project Period (FY) 2015-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2019: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2018: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2017: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2016: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsアルミニウム合金 / フラックスフリーろう付 / 表面張力 / 雰囲気酸素分圧 / フラックスフリーろう付け / 直接観察
Outline of Final Research Achievements

The standard brazing process of aluminium alloys require use of non-corrosive fluxes to remove oxides from the base material and to prevent oxidation during the heating process. However it is difficult to used the Flux when brazing aluminum alloys containg a certain amount of Mg. Furthermore, residual flux even after brazing followed by cleaning may cause defects in the final product. In order to develop flux-free brazing of aluminum alloys, it was investigated the influences of sample composition and oxygen partial pressure of atmospheric gas on the brazability of allminum alloys. As a result, it was confirmed that the addition of Mg into the sample improves flux-free brazability of aluminum alloy. Furthermore, when oxygen partial pressure of atmospheric gas was down to ultra low value of 1e-30 atm, very good brazability was obtained comparable with that by flux brazing. It was indicated that surface tension of molten filler alloys influences on the shape of brazing fillets.

Academic Significance and Societal Importance of the Research Achievements

本研究では,ジルコニア式酸素ポンプによる極低酸素分圧においてAl合金のフラックスフリーロウ付を実現した.これは,従来は困難であったZn添加による防食や,Mg添加された高強度Al材への適用が可能となるもので,社会的に意義が高い.また単にロウ付実験を行うだけで無く,溶融ろうの表面張力測定も行うことで,添加元素がフラックスフリーロウ付に与える本質的な効果を明らかにした.特に酸素については,従来は酸化に対する影響のみが着目されてきたが,それは強力な表面活性元素であるため,表面張力の変化を介しても,ロウ付性に影響していることを示した.これは,高温融体の表面科学の観点から学術的にも意義が高い.

Report

(6 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (33 results)

All 2019 2018 2017 2016

All Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results,  Open Access: 3 results,  Acknowledgement Compliant: 2 results) Presentation (29 results) (of which Int'l Joint Research: 5 results,  Invited: 2 results)

  • [Journal Article] Precise Density Measurement of Liquid Titanium by Electrostatic Levitator2017

    • Author(s)
      S. Ozawa, Y. Kudo, K. Kuribayashi, Y. Watanabe and T. Ishikawa,
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 58 Issue: 12 Pages: 1664-1669

    • DOI

      10.2320/matertrans.L-M2017835

    • NAID

      130006219307

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 銀銅融体の表面張力に対する組成,温度,酸素活量の影響2017

    • Author(s)
      小澤俊平,西村大
    • Journal Title

      日本熱物性シンポジウム講演論文集

      Volume: 38

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Influence of Trace Impurities on Oxygen Activity for High Purity Nitrogen Gas Processed by Zirconia Oxygen Pump2016

    • Author(s)
      Shumpei OZAWA, Yuki KAWANOBE, Kazuhiko KURIBAYASHI and Toru NAGASAWA
    • Journal Title

      International journal of microgravity science and application

      Volume: 33 Issue: 2 Pages: 330214

    • DOI

      10.15011/jasma.33.330214

    • NAID

      130007842624

    • ISSN
      2188-9783
    • Year and Date
      2016-04-30
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Influence of Trace Impurities on Oxygen Activity for High Purity Nitrogen Gas Processed by Zirconia Oxygen Pump2016

    • Author(s)
      S. Ozawa, Y, Kawanobe, K. Kuribayashi, and T. Nagasawa
    • Journal Title

      Int. J. Microgravity Sci. Appl.

      Volume: 33 Pages: 23456-23456

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] 選択式レーザ溶融法のビード形状に及ぼす雰囲気の影響2019

    • Author(s)
      濱田輝哉,中野禅,佐藤直子,小澤俊平
    • Organizer
      第27回機械学会・材料加工技術講演会(M&P2019)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 金属融体の表面張力に対する酸素分圧制御法の影響2019

    • Author(s)
      高橋駿,樋口龍輝,吉崎隼人,小澤俊平
    • Organizer
      日本マイクログラビティ応用学会 第31回学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 単純ガス混合および緩衝ガス混合下における溶鉄及び溶融ニッケルの表面張力測定2019

    • Author(s)
      樋口龍輝,高橋駿,吉崎隼人,小澤俊平
    • Organizer
      日本マイクログラビティ応用学会 第31回学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 溶鉄の表面張力に対する雰囲気ガス種の影響2019

    • Author(s)
      樋口龍輝,高橋駿,小澤 俊平
    • Organizer
      日本金属学会2019年秋期講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Influence of oxygen partial pressure on surface tension of metallic melts2019

    • Author(s)
      Shumpei Ozawa, Masaru Nishimura, Yu Kudo, and Takehiko Ishikawa
    • Organizer
      The 12th International Workshop on Subsecond Thermophysics (IWSSTP 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Composition dependence of surface tension for Fe-Si alloys measured by electromagnetic levitation method2019

    • Author(s)
      Hayato Yoshizaki, Masahiro Itakura, and Shumpei Ozawa
    • Organizer
      The 12th International Workshop on Subsecond Thermophysics (IWSSTP 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High temperature measurement of surface tension of liquid aluminum by electromagnetic levitation2019

    • Author(s)
      Takaya Iwano and Shumpei Ozawa
    • Organizer
      The 12th International Workshop on Subsecond Thermophysics (IWSSTP 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Surface tension of high temperature liquid silicon under well controlled oxygen partial pressure in vicinity of melt surface2019

    • Author(s)
      Kota Sugisawa, Masahiro Itakura, and Shumpei Ozawa
    • Organizer
      The 12th International Workshop on Subsecond Thermophysics (IWSSTP 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金属融体の表面張力に対する雰囲気酸素分圧の影響2019

    • Author(s)
      小澤俊平
    • Organizer
      溶接学会界面接合研究委員会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 電磁浮遊法を用いたアルミニウム融体の表面張力に対する雰囲気酸素分圧の影響2019

    • Author(s)
      岩野貴哉,小澤俊平
    • Organizer
      日本金属学会2019年春期講演大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Si 融体の表面張力に対する表面酸素分圧の影響2019

    • Author(s)
      杉澤昂太,板倉真博,小澤俊平
    • Organizer
      日本鉄鋼協会2019年春季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Surface tension of molten brazing filler alloys measured by the electromagnetic levitation technique2018

    • Author(s)
      Shumpei Ozawa, Mararu Nishimura
    • Organizer
      12th Asian Microgravity Symposium
    • Related Report
      2018 Annual Research Report
  • [Presentation] Surface Tension Measurement of Molten Fe-Si Alloys by Electromagnetic Levitation Method2018

    • Author(s)
      Hayato Yoshizaki, Takumi Tsukahara,Shumpei Ozawa
    • Organizer
      12th Asian Microgravity Symposium
    • Related Report
      2018 Annual Research Report
  • [Presentation] High Temperature Measurement of Surface Tension for Molten Zircaloy by Containerless Technique2018

    • Author(s)
      Takahiro Suzuki, Takuya Nakajima, Shumpei Ozawa
    • Organizer
      12th Asian Microgravity Symposium
    • Related Report
      2018 Annual Research Report
  • [Presentation] 表面酸素分圧を考慮した電磁浮遊法による半導体融体の表面張力測定2018

    • Author(s)
      板倉真博,杉澤昂太,村越至,栗林一彦,小澤俊平
    • Organizer
      日本マイクログラビティ応用学会 第30回学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電磁浮遊法を用いた半導体融体の表面張力に及ぼす雰囲気酸素分圧の影響2018

    • Author(s)
      杉澤昂太,板倉真博,村越至,栗林一彦,小澤俊平
    • Organizer
      日本マイクログラビティ応用学会 第30回学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電磁浮遊法を用いたFe-Si合金融体の表面張力2018

    • Author(s)
      吉崎隼人,塚原拓海,小澤俊平
    • Organizer
      日本マイクログラビティ応用学会 第30回学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電磁浮遊法による液体アルミニウムの表面張力測定2018

    • Author(s)
      岩野貴哉,小澤俊平
    • Organizer
      日本マイクログラビティ応用学会 第30回学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Fe-Si合金融体の表面張力に対する組成依存性2018

    • Author(s)
      吉崎隼人,小澤俊平
    • Organizer
      日本鉄鋼協会2018年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Al合金のろう付継手のフィレット形成に及ぼす酸素分圧の影響2018

    • Author(s)
      長島充宏,小澤俊平,松本卓也,篠田智之,柳川裕,鈴木太一
    • Organizer
      日本金属学会2018年秋期講演大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 密閉構造を有するAl合金のろう付性と雰囲気酸素分圧の関係2018

    • Author(s)
      長島充宏,小澤俊平,松本卓也,篠田智之,柳川裕,鈴木太一
    • Organizer
      溶接学会 平成30年度秋季全国大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電磁浮遊法によるジルカロイ融体の表面張力2018

    • Author(s)
      小澤俊平,鈴木岳大,中野拓哉,工藤優
    • Organizer
      日本金属学会2018年春期講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Al合金のフラックスフリーろう付に及ぼすMg添加と雰囲気酸素分圧の影響2017

    • Author(s)
      篠田智之,小澤俊平,栗林一彦,山吉知樹,伊藤泰永
    • Organizer
      日本金属学会2017年春期講演大会
    • Place of Presentation
      首都大学東京南大沢キャンパス(東京都八王子市)
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] 銀銅融体の表面張力に対する組成,温度,酸素活量の影響2017

    • Author(s)
      小澤俊平,西村大
    • Organizer
      第38回日本熱物性シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸素活量を考慮した電磁浮遊法によるシリコン融体の表面張力測定2017

    • Author(s)
      板倉真博,小澤俊平,栗林一彦,村越至
    • Organizer
      日本マイクログラビティ応用学会 第29回学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 電磁浮遊法によるジルカロイ融体の表面張力測定2017

    • Author(s)
      鈴木岳大,小澤俊平,栗林一彦,中野拓哉,工藤裕
    • Organizer
      日本マイクログラビティ応用学会 第29回学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Flux-free Brazing of Aluminum Alloys under Ultra-low Oxygen Partial Pressure using Zirconia Oxygen Pump2016

    • Author(s)
      T. Shinoda, S. Ozawa, K. Kuribayashi, T. Yamayoshi, and Y. Ito
    • Organizer
      10th International Conference on Trends in Welding Research
    • Place of Presentation
      一ツ橋ホール(東京都千代田区)
    • Year and Date
      2016-10-12
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 極低酸素分圧雰囲気におけるアルミニウム合金のフラックスレスろう付2016

    • Author(s)
      篠田智之,小澤俊平,栗林一彦,山吉知樹,伊藤泰永
    • Organizer
      軽金属学会 第130回春期大会
    • Place of Presentation
      大阪大学(大阪府吹田市)
    • Year and Date
      2016-05-28
    • Related Report
      2016 Annual Research Report
  • [Presentation] アルミニウム合金のフラックスレスろう付性に及ぼす加熱時間および雰囲気酸素分圧の影響2016

    • Author(s)
      篠田智之,小澤俊平,栗林一彦,山吉知樹,伊藤泰永
    • Organizer
      日本金属学会2016年春期(第158回)講演大会
    • Place of Presentation
      東京理科大学(東京都葛飾区)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2022-11-04  

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