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Clarification of step structure formation on the solution growth interface of SiC by direct interface observation and molecular dynamics simulation

Research Project

Project/Area Number 15H04166
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making/Resorce production engineering
Research InstitutionThe University of Tokyo

Principal Investigator

Yoshikawa Takeshi  東京大学, 生産技術研究所, 准教授 (90435933)

Co-Investigator(Kenkyū-buntansha) 川西 咲子  東北大学, 多元物質科学研究所, 助教 (80726985)
澁田 靖  東京大学, 大学院工学系研究科(工学部), 准教授 (90401124)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,250,000 (Direct Cost: ¥12,500,000、Indirect Cost: ¥3,750,000)
Fiscal Year 2017: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2016: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Keywordsシリコンカーバイド / 固液界面 / 直接観察 / 分子動力学法 / SiC / 溶液成長 / 界面観察 / ステップ構造
Outline of Final Research Achievements

By using the in-situ observation technique of solution growth interface , it was determined that the generation of striated inclusions at SiC growth interface is caused by bunching step forming after the interaction of the edge of spiral hilock with advancing steps. Then, the continuous stable growth of spiral growth at the threading screw dislocation was achieved at the small supersaturation condition, and its usage to derive the relative value of the step energy from its slope structure was demonstrated.
The interface growth behavior at the interface of Si-C solution and 3C, 4H, 6H-SiC crystals were studied by molecular dynamics simulation, and the growth behavior on different crystal planes was evaluated. Especially, the growth on 4H-SiC{1-102} shows the continuous stable growth with the rough interface.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (10 results)

All 2018 2017 2016 Other

All Int'l Joint Research (1 results) Presentation (9 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results)

  • [Int'l Joint Research] CNRS・Grenoble(フランス)

    • Related Report
      2017 Annual Research Report
  • [Presentation] Real-time Observation of Solution Growth Interface of SiC Using Alloy Solvent2018

    • Author(s)
      Sakiko Kawanishi, Takeshi Yoshikawa and Kazuki Morita
    • Organizer
      TMS2018
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] SiCの溶液成長における界面成長機構2018

    • Author(s)
      吉川 健
    • Organizer
      日本結晶成長学会バルク分科会第102回研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Si-Cr溶媒に添加したAlのSiC溶液成長界面への影響2017

    • Author(s)
      大黒 寛典, 川西 咲子, 吉川 健
    • Organizer
      日本金属学会
    • Place of Presentation
      首都大学東京(東京都八王子市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] In Situ Observation on Step-Bunching and Inclusion Formation During Solution Growth of SiC Combined with Ex Situ Analysis2017

    • Author(s)
      Kosuke Fukui, Miki Shiraishi, Sakiko Kawanishi, Takeshi Yoshikawa, Hironori Daikoku, Hiroaki Saito and Kazuhiko Kusunoki
    • Organizer
      The International Conference on Silicon Carbide and Related Materials 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In-situ observation of competition between spiral growth and step-flow growth during solution growth of 4H-SiC2016

    • Author(s)
      Sakiko Kawanishi, Takeshi Yoshikawa
    • Organizer
      The 11th European Conference on Silicon Carbide & Related Materials
    • Place of Presentation
      Halkidiki (Greece)
    • Year and Date
      2016-09-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of Al addition in Si-Cr melt by real-time observation of 4H-SiC growth interface2016

    • Author(s)
      Hironori Daikoku, Sakiko Kawanishi, Takeshi Yoshikawa
    • Organizer
      The 11th European Conference on Silicon Carbide & Related Materials
    • Place of Presentation
      Halkidiki (Greece)
    • Year and Date
      2016-09-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高温界面現象の理解へ向けた界面リアルタイム観察の取り組み2016

    • Author(s)
      吉川健, 川西咲子
    • Organizer
      日本鉄鋼協会
    • Place of Presentation
      大阪大学(大阪府吹田市)
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] SiC溶液成長時のスパイラル成長とステップの競合過程のその場観察2016

    • Author(s)
      川西咲子, 吉川健
    • Organizer
      第63回応用物理学会春季学術講演会,
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] In-situ observation of solution growth interface of SiC from Fe-Si solvent2016

    • Author(s)
      Sakiko Kawanishi and Takeshi Yoshikawa
    • Organizer
      40th International Conference and Expo on Advanced Ceramics and Composites
    • Place of Presentation
      Florida(United States)
    • Year and Date
      2016-01-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2015-04-16   Modified: 2019-03-29  

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