Development of Hybrid Anvil Cell for polarized and unpolarized neutron diffraction experiment

• Project/Area Number: 15H05433
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Quantum beam science
• Research Institution: National Institute for Materials Science
• Principal Investigator: Terada Noriki 国立研究開発法人物質・材料研究機構, 先端材料解析研究拠点, 主任研究員 (60442993)
• Project Period (FY): 2015-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥22,880,000 (Direct Cost: ¥17,600,000、Indirect Cost: ¥5,280,000); Fiscal Year 2017: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000); Fiscal Year 2016: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000); Fiscal Year 2015: ¥15,080,000 (Direct Cost: ¥11,600,000、Indirect Cost: ¥3,480,000)
• Keywords: マルチフェロイクス / 中性子回折 / 高圧力 / 中性子回折実験 / 強相関電子系 / 磁性 / 誘電体物性

Outline of Final Research Achievements

By developing the Hybrid-Anvil-Cell(HAC) for polarized and unpolarized neutron diffraction experiment, we have studied the pressure-induced ferroelectric properties in some multiferroic materials. By multi-exstream condition (5 GPa, 5 T, 1.5 K) neutron diffraction experiment for multiferroic TbMnO3 on the cold neutron time-of-flight diffractometer WISH in ISIS, we found that the gigantic ferroelectric polarization induced by high pressure in TbMnO3 is induced by the collinear magnetic ordering through the exchange striction mechanism. We also have developed the complete nonmagnetic HAC with nonmagnetic sapphire and diamond composite (or WC) anvils for Spherical-Neutron-Polarimetry (SNP) analysis experiment. By using the cell, we have succeeded in the first SNP analysis for the multiferroic CuFeO2 at Institut Laue Langevin, and determined the complex noncollinear magnetic structures in the pressure-induced ferroelectric phases.

Research Products

• [Int'l Joint Research] Rutherford Appleton Laboratory/University of Oxford(英国)
• [Int'l Joint Research] Institut Laue Langevin(フランス)
• [Int'l Joint Research] モスクワ大学(ロシア連邦)
• [Int'l Joint Research] Rutherford Appleton Laboratory(英国)
• [Int'l Joint Research] Institute of Laue Langevin(フランス)
• [Int'l Joint Research] Rutherford Appleton Laboratory(英国)
• [Int'l Joint Research] モスクワ大学(ロシア連邦)
• [Journal Article] High-Pressure Synthesis, Structures, and Properties of Trivalent A-Site-Ordered Quadruple Perovskites RMn7O12 (R = Sm, Eu, Gd, and Tb) (2018)
  • Author(s): L. Zhang, N. Terada, R. D. Johnson, D. Khalyavin, P. Manuel, Y. Katsuya, M. Tanaka, K. Yamaura, A. A. Belik
  • Journal Title: Inorganic Chemestry Volume: 印刷中
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Magnetic Bragg dip and Bragg edge in neutron transmission spectra of typical spin superstructures (2017)
  • Author(s): Mamiya Hiroaki、Oba Yojiro、Terada Noriki、Watanabe Norimichi、Hiroi Kosuke、Shinohara Takenao、Oikawa Kenichi
  • Journal Title: Scientific Reports Volume: 7 Issue: 1 Pages: 15516-15516
  • DOI: 10.1038/s41598-017-15850-3
  • Peer Reviewed / Open Access
• [Journal Article] Magneto-orbital ordering in the divalent A-site quadruple perovskite manganites AMn7O12 (A=Sr, Cd, and Pb) (2017)
  • Author(s): Johnson R. D.、Khalyavin D. D.、Manuel P.、Radaelli P. G.、Glazkova I. S.、Terada N.、Belik A. A.
  • Journal Title: Physical Review B Volume: 96 Issue: 5 Pages: 054448-054448
  • DOI: 10.1103/physrevb.96.054448
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Rich magnetoelectric phase diagrams of multiferroic single-crystal α-NaFeO2 (2017)
  • Author(s): Terada Noriki、Ikedo Yuta、Sato Hirohiko、Khalyavin Dmitry D.、Manuel Pascal、Miyake Atsushi、Matsuo Akira、Tokunaga Masashi、Kindo Koichi
  • Journal Title: Physical Review B Volume: 96 Issue: 3 Pages: 035128-035128
  • DOI: 10.1103/physrevb.96.035128
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Evidence of Charge Transfer and Orbital Magnetic Moment in Multiferroic CuFeO2 (2016)
  • Author(s): Yasuo Narumi, Tetsuya Nakamura, Hidekazu Ikeno, Noriki Terada, Takayuki Morioka, Kota Saito, Hideaki Kitazawa, Koichi Kindo, and Hiroyuki Nojiri
  • Journal Title: Journal of the Physical Society of Japan Volume: 85 Issue: 11 Pages: 114705-114705
  • DOI: 10.7566/jpsj.85.114705
  • NAID: 210000134153
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Magnetic ordering in pressure-induced phases with giant spin-driven ferroelectricity in multiferroic TbMnO3 (2016)
  • Author(s): N. Terada, D. D. Khalyavin, P. Manuel, T. Osakabe, A. Kikkawa, H. Kitazawa
  • Journal Title: Physical Review B (Rapid Communications) Volume: 93 Issue: 8 Pages: 081104-081104
  • DOI: 10.1103/physrevb.93.081104
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Spin-Driven Multiferroic Properties of PbMn7O12 Perovskite (2016)
  • Author(s): A. A. Belik, Y. S. Glazkova, N. Terada, Y. Matsushita, A. V. Sobolev, I. A. Presniakov, N. Tsujii, S. Nimori, K. Takehana, and Y. Imanaka
  • Journal Title: Inorganic chemistry Volume: 55 Issue: 12 Pages: 6169-6169
  • DOI: 10.1021/acs.inorgchem.6b00774
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Differentiation between Ferroelectricity and Thermally Stimulated Current in Pyrocurrent Measurements of Multiferroic MMn7O12 (M = Ca, Sr, Cd, Pb) (2016)
  • Author(s): N. Terada, Y. S. Glazkova, and A. A. Belik
  • Journal Title: Physical Review B Volume: 93 Issue: 15 Pages: 155127-155127
  • DOI: 10.1103/physrevb.93.155127
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Activation of frozen ferroelectric domain wall by magnetic field sweeping in multiferroic CuFeO2 (2016)
  • Author(s): H. Tamatsukuri, S. Mitsuda, T. Nakajima, K. Shibata, C. Kaneko, K. Takehana, Y. Imanaka, N. Terada, H. Kitazawa, K. Prokes, S. Matas, K. Kiefer, S. Paeckel, A. Sokolowski, B. Klemke, and S. Gerischer
  • Journal Title: PHYSICAL REVIEW B Volume: 93 Issue: 17 Pages: 174101-174101
  • DOI: 10.1103/physrevb.93.174101
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] 冷中性子TOF回折計WISHにおけるHybrid-Anvil-Cellを用いた高圧力中性子回折実験：マルチフェロイクスへの応用 (2016)
  • Author(s): 寺田典樹
  • Journal Title: 日本中性子科学会誌 「波紋」 Volume: 26 Pages: 91-91
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] 冷中性子TOF回折計WISHにおけるHybrid-Anvil-Cellを用いた 高圧力下中性子回折実験：マルチフェロイクスへの応用 (2016)
  • Author(s): 寺田典樹
  • Journal Title: 中性子科学会誌 波紋 Volume: ５月号
  • NAID: 130007510633
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Magnetic structure of the frustrated antiferromagnetic spin-1/2 chain substance Cu3Mo2O9: appearance of a partial disordered state (2015)
  • Author(s): M. Hase, H. Kuroe, V. Y. Pomjakushin, L. Leller, R. Tamura, N. Terada, Y. Matsushita, A. Doenni, and T. Sekine
  • Journal Title: Physical Review B Volume: 92 Issue: 5
  • DOI: 10.1103/physrevb.92.054425
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] High-Pressure Synthesis, Crystal Structures, and Properties of CdMn7O12 and SrMn7O12 Perovskites (2015)
  • Author(s): Y. S. Glazkova, N. Terada, Y. Matsushita, Y. Katsuya, M. Tanaka, I. A. Presniakov, A. V. Sobolev, and A. A. Belik
  • Journal Title: Inorganic Chemistry Volume: 54 Issue: 18 Pages: 9081-9091
  • DOI: 10.1021/acs.inorgchem.5b01472
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Multistage ordering and critical singularities in Co1-xZnxAl2O4 (0<x<1): Dilution and pressure effects in a magnetically frustrated (2015)
  • Author(s): T. Naka, K. Sato, Y. Matsushita, N. Terada, S. Ishii, T. Nakane, M. Taguchi, M. Nakayama, S. Ohara, S. Takami, A. Matsushita
  • Journal Title: Physical Review B Volume: 91 Issue: 22 Pages: 1-10
  • DOI: 10.1103/physrevb.91.224412
  • Peer Reviewed
• [Journal Article] Magnetic ordering and ferroelectricity in multiferroic 2H－AgFeO2: Comparison between hexagonal and rhombohedral polytypes (2015)
  • Author(s): N. Terada, D. D. Khalyavin, P. Manuel, Y. Tsujimoto, and A. A. Belik
  • Journal Title: Physical Review B Volume: 91 Issue: 9
  • DOI: 10.1103/physrevb.91.094434
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Ferroelectricity induced by ferriaxial crystal rotation and spin helicity in a B-site-ordered double-perovskite multiferroic In2NiMnO6 (2015)
  • Author(s): Noriki Terada, Dmitry D. Khalyavin, Pascal Manuel, Wei Yi, Hiroyuki S. Suzuki, Naohito Tsujii, Yasutaka Imanaka, and Alexei A. Belik
  • Journal Title: Physical Review B Volume: 91 Issue: 10
  • DOI: 10.1103/physrevb.91.104413
  • Peer Reviewed / Int'l Joint Research
• [Presentation] 単結晶を用いた菱面体晶および六方晶AgFeO2の磁気秩序と誘電分極の探査 (2018)
  • Author(s): 寺田典樹, D D. Khalyavin, P. Manuel, F. Orlandi, 池戸優太, 佐藤博彦
  • Organizer: 2018年日本物理学会年次大会
• [Presentation] 中性子透過スペクトルに現れるスピン秩序由来の磁気ブラッグエッジ・ブラッグディップとその利用 (2018)
  • Author(s): 間宮広明, 大場洋次郎, 寺田典樹, 渡邉騎通, 廣井孝介, 篠原武尚, 及川健一
  • Organizer: 2018年日本物理学会年次大会
• [Presentation] 高圧力下3次元偏極解析に向けた非磁性ハイブリッドアンビルセルの開発 (2017)
  • Author(s): 寺田典樹, Laurent Chapon, 長壁豊隆
  • Organizer: 2017年日本物理学会年次大会
  • Place of Presentation: 大阪大学（大阪府豊中市）
  • Year and Date: 2017-03-17
• [Presentation] スピン誘導型強誘電体CuFeO2の一軸圧力下における磁場誘起新奇強誘電相の探査 (2017)
  • Author(s): 玉造博夢, 清水崇宏, 満田節生, 廣浦晃, 山崎祐希, 竹端寛治, 今中康貴, 寺田典樹, 北澤英明
  • Organizer: 2017年日本物理学会年次大会
  • Place of Presentation: 大阪大学（大阪府豊中市）
  • Year and Date: 2017-03-17
• [Presentation] Spherical neutron polarimetry analysis under pressure for delafossite CuFeO2 (2017)
  • Author(s): N. Terada, N. Qureshi, L. C. Chapon and T. Osakabe
  • Organizer: The 9th Asia Pacific Center for Theoretical Physics Workshop on Multiferroics, University of Tokyo, Kashiwa Nov 9-11, 2017
  • Int'l Joint Research
• [Presentation] New perovskites in R2O3-Mn2O3 systems (R = rare-earths) (2017)
  • Author(s): A. A. Belik, L. Zhang, Y. Matsushita, N. Terada, Y. Katsuya, M. Tanaka, and K. Yamaura
  • Organizer: AIRAPT-26, China National Convention Center,Beijing,China Aug 19-24, 2017
  • Int'l Joint Research / Invited
• [Presentation] High-Pressure Neutron Diffraction with Hybrid-Anvil-Cell for Multiferroic Research (2017)
  • Author(s): N. Terada
  • Organizer: The 15th International Conference on Advanced Materials
  • Int'l Joint Research / Invited
• [Presentation] 高圧・高磁場下における中性子回折実験によるマルチフェロイクスの研究 (2017)
  • Author(s): 寺田典樹
  • Organizer: 強磁場コラボラトリーが拓く未踏計測領域への挑戦と物質・材料科学の最先端
• [Presentation] 中性子散乱でできること (2017)
  • Author(s): 寺田典樹
  • Organizer: 第６０回化合部新磁性材料研究会
  • Invited
• [Presentation] 高圧力下中性子3次元偏極解析によるマルチフェロイクスCuFeO2の圧力誘起強誘電相の磁気構造決定 (2017)
  • Author(s): 寺田典樹, Navid Qureshi, Laurent Chapon, 長壁豊隆
  • Organizer: 2017年日本物理学会秋季大会
• [Presentation] High-Pressure Neutron Diffraction with Hybrid-Anvil-Cell for Multiferroic Research (2016)
  • Author(s): 寺田典樹
  • Organizer: 第２６回 日本MRS年次大会
  • Place of Presentation: マツ・ムラホール（神奈川県横浜市中区住吉町）
  • Year and Date: 2016-12-19
  • Invited
• [Presentation] High-Pressure Neutron Diffraction with Hybrid-Anvil-Cell for Multiferroic Research (2016)
  • Author(s): Noriki Terada
  • Organizer: The 8th Asia Pacific Center for Theoretical Physics Workshop
  • Place of Presentation: 上海大学（中国）
  • Year and Date: 2016-10-08
  • Int'l Joint Research / Invited
• [Presentation] マルチフェロイクスMM7O12における焦電流の再検証 (2016)
  • Author(s): 寺田典樹, Y. S. Glazkova, and A. A. Belik
  • Organizer: 2016年日本物理学会年会
  • Place of Presentation: 東北学院大学
  • Year and Date: 2016-03-19
• [Presentation] マルチフェロイック物質 CuFeO2 の価数状態 (2016)
  • Author(s): 鳴海康雄,中村哲也,池野豪一, 寺田典樹,北澤英明, 金道浩一, 野尻浩之
  • Organizer: 2016年日本物理学会年会
  • Place of Presentation: 東北学院大学
  • Year and Date: 2016-03-19
• [Presentation] 高圧下中性子回折によるマルチフェロイクスの研究 (2015)
  • Author(s): 寺田典樹
  • Organizer: 第５回 応用セラミックス研究所 材料構造講演会
  • Place of Presentation: 東工大
  • Year and Date: 2015-10-26
  • Invited
• [Presentation] High-Pressure Neutron Diffraction with Hybrid-Anvil-Cell for Multiferroic Materials (2015)
  • Author(s): N. Terada, D. D. Khalyavin, P. Manuel, T. Osakabe, A. Kikkawa, P. G. Radaelli and H. Kitazawa
  • Organizer: NIMS conference 2015
  • Place of Presentation: つくば
  • Year and Date: 2015-10-14
  • Int'l Joint Research / Invited
• [Presentation] Magnetic ordering and ferroelectricity in multiferroic 2H-AgFeO2: Comparison between hexagonal and rhombohedral polytypes (2015)
  • Author(s): N. Terada, D. D. Khalyavin, P. Manuel, Y. Tsujimoto and A. A. Belik
  • Organizer: NIMS conference 2015
  • Place of Presentation: つくば
  • Year and Date: 2015-10-14
  • Int'l Joint Research
• [Presentation] 高圧下中性子回折によるTbMnO3の圧力磁場誘起巨大強誘電相の磁気秩序の解明 (2015)
  • Author(s): 寺田典樹, Dmitry Khalyavin, Pascal Manuel, 長壁豊隆, 吉川明子, 北澤英明
  • Organizer: 2015年日本物理学会秋季大会
  • Place of Presentation: 関西大学
  • Year and Date: 2015-09-25
• [Presentation] マルチフェロイック三角格子反強磁性体3R-AgFeO2とα-NaFeO2の単結晶作成と強磁場物性 (2015)
  • Author(s): 池戸優太, 佐藤博彦, 金道浩一, 松尾晶, 徳永将史, 三宅厚志, 寺田典樹
  • Organizer: 2015年日本物理学会秋季大会
  • Place of Presentation: 関西大学
  • Year and Date: 2015-09-25
• [Presentation] スピネル型CoAl2O4系の置換および圧力効果 (2015)
  • Author(s): 名嘉節, 佐藤康一, 寺田典樹, 石井聡, 高見誠一, 田口実, 中根茂行, 中山美奈子, 松下能孝, 松下明行
  • Organizer: 2015年日本物理学会秋季大会
  • Place of Presentation: 関西大学
  • Year and Date: 2015-09-25
• [Presentation] Crystal Chemistry and Physics of Perovskites with Small Cations at the A Site (2015)
  • Author(s): A. A. Belik, Y. Wei, Y. Matsushita, M. Tanaka, N. Terada, H. S. Suzuki, N. Tsujii, Y. Imanaka, D. D. Khalyavin, P. Manuel, A. V. Sobolev and I. A. Presnyakov
  • Organizer: 15th EUROPEAN CONFERENCE ON SOLID STATE CHEMISTRY
  • Place of Presentation: Vienna
  • Year and Date: 2015-08-23
  • Int'l Joint Research
• [Presentation] Crystal Chemistry and Physics of Perovskites with Small Cations at the A Site (2015)
  • Author(s): A. A. Belik, Y. Wei, Y. Matsushita, M. Tanaka, N. Terada, H. S. Suzuki, N. Tsujii, Y. Imanaka, D. D. Khalyavin, P. Manuel, A. V. Sobolev and I. A. Presnyakov
  • Organizer: 12th International Conference on Materials Chemistry
  • Place of Presentation: Univ. of York, UK
  • Year and Date: 2015-07-20
  • Int'l Joint Research
• [Presentation] Field induced phenomena in magnetically frustrated systems Co1-xMxAl2O4 (M = Mg, Zn) (2015)
  • Author(s): T. Naka, K. Sato, S. Ishii, T. Nakane. N. Terada, M. Taguchi, M. Nakayama, Y. Matsushita, A. Matsushita and S. Takami
  • Organizer: International conference on magnetism 2015
  • Place of Presentation: Barcelona
  • Year and Date: 2015-07-05
  • Int'l Joint Research
• [Presentation] Magnetic structure of quasi-one-dimensional frustrated antiferromagnet Cu3Mo2O9 (2015)
  • Author(s): M. Hase, H. Kuroe, V. Y. Pomjakushin, L. Keller, R. Tamura, N. Terada, Y. Matsushita, S Dnni, and T. Sekine
  • Organizer: International conference on magnetism 2015
  • Place of Presentation: Barcelona
  • Year and Date: 2015-07-05
  • Int'l Joint Research
• [Presentation] Single-crystal growth and magnetic properties of multiferroic triangular- lattice antiferromagnet AgFeO2 and alpha-NaFeO2 (2015)
  • Author(s): Y. Ikedo, H. Sato, K. Kindo, A. Matsuo, M. Tokunaga, A. Miyake and N. Terada
  • Organizer: International conference on magnetism 2015
  • Place of Presentation: Barcelona
  • Year and Date: 2015-07-05
  • Int'l Joint Research
• [Presentation] A comparison in multiferroic coupling between triangular lattice polytypes of hexagonal and rhombohedral AgFeO2 (2015)
  • Author(s): N. Terada, D. D. Khalyavin. P. Manuel, Y. Tsujimoto. A. A. Belik
  • Organizer: International conference on magnetism 2015
  • Place of Presentation: Barcelona
  • Year and Date: 2015-07-05
  • Int'l Joint Research
• [Remarks] Terada homepage
  • URL: http://www.nims.go.jp/nsg/terada/index.html
• [Remarks] SAMURAI NIMS Researchers Directory Service
  • URL: https://samurai.nims.go.jp/profiles/terada_noriki
• [Remarks] 物質・材料研究機構のSAMURAIシステム
  • URL: http://samurai.nims.go.jp/TERADA_Noriki-j.html
• [Remarks] 寺田典樹のホームページ
  • URL: http://www.nims.go.jp/nsg/terada/index.html