Development of unique physical properties of three dimensional graphene

• Project/Area Number: 15H05473
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Physical chemistry
• Research Institution: University of Tsukuba (2016-2017); Tohoku University (2015)
• Principal Investigator: ITO Yoshikazu 筑波大学, 数理物質系, 准教授 (90700170)
• Project Period (FY): 2015-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥24,830,000 (Direct Cost: ¥19,100,000、Indirect Cost: ¥5,730,000); Fiscal Year 2017: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000); Fiscal Year 2016: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000); Fiscal Year 2015: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
• Keywords: グラフェン / 多孔質 / 周期構造 / ３次元デバイス / 化学ドープ / トランジスタ / プラズモン / 触媒 / ディラック電子 / テラヘルツ / 化学物理 / ナノ多孔質 / 炭素材料 / 周期的極小曲面 / ディラックコーン / 電子状態密度 / 比熱

Outline of Final Research Achievements

3D graphene constructed by a single 2D graphene sheet preserved with graphene characters such as Dirac fermion system, high conductivity and high electron mobility has been developed to reveal the fundamental physics in the 3D graphene and to overcome limitations in 2D graphene based applications. The 3D graphene produced on porous metal by chemical vapor deposition methods has greatly extended the possible use of graphene materials in transistor, plasmon and catalysts as 3D graphene devices, and these physical properties were elucidated.

Research Products

• [Int'l Joint Research] 上海交通大学(中国)
• [Int'l Joint Research] ローマ・ラ・サピエンツァ大学(イタリア)
• [Int'l Joint Research] クイーンズランド工科大学(オーストラリア)
• [Int'l Joint Research] マックスプランク研究所(ドイツ)
• [Int'l Joint Research] 国立台湾大学(台湾)
• [Int'l Joint Research]
• [Int'l Joint Research] Johns Hopkins University(米国)
• [Int'l Joint Research] East China Normal University(中国)
• [Journal Article] Cooperation between holey graphene and NiMo alloy for hydrogen evolution in an acidic electrolyte (2018)
  • Author(s): Yoshikazu Ito, Tatsuhiko Ohto, Daisuke Hojo, Mitsuru Wakisaka, Yuki Nagata, Linghan Chen, Kailong Hu, Masahiko Izumi, Jun-ichi Fujita, and Tadafumi Adschiri
  • Journal Title: ACS Catal. Volume: in press Issue: 4 Pages: 3579-3586
  • DOI: 10.1021/acscatal.7b04091
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Topology and doping effects in three-dimensional nanoporous graphene (2018)
  • Author(s): Di Bernardo Iolanda、Avvisati Giulia、Chen Chaoyu、Avila Jose、Asensio Maria Carmen、Hu Kailong、Ito Yoshikazu、Hines Peter、Lipton-Duffin Josh、Rintoul Llew、Motta Nunzio、Mariani Carlo、Betti Maria Grazia
  • Journal Title: Carbon Volume: 131 Pages: 258-265
  • DOI: 10.1016/j.carbon.2018.01.076
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Improved graphene applications made possible by 3D graphene structures (2018)
  • Author(s): Ito Yoshikazu
  • Journal Title: TANSO Volume: 2018 Issue: 281 Pages: 8-15
  • DOI: 10.7209/tanso.2018.8
  • NAID: 130006405212
  • ISSN: 0371-5345, 1884-5495
  • Peer Reviewed
• [Journal Article] Bottom-up Synthesis of Porous NiMo Alloy for Hydrogen Evolution Reaction (2018)
  • Author(s): Hu Kailong、Jeong Samuel、Wakisaka Mitsuru、Fujita Jun-ichi、Ito Yoshikazu
  • Journal Title: Metals Volume: 8 Issue: 2 Pages: 83-83
  • DOI: 10.3390/met8020083
  • NAID: 120007133858
  • Peer Reviewed / Open Access
• [Journal Article] Three-dimensional porous graphene networks expand graphene-based electronic device application (2018)
  • Author(s): Y. Ito, Y. Tanabe, K. Sugawara, M. Koshino, T. Takahashi, K. Tanigaki, H. Aoki, M. Chen
  • Journal Title: Phys. Chem. Chem. Phys. Volume: 20 Issue: 9 Pages: 6024-6033
  • DOI: 10.1039/c7cp07667c
  • NAID: 120007134239
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Near room temperature chemical vapor deposition of graphene with diluted methane and molten gallium catalyst (2017)
  • Author(s): Fujita Jun-ichi、Hiyama Takaki、Hirukawa Ayaka、Kondo Takahiro、Nakamura Junji、Ito Shin-ichi、Araki Ryosuke、Ito Yoshikazu、Takeguchi Masaki、Pai Woei Wu
  • Journal Title: Scientific Reports Volume: 7 Issue: 1 Pages: 1-7
  • DOI: 10.1038/s41598-017-12380-w
  • NAID: 120007134786
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Two-Dimensional Hallmark of Highly Interconnected Three-Dimensional Nanoporous Graphene (2017)
  • Author(s): Di Bernardo Iolanda、Avvisati Giulia、Mariani Carlo、Motta Nunzio、Chen Chaoyu、Avila Jose、Asensio Maria Carmen、Lupi Stefano、Ito Yoshikazu、Chen Mingwei、Fujita Takeshi、Betti Maria Grazia
  • Journal Title: ACS Omega Volume: 2 Issue: 7 Pages: 3691-3697
  • DOI: 10.1021/acsomega.7b00706
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Terahertz and mid-infrared plasmons in three-dimensional nanoporous graphene (2017)
  • Author(s): D’Apuzzo Fausto、Piacenti Alba R.、Giorgianni Flavio、Autore Marta、Guidi Mariangela Cestelli、Marcelli Augusto、Schade Ulrich、Ito Yoshikazu、Chen Mingwei、Lupi Stefano
  • Journal Title: Nature Communications Volume: 8 Issue: 1 Pages: 14885-14885
  • DOI: 10.1038/ncomms14885
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] One-step nanoporous structure formation using NiO nanoparticles: pore size control and pore size dependence of hydrogen evolution reaction (2017)
  • Author(s): Yoshikazu Ito, Masahiko Izumi, Daisuke Hojo, Mitsuru Wakisaka, Tsutomu Aida, Tadafumi Adschiri
  • Journal Title: Chemistry Letters Volume: 46 Issue: 2 Pages: 267-270
  • DOI: 10.1246/cl.161017
  • NAID: 130005317050
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Correlation between Chemical Dopants and Topological Defects in Catalytically Active Nanoporous Graphene (2016)
  • Author(s): Yoshikazu Ito, Yuhao Shen, Daisuke Hojo, Yoji Itagaki, Takeshi Fujita, Linghan Chen, Tsutomu Aida, Zheng Tang, Tadafumi Adschiri, Mingwei Chen
  • Journal Title: Advanced Materials Volume: 28 Issue: 48 Pages: 10644-10651
  • DOI: 10.1002/adma.201604318
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Electric Properties of Dirac Fermions Captured into 3D Nanoporous Graphene Networks (2016)
  • Author(s): Y. Tanabe, Y. Ito, K. Sugawara, D. Hojo, M. Koshino, T. Fujita, T. Aida, X. Xu, K. K. Huynh, H. Shimotani, T. Adschiri, T. Takahashi, K. Tanigaki, H. Aoki, and M. Chen
  • Journal Title: Adv. Mater. Volume: 28 Issue: 46 Pages: 10304-10304
  • DOI: 10.1002/adma.201601067
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Presentation] ナノポーラスグラフェンにおける弱局在の幾何学的制御 (2018)
  • Author(s): 岡本拓也, 伊藤良一, 藤田武志, 河野行雄
  • Organizer: 日本物理学会第73回年次大会
• [Presentation] 太陽光熱を高効率に利用した3次元グラフェンデバイスの開発 (2018)
  • Author(s): 伊藤良一
  • Organizer: 第二回プレ戦略研究会「次世代物質・デバイス戦略開発拠点」
• [Presentation] ワンステップで作成したナノ多孔質ニッケル電極による水素発生電極の開発 (2017)
  • Author(s): 伊藤良一、泉正彦、北條大介、脇坂暢、相田努、阿尻 雅文
  • Organizer: 日本化学会 第97春季年会 (2017)
  • Place of Presentation: 慶應義塾大学 日吉キャンパス（神奈川県横浜市）
  • Year and Date: 2017-03-16
• [Presentation] 3D Graphene Provide New Ways for Creating Graphene Applications (2017)
  • Author(s): Yoshikazu Ito
  • Organizer: 2017 TIMS-CENIDE Joint Symposium on Nanoscience and Nanotechnology
  • Place of Presentation: 筑波大学（茨城県つくば市）
  • Year and Date: 2017-03-10
  • Int'l Joint Research
• [Presentation] 3D graphene expands graphene applications (2017)
  • Author(s): Yoshikazu Ito
  • Organizer: The AIMR International Symposium 2017
  • Place of Presentation: Sendai International Center（宮城県仙台市）
  • Year and Date: 2017-02-13
  • Int'l Joint Research / Invited
• [Presentation] 穴が空いたグラフェンで表面を保護された強酸性水溶液中での卑金属水素発生電極の開発 (2017)
  • Author(s): 伊藤良一, 北條大介, 脇坂暢, 阿尻雅文
  • Organizer: 第11回分子科学討論会
• [Presentation] 窒素ドープグラフェンで保護されたNiMoナノ粒子による強酸性水溶液での高効率水素発生材料の開発 (2017)
  • Author(s): 胡 凱龍，藤田 淳一，伊藤良一
  • Organizer: 第11回分子科学討論会
• [Presentation] Analyzing nanoscale optical and thermal properties in nanoporous graphene by near-field infrared microscopy (2017)
  • Author(s): Takuya Okamoto, D. Suzuki, Yoshikazu. Ito, Takeshi Fujita, Yukio Kawano
  • Organizer: 42nd International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz)
  • Int'l Joint Research
• [Presentation] 3D graphene expands graphene applications for sustainable societies (2017)
  • Author(s): Yoshikazu Ito
  • Organizer: Interdisciplinary Symposium for Up-and-coming Material Scientists 2017 (ISUMS2017)
  • Int'l Joint Research / Invited
• [Presentation] ３次元グラフェンの合成と物性評価およびデバイス応用 (2016)
  • Author(s): 伊藤良一
  • Organizer: 日本物理学会 2016年秋季大会（物性）
  • Place of Presentation: 金沢大学角間キャンパス（石川県金沢市）
  • Year and Date: 2016-09-13
  • Invited
• [Presentation] 金属を使用しないナノ多孔質グラフェンを用いた水素発生電極の開発 (2016)
  • Author(s): 伊藤 良一、北條 大介、板垣 陽地、Yuhao Shen、藤田 武志、Tang Zheng、相田 努、阿尻 雅文、陳 明偉
  • Organizer: 第10回分子科学討論会
  • Place of Presentation: 神戸ファッションマート（兵庫県神戸市）
  • Year and Date: 2016-09-13
• [Presentation] ナノ多孔質グラフェンを用いた高効率水蒸気発生材料 (2016)
  • Author(s): 伊藤良一, 田邉洋一, 韓久慧, 藤田武志, 谷垣勝己, 陳明偉
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 京田辺市多々羅都谷 同志社大学
  • Year and Date: 2016-03-24
• [Presentation] 3次元ナノ多孔質グラフェンを用いた高効率エネルギー創生 (2015)
  • Author(s): 伊藤 良一,Qiu H.-J., 藤田 武志, 陳 明偉
  • Organizer: 分子科学討論会
  • Place of Presentation: 東京都目黒区大岡山 東京工業大学
  • Year and Date: 2015-09-16
• [Presentation] High Quality Three-Dimensional Nanoporous Graphene (2015)
  • Author(s): Yoshikazu Ito, Takeshi Fujita, Mingwei Chen
  • Organizer: 22nd International Symposium on Metastable, Amorphous and Nanostructured Materials
  • Place of Presentation: フランス パリ
  • Year and Date: 2015-07-13
  • Int'l Joint Research
• [Remarks] 平成29年度 科学技術分野 文部科学大臣表彰若手科学者賞 数理物質系 伊藤 良一
  • URL: http://www.tsukuba.ac.jp/update/awards/20170511143104.html
• [Remarks] 平成29年度筑波大学若手教員特別奨励賞 数理物質系 伊藤 良一
  • URL: http://www.tsukuba.ac.jp/update/awards/20170620113304.html
• [Remarks] 第30回安藤博記念学術奨励賞
• [Remarks] 第39回本多記念奨励賞
  • URL: http://hondakinenkai.or.jp/docs/59th_awards.pdf
• [Remarks] 日刊工業新聞、伊藤筑波大准教授ら選定
  • URL: https://www.nikkan.co.jp/articles/view/00429832
• [Remarks] 伊藤助教、第10回 PCCP Prize受賞
  • URL: http://www.wpi-aimr.tohoku.ac.jp/jp/news/media/2016/20160328_000619.html
• [Remarks] 伊藤助教、トーキン科学技術賞受賞
  • URL: http://www.wpi-aimr.tohoku.ac.jp/jp/news/media/2016/20160316_000617.html
• [Patent(Industrial Property Rights)] 多孔質体およびその製造方法並びに電極 (2016)
  • Inventor(s): 伊藤良一、陳明偉、阿尻雅文、北條大介、藤田武志、相田努
  • Industrial Property Rights Holder: 伊藤良一、陳明偉、阿尻雅文、北條大介、藤田武志、相田努
  • Industrial Property Rights Type: 特許
  • Filing Date: 2016-04-28