Precision supramolecular polymerization under kinetic control
| Project/Area Number |
15H05483
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional solid state chemistry
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| Research Institution | National Institute for Materials Science |
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Principal Investigator |
Sugiyasu Kazunori 国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主幹研究員 (80469759)
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| Research Collaborator |
FUKUI Tomoya
SASAKI Norihiko
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥25,090,000 (Direct Cost: ¥19,300,000、Indirect Cost: ¥5,790,000)
Fiscal Year 2017: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2016: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2015: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
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| Keywords | 超分子ポリマー / 精密超分子重合 / ポルフィリン / アゾベンゼン / 自己集合 / 超分子化学 / 精密重合 |
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| Outline of Final Research Achievements |
In this research program, we aimed at establishing a method that allows the precision supramolecular polymerization. As demonstrated in polymer chemistry, molecular weight (or length) of a polymer is one of the most fundamental structural parameters that determine function and property of polymeric materials.
During the last two years, we have succeeded in (1) controlled supramolecular polymerization in two-dimension, and (2) photoregulated controlled supramolecular polymerization. Further studies on the structure-property relationship of the thus-obtained supramolecular polymers are expected to shed light on a new aspect of supramolecular polymeric materials.
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Report
(4 results)
Research Products
(37 results)
