Expansion of Molecular Palladium Chains Affording Single-Molecular Function
| Project/Area Number |
15H06407
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nara Women's University |
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Principal Investigator |
Nakamae Kanako 奈良女子大学, 自然科学系, 助教 (20757231)
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| Project Period (FY) |
2015-08-28 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Keywords | 金属クラスター / 金属-金属結合 / パラジウム / 多座ホスフィン / 単分子素子 / 金属―金属結合 / 金属‐金属結合 |
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| Outline of Final Research Achievements |
This project intended to synthesize linear palladium-extended metal atom chains by bottom-up construction using octanuclear palladium complexes supported by linear tetraphosphines. We have got results suggesting a possibility for further aggregation of the linear palladium units by reduction of Pd8 complexes with an aim of connecting through metal-metal bonding interaction. By using organic compounds as 2-connecting ligands, we have synthesized and characterized coordination polymers consisting of palladium chains.
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Report
(3 results)
Research Products
(15 results)
