Study for structure and catalysis of supported metal nanoparticles
| Project/Area Number |
15H06468
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Nanomaterials chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
TOKUNAGA Makoto 九州大学, 大学院理学研究院, 教授 (40301767)
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| Project Period (FY) |
2015-08-28 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Keywords | 金属ナノ粒子調製 / 選択的水素化反応 / 水素化反応 / 触媒・化学プロセス / ナノ材料 / ナノ粒子調製 |
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| Outline of Final Research Achievements |
Conventional impregnation methods are useful for preparing supported metal nanoparticles except small gold (Au) nanoparticles. We developed a novel simple and easy impregnation method using Au complexes coordinated with β-alanine as precursors. The chloride-free Au complexes were successful for the preparing small Au nanoparticles, which exhibited an average diameter less than 3 nm on the basis of TEM observations, on various supports including silica, which were difficult to be applied for conventional methods. Thermal behavior of the Au complex was investigated by thermogravimetry-differential thermal analyses and in situ X-ray absorption fine structure (XAFS). Lower decomposition and reduction temperature of the Au complex prevented Au atoms from aggregating and from following growth of Au particles. The prepared Au/SiO2 showed high selectivity for hydrogenation of 1-nitro-4-vinylbenzene into 1-ethyl-4-nitorobenzene.
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Report
(3 results)
Research Products
(12 results)
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[Presentation] Removal of Aged Odor from Japanese Sake with Supported Gold and Silver Nanoparticles by Chemical Adsorption2016
Author(s)
H. Murayama, Y. Yamamoto, T. Hasegawa, M. Tone, E. Yamamoto, T. Ishida, A. Isogai, T. Fujii, M. Okumura, T. Fujitani, T. Honma, M. Tokunaga
Organizer
C&FC2016 (International Symposium on Catalysis and Fine Chemicals 2016)
Place of Presentation
Taipei, Taiwan
Year and Date
2016-11-12
Related Report
Int'l Joint Research
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