Unveiling the origine of activity of carbon-based electrocatalysts and synthesis of highly active abundant-element-based catalysts
Project/Area Number |
15H06850
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Research Category |
Grant-in-Aid for Research Activity Start-up
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Allocation Type | Single-year Grants |
Research Field |
Inorganic industrial materials
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Research Institution | National Institute for Materials Science |
Principal Investigator |
Sakaushi Ken 国立研究開発法人物質・材料研究機構, エネルギー・環境材料研究拠点, 研究員 (50756484)
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Project Period (FY) |
2015-08-28 – 2017-03-31
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Project Status |
Completed (Fiscal Year 2016)
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Budget Amount *help |
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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Keywords | 材料科学 / 電極過程 / 化学物理 / 化学構造 / 窒化炭素構造体 / 触媒 / 無機工業材料 / 材料化学 |
Outline of Final Research Achievements |
Highly efficient electrocatalyst based on abundant elements is key for wide spread of renewable energies. This study describes a one-step and simple synthetic strategy to obtain graphitic, nanoporous C-,N-architectures (CNAs) consisted of porous nanosheets with controlled catalytic activity. Those materials were examined on the oxygen/hydrogen electrocatalytic reactions in order to unveil their electrode processes as the multifunctional electrocatalyst, and show that the CNAs can undergo the ORR in H2SO4 solution with the four-electron process together with a high electrocatalytic activity The results show that the combination of porosity and the specific chemical structure of nitrogen is the key for the selectivity of the electrochemical reaction and a high ORR/HER activity using C-, N-based catalysts.
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Report
(3 results)
Research Products
(14 results)