| Project/Area Number |
15K00600
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Environmental conscious materials and recycle
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| Research Institution | Gunma University |
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Principal Investigator |
Ozaki Jun-ichi 群馬大学, 大学院理工学府, 教授 (30214125)
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| Co-Investigator(Kenkyū-buntansha) |
石井 孝文 群馬大学, 大学院理工学府, 助教 (50750155)
神成 尚克 群馬大学, 大学院理工学府, 助教 (90743336)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
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| Keywords | カーボンアロイ / ナノシェルカーボン / BNドープカーボン / 過酸化水素 / 酸素還元活性 / 表面塩基性 / ヘテロポリ酸 / ドープカーボン |
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| Outline of Final Research Achievements |
This research was aimed at the development of two types of carbon alloy catalysts necessary for constructing the system shown in the title. As for the preparation of the first type catalyts, we prepared carbon materials from mixtures of a starting polymer and different types of transition metal complexs and evaluated the hydrogen peroxide formation. The second type catalysts were the heteropolyacid (HPA) fixed on the carbon alloys with surface basicity. We conducted the characterization and activity test using 3-methyl -3-buten-1-ol as the reactant to be oxidezed by hydrogen peroxide. We found the possibilities to control the electronic state and the catalytic activity of HPA by tuning the surface properties of the carbon substrates.
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