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Search of the guideline for molecular design of the soft materials applicable for flexible thermoelectric devices

Research Project

Project/Area Number 15K05609
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic and hybrid materials
Research InstitutionShimane University

Principal Investigator

Yamaguchi Isao  島根大学, 総合理工学研究科, 教授 (00272708)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords導電性高分子 / 熱電変換素子 / ドープ率 / ゼーベック係数 / ドーパント / ピロリン酸 / ドープ率制御 / 熱電変換 / 電気伝導度 / キャリア / ドーピング / 電気伝導後 / キャリアー
Outline of Final Research Achievements

In this study, we investigated the electric properties of the p- and n-types conducting polymers with high electric conductivity for the purpose of the development of flexible thermoelectric devices. We succeeded in control of doping rates of p-type polyaniline copolymers. In order to obtain the conducting polymers which show air-stable n-doped state, the monomer with a dopant cation trapping site was synthesized, but polymerization of the monomer did not conducted owing to its low yield.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (8 results)

All 2018 2017 2016

All Journal Article (8 results) (of which Peer Reviewed: 3 results)

  • [Journal Article] Chemical Properties and Self-assembled Ordered Structures of π-Conjugated Cooligomers Consisted of 2,6-Dialkoxynaphthalene-1,5-diyl, 2,1,3-Benzothiadiazole-4,7-diyl, and 1,4-Phenylenediethynylene Units2018

    • Author(s)
      I. Yamaguchi, A. Kondo
    • Journal Title

      Polymer Bulletin

      Volume: 75 Issue: 4 Pages: 1635-1650

    • DOI

      10.1007/s00289-017-2117-9

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Ru-Complex-Catalyzed Synthesis of Telechelic Oligobenzimidazoles and Their Chemical Properties, Reactivity, and Structures2018

    • Author(s)
      I. Yamaguchi, K. Imoto
    • Journal Title

      Macromolecules

      Volume: 51 Issue: 1 Pages: 91-100

    • DOI

      10.1021/acs.macromol.7b02187

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Synthesis and Electrical Properties of Copolymers of o-Phenylenediamine with Aniline, 3,4-Ethylenedioxythiophene and 2,3,5,6-Tetrafluoroaniline2017

    • Author(s)
      I. Yamaguchi, R. Morisaka
    • Journal Title

      Polymer International

      Volume: 66 Issue: 2 Pages: 320-326

    • DOI

      10.1002/pi.5269

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Synthesis of Hydroxyoligophenylenes Containing Electron-donating, Electron Accepting Groups, or π-Deficient Aromatic Ring and Their Solvatochromic Behavior2017

    • Author(s)
      I. Yamaguchi, R. Yamaji
    • Journal Title

      Journal of Physical Organic Chemistry

      Volume: 30 Issue: 10 Pages: e3671-e3671

    • DOI

      10.1002/poc.3671

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Synthesis of Polyfluorene and Oligofluorene with N1-Hexylcytosine Side Chains and Their Sensing Ability for Nucleosides2017

    • Author(s)
      I. Yamaguchi, K. Miyawaki
    • Journal Title

      Reactive and Functional Polymers

      Volume: 120 Pages: 14-19

    • DOI

      10.1016/j.reactfunctpolym.2017.09.001

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Self-doped N-4-Sulfopropylaniline-3,4-Ethylenedioxythiophene Copolymers: Synthesis and Optical and Electrical Properties2017

    • Author(s)
      I. Yamaguchi, M. Ito
    • Journal Title

      High Perform. Polym.

      Volume: 未定 Issue: 8 Pages: 976-983

    • DOI

      10.1177/0954008316665895

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Optical and Electrical Properties of Self-doped Copolymers Consisting of N-4-Sulfopropylaniline and 3,4-Ethylenedioxythiophene Units2016

    • Author(s)
      I. Yamaguchi, H. Yamanoue
    • Journal Title

      High Performance Polymers

      Volume: 28 Issue: 6 Pages: 717-723

    • DOI

      10.1177/0954008315595446

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Chemical Properties of Polyphenylenes Cross-linked by Electron-accepting Viologen Moiety,2016

    • Author(s)
      I. Yamaguchi, M. Yamamoto
    • Journal Title

      Polymer Bulletin

      Volume: 73 Issue: 7 Pages: 1827-1839

    • DOI

      10.1007/s00289-015-1579-x

    • Related Report
      2015 Research-status Report
    • Peer Reviewed

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Published: 2015-04-16   Modified: 2019-03-29  

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