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Novel environmentally friendly red inorganic pigments

Research Project

Project/Area Number 15K05643
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionTottori University

Principal Investigator

MASUI Toshiyuki  鳥取大学, 工学研究科, 教授 (00304006)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords顔料 / 赤色 / 環境調和型 / 希土類 / アルカリ土類金属 / 複合酸化物 / 無機顔料 / 希土類元素 / コバルト / 赤色顔料 / イットリウム / セリウム / 結晶場分裂 / 酸化ビスマス / 酸化ジルコニウム / バンドギャップ
Outline of Final Research Achievements

Cadmium red, red lead and cinnabar have been known as red inorganic pigments, but these include metals showing strong toxicity such as cadmium, lead and mercury. In this research, we aimed to develop new red inorganic pigments that do not contain elements harmful to the human body and the environment. It was found that the samples exhibit red color when Ce3+ was used as a coloring source, by synthesizing various composite oxides and evaluating their colors. In particular, SrY2-xCexO4 (0 < x < 1.2) samples were synthesized and it turned out that it changed from white to reddish brown with increasing the Ce3+ concentration, and the redness was the highest at the composition of SrYCeO4.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (18 results)

All 2018 2017 2016 2015

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 3 results,  Acknowledgement Compliant: 2 results) Presentation (12 results) (of which Int'l Joint Research: 1 results,  Invited: 4 results)

  • [Journal Article] Synthesis and characterisation of Ba(Zn1-xCox)2Si2O7 (0 ≦ x ≦ 0.50) for blue-violet inorganic pigments2018

    • Author(s)
      Tsukimori Takashi、Shobu Yusuke、Oka Ryohei、Masui Toshiyuki
    • Journal Title

      RSC Advances

      Volume: 8 Issue: 16 Pages: 9017-9022

    • DOI

      10.1039/c8ra00101d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis and characterisation of SrY2-xCexO4 as environmentally friendly reddish-brown pigments2017

    • Author(s)
      Oka Ryohei、Shobu Yusuke、Aoyama Fumiya、Tsukimori Takashi、Masui Toshiyuki
    • Journal Title

      RSC Advances

      Volume: 7 Issue: 87 Pages: 55081-55087

    • DOI

      10.1039/c7ra10250j

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Perovskite-type <i>ALn</i>O<sub>3</sub> (<i>A</i> = Ca, Sr, Ba; <i>Ln</i> = Ce, Pr, Tb) oxides as environmentally friendly yellow pigments2017

    • Author(s)
      OKA Ryohei、TSUKIMORI Takashi、INOUE Hiroki、MASUI Toshiyuki
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 125 Issue: 8 Pages: 652-656

    • DOI

      10.2109/jcersj2.17118

    • NAID

      130005878457

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis and Characterization of Bi4Zr3O12 as an Environment-friendly Inorganic Yellow Pigment2017

    • Author(s)
      T. Tsukimori, R. Oka, and T. Masui
    • Journal Title

      Dyes and Pigments

      Volume: 139 Pages: 808-811

    • DOI

      10.1016/j.dyepig.2017.01.013

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis and Characterization of Black Pigments Based on Calcium Manganese Oxides for High Near-infrared (NIR) Reflectance2016

    • Author(s)
      R. Oka and T. Masui
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 93 Pages: 90952-90957

    • DOI

      10.1039/c6ra21443f

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Novel Environment Friendly Inorganic Red Pigments Based on Bi4V2O112015

    • Author(s)
      Wendusu, A. Shiraishi, N. Takeuchi, T. Masui, and N. Imanaka
    • Journal Title

      RSC Advances

      Volume: 5 Issue: 56 Pages: 44886-44894

    • DOI

      10.1039/c5ra04734j

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 環境調和型の着色無機顔料2017

    • Author(s)
      増井敏行
    • Organizer
      第75回顔料工学講座
    • Place of Presentation
      大阪科学技術センター
    • Year and Date
      2017-03-08
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Calcium Manganite Black Pigments for High Near-infrared Reflectance2017

    • Author(s)
      R. Oka and T. Masui,
    • Organizer
      The 34th International Japan-Korea Seminar on Ceramics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] BaZn2Si2O7を母体とする新規な青紫色無機顔料の合成とその評価2017

    • Author(s)
      月森貴史・岡 亮平・増井敏行
    • Organizer
      2017年日本化学会中国四国支部鳥取大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ストロンチウムとイットリウムの複合酸化物からなる優環境型無機顔料2017

    • Author(s)
      岡 亮平・青山文哉・月森貴史・増井敏行
    • Organizer
      日本セラミックス協会第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] BaZn2Si2O7を母体とする新規な青紫色無機顔料の合成とその評価2017

    • Author(s)
      月森貴史・増井敏行
    • Organizer
      日本セラミックス協会第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 環境に優しい無機顔料2016

    • Author(s)
      増井敏行
    • Organizer
      第7回セラミックスの基礎学問研修会
    • Place of Presentation
      岡山大学
    • Year and Date
      2016-11-24
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] ビスマスとジルコニウムを用いた新規黄色顔料の開発2016

    • Author(s)
      月森貴史・増井敏行
    • Organizer
      2016年日本化学会中国四国支部香川大会
    • Place of Presentation
      香川大学
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] カルシウムとマンガンを用いた黒色遮熱無機顔料の開発2016

    • Author(s)
      岡 亮平・増井敏行
    • Organizer
      2016年日本化学会中国四国支部香川大会
    • Place of Presentation
      香川大学
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] ビスマスとジルコニウムを用いた新規黄色顔料の開発2016

    • Author(s)
      月森貴史・増井敏行
    • Organizer
      2016年色材研究発表会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-10-13
    • Related Report
      2016 Research-status Report
  • [Presentation] カルシウムとマンガンを用いた黒色遮熱無機顔料の開発2016

    • Author(s)
      岡 亮平・増井敏行
    • Organizer
      2016年色材研究発表会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-10-13
    • Related Report
      2016 Research-status Report
  • [Presentation] 希土類入門-4f電子とは?-2015

    • Author(s)
      増井敏行
    • Organizer
      第19回希土類サマースクール
    • Place of Presentation
      ホテルラングウッド新潟
    • Year and Date
      2015-08-06
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 環境に優しい無機顔料2015

    • Author(s)
      増井敏行
    • Organizer
      第50回東海若手セラミスト懇話会夏期セミナー
    • Place of Presentation
      アヤハレークサイドホテル
    • Year and Date
      2015-06-25
    • Related Report
      2015 Research-status Report
    • Invited

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Published: 2015-04-16   Modified: 2019-03-29  

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