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Nano-spectroscopic elucidation of prebiotic chemical reactions on mineral surfaces

Research Project

Project/Area Number 15K13601
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Geochemistry/Cosmochemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

Masahiko Hara  東京工業大学, 物質理工学院, 教授 (50181003)

Co-Investigator(Kenkyū-buntansha) 矢野 隆章  東京工業大学, 物質理工学院, 助教 (90600651)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords走査型プローブ顕微鏡 / 化学進化 / ラマン分光法 / 原子間力顕微鏡
Outline of Final Research Achievements

A nano-spectroscopic method was developed by combining atomic force microscopy with advanced laser spectroscopy, which enabled us to probe biomolecular interactions on mineral surfaces. We also developed another nano-spectroscopic method using nanoparticles of minerals. Raman scattering from amino acid molecules adsorbed on the nanoparticle surfaces was found to be strongly enhanced by the size-depedent electromagnetic resonances of the nanoparticles, allowing us to spectroscopically investigate the adsorbate states.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (9 results)

All 2016 2015

All Journal Article (3 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results,  Open Access: 1 results) Presentation (6 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Surface force analysis of pyrite: its reactivity to amino acid adsorption2016

    • Author(s)
      Narangerel, G., Matsuzaki, N., Nakazawa, Y., Afrin, R., Aono, M., Yano, T., Hayashi, T., Hara, M.
    • Journal Title

      Advances in Materials Physics and Chemistry

      Volume: 6 Issue: 07 Pages: 167-176

    • DOI

      10.4236/ampc.2016.67018

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Laser scanning assisted tip-enhanced optical microscopy for robust optical nanospectroscopy2016

    • Author(s)
      Yano, T., Tsuchimoto, Y., Mochizuki, M., Hayashi, T., Hara, M.
    • Journal Title

      Appl. Spectrosc

      Volume: 70 Issue: 7 Pages: 1239-1243

    • DOI

      10.1177/0003702816652369

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation and Structure of Self-Assembled Monolayers by Adsorption of Octaneselenocyanate on Au(111)2016

    • Author(s)
      Han, S. Kang, H. Park, J. B. Hayashi, T. Hara, M. Noh, J.
    • Journal Title

      Journal of Nanoscience and Nanotechnology

      Volume: 16 Issue: 8 Pages: 8610-8613

    • DOI

      10.1166/jnn.2016.12509

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Nano-analysis of Prebiotic Molecular Interactions on Rutile TiO2 Surfaces Using Thermal Desorption Spectroscopy and Atomic Force Microscopy2016

    • Author(s)
      K. Imai, G. Narangerel, T. Yano, M. Aono, M. Hara
    • Organizer
      AsiaNANO 2016
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2016-10-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Interaction of prebiotic biomolecules with mineral surface using single molecule dynamic force spectroscopy2016

    • Author(s)
      R. Afrin, G. Narangerel, T. Yano, T. Hayashi, M. Aono and M. Hara
    • Organizer
      AsiaNANO 2016
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2016-10-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Surface force analysis of pyrite (FeS2) mineral: its reactivity to amino acid adsorption2015

    • Author(s)
      Narangerel Ganbaatar, 松崎仁奈, 林智広, 矢野隆章, 原正彦
    • Organizer
      2015年真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2015-12-03
    • Related Report
      2015 Research-status Report
  • [Presentation] アミノ酸重合に対する鉱物表面の触媒作用に関する研究2015

    • Author(s)
      中澤友哉, 矢野隆章, 林智弘, 原正彦
    • Organizer
      2015年真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2015-12-03
    • Related Report
      2015 Research-status Report
  • [Presentation] Observation of Streptavidin Immobilization on Mixed SAMs of Octanethiols and Biotin-tagged thiols by Atomic Force Microscopy2015

    • Author(s)
      クスバンティアティカ, 原正彦
    • Organizer
      2015年真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2015-12-03
    • Related Report
      2015 Research-status Report
  • [Presentation] Au(111)表面再配列と帯状構造に関する研究2015

    • Author(s)
      松崎仁奈, 矢野隆章, 林智広, 原正彦
    • Organizer
      2015年真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2015-12-03
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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