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Development of hydride ion conduction mechanism and novel energy devices

Research Project

Project/Area Number 15K13803
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

Kanno Ryoji  東京工業大学, 物質理工学院, 教授 (90135426)

Co-Investigator(Kenkyū-buntansha) 平山 雅章  東京工業大学, 物質理工学院, 准教授 (30531165)
鈴木 耕太  東京工業大学, 物質理工学院, 助教 (40708492)
小林 玄器  分子科学研究所, 協奏分子システム研究センター, 特任准教授 (30609847)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsヒドリドイオン / イオン導電体 / 結晶構造 / 導電メカニズム / ヒドリドイオン導電体 / 高圧合成 / イオン導電機構 / 電気化学デバイス
Outline of Final Research Achievements

New material search and hydride ion conduction mechanism analysis were carried out to develop the hydride conduction mechanism and the novel energy devices. The hydride ion conduction in the K2NiF4 type structure, which is the basic structure of the hydride ion conducting oxy-hydrides, proceeds mainly in the perovskite layer and hydride ion conduction in the perovskite layer is relatively faster than that of hydride ion in the rock salt layer. The K2NiF4 type La-Sr-Li-H-O based material was synthesized by sintering in a container sealed in a hydrogen atmosphere. Since larger quantities of samples can be obtained at one, the process was found to be suitable for the device verification has been established.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (25 results)

All 2017 2016 2015 Other

All Journal Article (3 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (19 results) (of which Int'l Joint Research: 5 results,  Invited: 10 results) Remarks (3 results)

  • [Journal Article] Ambient Pressure Synthesis and H<sup>&minus;</sup> Conductivity of LaSrLiH<sub>2</sub>O<sub>2</sub>2017

    • Author(s)
      Akihiro WATANABE, Genki KOBAYASHI, Naoki MATSUI, Masao YONEMURA, Akiko KUBOTA, Kota SUZUKI, Masaaki HIRAYAMA, Ryoji KANNO
    • Journal Title

      Electrochemistry

      Volume: 85 Issue: 2 Pages: 88-92

    • DOI

      10.5796/electrochemistry.85.88

    • NAID

      130005316112

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] ヒドリドイオン導電体2016

    • Author(s)
      小林玄器
    • Journal Title

      固体物理

      Volume: 51(12) Pages: 825-830

    • NAID

      40021038213

    • Related Report
      2016 Annual Research Report
  • [Journal Article] ヒドリドイオン導電体の開発と電解質材料への応用可能性2016

    • Author(s)
      小林玄器
    • Journal Title

      Energy Device

      Volume: 3(6) Pages: 53-58

    • Related Report
      2016 Annual Research Report
  • [Presentation] H- 導電性酸水素化物 La2-x-ySrx+yLiH3-x+yO3-y の常圧合成とイオン導電特性2017

    • Author(s)
      小林玄器, 渡邉明尋, 久保田亜紀子, 松井直喜, 米村雅雄, 鈴木耕太, 平山雅章, 菅野 了次
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] ヒドリドイオンが固体中を動く-新物質創成と電気化学デバイスへの期待2017

    • Author(s)
      菅野了次, 小林玄器
    • Organizer
      日本化学会第97回年会
    • Place of Presentation
      慶應義塾大学 日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] ヒドリドイオン導電性酸水素化物の物質開発2017

    • Author(s)
      小林玄器
    • Organizer
      第163回アドバンスト・バッテリー技術研究会「ポスト電池討論会」
    • Place of Presentation
      大阪科学技術センター
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] ヒドリドイオン導電体の開発2017

    • Author(s)
      小林玄器
    • Organizer
      2016年度量子ビームサイエンスフェスタ
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] ヒドリドイオン導電性酸水素化物の物質開発2017

    • Author(s)
      小林玄器
    • Organizer
      Workshop on Materials Science under Ultra-High Pressure 201
    • Place of Presentation
      愛媛大学
    • Year and Date
      2017-03-03
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] La2LiH1-2xO3の常圧合成と電気化学特性2016

    • Author(s)
      松井直喜, 小林玄器, 鈴木耕太, 渡邊明尋, Iqbal Muhammad, 米村雅雄, 平山雅章, 菅野了次
    • Organizer
      第42回固体イオニクス討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2016-12-05
    • Related Report
      2016 Annual Research Report
  • [Presentation] Ba-Li 系酸水素化物のヒドリドイオン導電特性2016

    • Author(s)
      小林玄器, 渡邉明尋, 米村雅雄, 鈴木耕太, 平山雅章, 菅野了次
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ
    • Year and Date
      2016-11-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] La2LiH1-2xO3+xの常圧下における合成と構造2016

    • Author(s)
      松井直喜, 鈴木耕太, 小林玄器, Iqbal Muhammad, 米村雅雄, 平山雅章, 菅野了次
    • Organizer
      第6回CSJ化学フェスタ2016
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2016-11-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ヒドリドイオン導電性酸水素化物の高圧合成2016

    • Author(s)
      小林玄器, 渡邉明尋, 米村雅雄, 鈴木耕太, 平山雅章, 菅野了次
    • Organizer
      第57回高圧討論会
    • Place of Presentation
      筑波大学
    • Year and Date
      2016-10-28
    • Related Report
      2016 Annual Research Report
  • [Presentation] Synthesis and H- Conductivity of Ba2LiH3-2xO1+X2016

    • Author(s)
      G. Kobayashi, A. Watanabe, K. Suzuki, M. Hirayama, M. Yonemura, R. Kanno
    • Organizer
      PRiME2016
    • Place of Presentation
      Hawaii,USA
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Material Design for H- Conductive Oxyhydrides2016

    • Author(s)
      Genki Kobayashi
    • Organizer
      Solid State Protonic Conductor-18
    • Place of Presentation
      Oslo, Norway
    • Year and Date
      2016-09-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of H- Conductive Oxyhydrides under Ambient Pressure2016

    • Author(s)
      G. Kobayashi, A. Kubota, N. Matsui, A. Watanabe, K. Suzuki, M. Hirayama, M. Yonemura, R. Kanno
    • Organizer
      Solid State Protonic Conductor-18
    • Place of Presentation
      Oslo, Norway
    • Year and Date
      2016-09-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of H- Conductivity of Ba2ScHO3 with the K2NiF4-Type Structure2016

    • Author(s)
      A. Watanabe, G. Kobayashi, T. Yamanaka, N. Matsui, K. Suzuki, M. Hirayama, M. Yonemura, R. Kanno
    • Organizer
      Solid State Protonic Conductor-18
    • Place of Presentation
      Oslo, Norway
    • Year and Date
      2016-09-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] H-導電性酸水素化物の合成2016

    • Author(s)
      小林玄器
    • Organizer
      セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] La-Sr-Li系酸水素化物の合成とH-導電特性2016

    • Author(s)
      小林玄器
    • Organizer
      第4回酸化物研究の新機軸に向けた学際討論会「ナノ酸化物で見える科学と物理:新展開と異分野融合」
    • Place of Presentation
      京都大学 化学研究所
    • Year and Date
      2016-08-05
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] ヒドリドイオン導電体の開発2016

    • Author(s)
      小林玄器
    • Organizer
      新世代研究所 第1回界面ナノ科学研究会
    • Place of Presentation
      湯沢グランドホテル
    • Year and Date
      2016-07-04
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] H-導電性酸水素化物の合成とイオン導電特性2016

    • Author(s)
      小林玄器
    • Organizer
      セラミックス協会2016年年会 サテライトプログラム 第2回構造科学と新物質探索研究会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2016-03-14
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Hydride Conduction in Oxyhydrides2015

    • Author(s)
      Genki Kobayashi
    • Organizer
      20th International Conference on Solid State Ionics
    • Place of Presentation
      Keystone, USA
    • Year and Date
      2015-06-14
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] ヒドリド導電性酸水素化物の合成2015

    • Author(s)
      小林玄器, 今井弓子, 日沼洋陽, 渡邉明尋, Muhammad IQBAL, 平山雅章, 田中功, 菅野了次
    • Organizer
      粉体粉末冶金協会平成27年度春季大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-05-26
    • Related Report
      2015 Research-status Report
  • [Remarks] 東工大菅野平山研ホームページ

    • URL

      http://www.kanno.echem.titech.ac.jp/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 分子科学研究所小林グループホームページ

    • URL

      https://www.ims.ac.jp/organization/kobayashi_g/index.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 東京工業大学 菅野・平山研究室

    • URL

      http://www.kanno.echem.titech.ac.jp/

    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

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